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An open quantum system refers to a system that is further coupled to a bath system consisting of surrounding radiation fields, atoms, molecules, or proteins. The bath system is typically modeled by an infinite number of harmonic…

Chemical Physics · Physics 2020-07-10 Yoshitaka Tanimura

For a system strongly coupled to a heat bath, the quantum coherence of the system and the heat bath plays an important role in the system dynamics. This is particularly true in the case of non-Markovian noise. We rigorously investigate the…

Statistical Mechanics · Physics 2015-02-16 Yoshitaka Tanimura

The hierarchical equations of motion technique has found widespread success as a tool to generate the numerically exact dynamics of non-Markovian open quantum systems. However, its application to low temperature environments remains a…

Chemical Physics · Physics 2013-10-15 Jeremy M. Moix , Jianshu Cao

We derive the formula of energy flux for the hierarchical equations of motion (HEOM) method with the help of stochastic decoupling technique. The resulting expression is a combination of the terms in the first two layers of the hierarchy.…

Statistical Mechanics · Physics 2019-04-30 Yun Zhou , Tie-Jun Xiao , Jun Cao , Yun-An Yan

The hierarchical equations of motion (HEOM) for a generalized quantum dissipative system is rigorously constructed in the frameworks of two different stochastic dynamical descriptions, i.e., the non-Markovian quantum state diffusion…

Quantum Physics · Physics 2018-07-18 Wei Wu

A recently developed approach to the thermodynamics of open quantum systems, on the basis of the principle of minimal dissipation, is applied to the spin-boson model. Employing a numerically exact quantum dynamical treatment based on the…

Quantum Physics · Physics 2024-08-30 Salvatore Gatto , Alessandra Colla , Heinz-Peter Breuer , Michael Thoss

Over the last two decades, the hierarchical equations of motion (HEOM) of Tanimura and Kubo have become the equation of motion-based tool for numerically exact calculations of system-bath problems. The HEOM is today generalized to many…

Quantum Physics · Physics 2023-05-15 Robert Fuchs , Marten Richter

We investigate the quantum dynamics of Coulomb potential systems in thermal baths. We study these systems within the framework of open quantum dynamics theory, focusing on preserving the rotational symmetry of the entire system, including…

Quantum Physics · Physics 2026-03-18 Yankai Zhang , Yoshitaka Tanimura

We have developed a computer code for the thermodynamic hierarchical equations of motion derived from a spin subsystem coupled to multiple Drude baths at different temperatures, which are connected to or disconnected from the subsystem as a…

Statistical Mechanics · Physics 2024-10-31 Shoki Koyanagi , Yoshitaka Tanimura

A nonperturbative theory is developed, aiming at an exact and efficient evaluation of a general quantum system interacting with arbitrary bath environment at any temperature and in the presence of arbitrary time-dependent external fields.…

Statistical Mechanics · Physics 2007-05-23 Rui-Xue Xu , YiJing Yan

Using the quasi-equilibrium Helmholtz energy (qHE), defined as the thermodynamic work in a quasi-static process, we investigate the thermal properties of both an isothermal process and a transition process between the adiabatic and…

Statistical Mechanics · Physics 2022-07-06 Shoki Koyanagi , Yoshitaka Tanimura

A nonperturbative quantum impurity solver is proposed based on a formally exact hierarchical equations of motion (HEOM) formalism for open quantum systems. It leads to quantitatively accurate evaluation of physical properties of strongly…

Strongly Correlated Electrons · Physics 2014-08-04 Dong Hou , Rulin Wang , Xiao Zheng , NingHua Tong , JianHua Wei , YiJing Yan

Understanding how coherence of quantum systems affects thermodynamic quantities, such as work and heat, is essential for harnessing quantumness effectively in thermal quantum technologies. Here, we study the unique contributions of quantum…

Quantum Physics · Physics 2025-02-07 Rui Huang , Q. Y. Cai , Farzam Nosrati , Rosario Lo Franco , Zhong-Xiao Man

The theory of hierarchical equations of motion (HEOM) is one of the standard methods to give exact evaluations of the dynamics as coupled to harmonic oscillator environments. However, the theory is numerically demanding due to its…

Chemical Physics · Physics 2022-05-31 Tatsushi Ikeda , Akira Nakayama

We consider the problem of finding the energy minimum of a complex quantum Hamiltonian by employing a non-Markovian bath prepared in a low energy state. The energy minimization problem is thus turned into a thermodynamic cooling protocol in…

Quantum Physics · Physics 2024-03-29 Alberto Imparato , Nicholas Chancellor , Gabriele De Chiara

Local master equations are a widespread tool to model open quantum systems, especially in the context of many-body systems. These equations, however, are believed to lead to thermodynamic anomalies and violation of the laws of…

Quantum Physics · Physics 2021-02-23 Adam Hewgill , Gabriele De Chiara , Alberto Imparato

The hierarchical equations of motion (HEOM) approach is an accurate method to simulate open system quantum dynamics, which allows for systematic convergence to numerically exact results. To represent the effects of the bath, the reservoir…

Strongly Correlated Electrons · Physics 2023-05-31 Xiaohan Dan , Meng Xu , J. T. Stockburger , J. Ankerhold , Qiang Shi

Quantum computing offers promising new avenues for tackling the long-standing challenge of simulating the quantum dynamics of complex chemical systems, particularly open quantum systems coupled to external baths. However, simulating such…

Quantum Physics · Physics 2025-02-20 Xiaohan Dan , Eitan Geva , Victor S. Batista

The hierarchical equations of motion (HEOM) theory is one of the standard methods to rigorously describe open quantum dynamics coupled to harmonic environments. Such a model is used to capture non-Markovian and non-perturbative effects of…

Chemical Physics · Physics 2020-06-02 Tatsushi Ikeda , Gregory D. Scholes

The hierarchical equations of motion (HEOM) method is a numerically exact open quantum system dynamics approach. The method is rooted in an exponential expansion of the bath correlation function, which in essence strategically reshapes a…

Chemical Physics · Physics 2023-06-14 Yaling Ke
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