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Calculations of formation energies and charge transition levels of defects routinely rely on density functional theory (DFT) for describing the electronic structure. Since bulk band gaps of semiconductors and insulators are not well…

Materials Science · Physics 2012-04-19 Audrius Alkauskas , Alfredo Pasquarello

The analysis of structure-preserving numerical methods for the Poisson--Nernst--Planck (PNP) system has attracted growing interests in recent years. In this work, we provide an optimal rate convergence analysis and error estimate for finite…

Numerical Analysis · Mathematics 2022-02-23 Jie Ding , Cheng Wang , Shenggao Zhou

We propose a method to calculate the charge dynamical structure factors for the ground states of correlated electron systems based on the variational Monte Carlo method. Our benchmarks for the one- and two-dimensional Hubbard models show…

Strongly Correlated Electrons · Physics 2020-02-25 Kota Ido , Masatoshi Imada , Takahiro Misawa

Using a novel self-consistent implementation of Hedin's GW perturbation theory we calculate space and energy dependent self-energy for a number of materials. We find it to be local in real space and rapidly convergent on second-- to third--…

Strongly Correlated Electrons · Physics 2012-04-11 N. E. Zein , S. Y. Savrasov , G. Kotliar

We derive and implement symmetry-projected Hartree-Fock-Bogoliubov (HFB) equations and apply them to the molecular electronic structure problem. All symmetries (particle number, spin, spatial, and complex conjugation) are deliberately…

Strongly Correlated Electrons · Physics 2012-02-15 Gustavo E. Scuseria , Carlos A. Jimenez-Hoyos , Thomas M. Henderson , Kousik Samanta , Jason K. Ellis

An energy functional for orbital based $O(N)$ calculations is proposed, which depends on a number of non orthogonal, localized orbitals larger than the number of occupied states in the system, and on a parameter, the electronic chemical…

mtrl-th · Physics 2016-09-07 Jeongnim Kim , Francesco Mauri , Giulia Galli

We propose a new, alternative method for ab-initio calculations of the electronic structure of solids, which has been specifically adapted to treat many-body effects in a more rigorous way than many existing ab-initio methods. We start from…

Condensed Matter · Physics 2007-05-23 I. Schnell , G. Czycholl , R. C. Albers

A new reference state for density functional theory, termed the independent atom ansatz, is introduced in this work. This ansatz allows for the exact representation of electron density in terms of non-interacting, atom-localized orbitals.…

Chemical Physics · Physics 2024-05-03 Alexander V. Mironenko

First-principles descriptions of correlated quantum materials require a simultaneous treatment of strong local many-body effects and nonlocal dynamical screening. We present an efficient fully self-consistent implementation of $GW$+EDMFT…

Strongly Correlated Electrons · Physics 2026-03-16 Chia-Nan Yeh , Francesco Petocchi , Alexander Hampel , Philipp Werner , Olivier Parcollet , Antoine Georges , Miguel Morales

We build a new mathematical model of shape optimization for maximizing ionic concentration governed by the multi-physical coupling steady-state Poisson-Nernst-Planck system. Shape sensitivity analysis is performed to obtain the Eulerian…

Optimization and Control · Mathematics 2025-05-13 Jiajie Li , Shenggao Zhou , Shengfeng Zhu

We review a recent approach for the simulation of many-body interacting systems based on an efficient generalization of the Lanczos method for Quantum Monte Carlo simulations. This technique allows to perform systematic corrections to a…

Strongly Correlated Electrons · Physics 2007-05-23 Sandro Sorella

In this work we explore the performance of a recently derived many-body effective energy theory for the calculation of photoemission spectra in the regime of strong electron correlation. We apply the theory to paramagnetic MnO, FeO, CoO,…

Strongly Correlated Electrons · Physics 2019-03-25 S. Di Sabatino , J. A. Berger , P. Romaniello

This paper proposes a new class of mass or energy conservative numerical schemes for the generalized Benjamin-Ono (BO) equation on the whole real line with arbitrarily high-order accuracy in time. The spatial discretization is achieved by…

Numerical Analysis · Mathematics 2021-08-31 Kai Yang

We present a first-principle numerical study of charge transport in a realistic two-dimensional tight-binding model of organic molecular semiconductors. We use the Hybrid Monte Carlo (HMC) algorithm to simulate the full quantum dynamics of…

Materials Science · Physics 2024-09-12 Johann Ostmeyer , Tahereh Nematiaram , Alessandro Troisi , Pavel Buividovich

The success of analytic waveform modeling within the effective-one-body (EOB) approach relies on the precise understanding of the physical importance of each technical element included in the model. The urgency of constructing progressively…

General Relativity and Quantum Cosmology · Physics 2023-12-12 Alessandro Nagar , Piero Rettegno , Rossella Gamba , Simone Albanesi , Angelica Albertini , Sebastiano Bernuzzi

The recently developed localized orbital scaling correction (LOSC) method shows the ability to systematically and size-consistently reduce the delocalization error existing in conventional density functional approximations (DFAs). Applying…

Chemical Physics · Physics 2020-10-19 Yuncai Mei , Zehua Chen , Weitao Yang

Extending many-body numerical techniques which are powerful in the context of simple model calculations to the realm of realistic material simulations can be a challenging task. Realistic systems often involve multiple active orbitals,…

Strongly Correlated Electrons · Physics 2025-07-23 Jonas B. Profe , Jiawei Yan , Karim Zantout , Philipp Werner , Roser Valentí

This paper proposes a charge-conserving, variational, spatio-temporal discretization for the drift-kinetic Vlasov-Maxwell system, utilizing finite-elements for the electromagnetic fields and the particle-in-cell approach for the Vlasov…

Plasma Physics · Physics 2019-10-09 Eero Hirvijoki

We introduce an efficient method to construct optimal and system adaptive basis sets for use in electronic structure and quantum Monte Carlo calculations. The method is based on an embedding scheme in which a reference atom is singled out…

Strongly Correlated Electrons · Physics 2016-02-02 Sandro Sorella , Nicolas Devaux , Mario Dagrada , Guglielmo Mazzola , Michele Casula

We present a simple, robust and highly efficient method for optimizing all parameters of many-body wave functions in quantum Monte Carlo calculations, applicable to continuum systems and lattice models. Based on a strong zero-variance…

Other Condensed Matter · Physics 2009-11-11 C. J. Umrigar , Julien Toulouse , Claudia Filippi , S. Sorella , R. G. Hennig