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We investigate theoretically charge ordered states on the anisotropic triangular lattice characteristic of the theta-(BEDT-TTF)_2 X materials. Using exact diagonalization studies, we establish that the charge order (CO) pattern corresponds…

Strongly Correlated Electrons · Physics 2009-11-07 R. T. Clay , S. Mazumdar , D. K. Campbell

We report observation of substantial thermal relaxation in single crystal of charge ordered system Pr$_{0.63}$Ca$_{0.37}$MnO$_3$ in an applied magnetic field of H = 8T. The relaxation is observed when the temperature is scanned in presence…

Strongly Correlated Electrons · Physics 2009-10-31 A. K. Raychaudhuri , Ayan Guha , I. Das , R. Rawat , C. N. R. Rao

We show that in mixed-valence 3d transition metal oxides undergoing a structural transition, the low temperature phase results from an effective ordering of the charge. This arrangement and the quantitative evaluation of the atomic charges…

Materials Science · Physics 2007-05-23 Y. Joly , S. Grenier , J. E. Lorenzo

Phase diagram of Na$_x$CoO$_2$ (x $\gtrsim$ 0.71) has been reinvestigated using electrochemically fine tuned single crystals. Both phase separation and staging phenomena as a result of sodium multi-vacancy cluster ordering have been found.…

Strongly Correlated Electrons · Physics 2009-07-13 G. J. Shu , F. -T. Huang , M. -W. Chu , J. -Y. Lin , Patrick A. Lee , F. C. Chou

Clarifying the underlying mechanisms that govern ordering transitions in condensed matter systems is crucial for comprehending emergent properties and phenomena. While transitions are often classified as electronically driven or…

We study the temperature dependence as well as anisotropy of optical conductivity ($\sigma_1$) in the pseudocubic single crystal Pr$_{0.5}$Ca$_{1.5}$MnO$_{4}$ using spectrocopic ellipsometry. Three transition temperatures are observed and…

The presence of strong disorder can significantly impact electrical conduction in metallic systems. Here, we investigate the temperature dependence of the electrical resistivity, $\rho(T)$, in nonmagnetic single crystals of the…

Materials Science · Physics 2026-02-27 Juliana Gonçalves Dias , Shyam Sundar , Leticie Mendonça-Ferreira , Marcos A. Avila

The coupling of spin, charge and lattice degrees of freedom results in the emergence of novel states of matter across many classes of strongly correlated electron materials. A model example is unconventional superconductivity, which is…

Based on a two-dimensional extended Hubbard model with electron-phonon interaction, we have studied the effect of polaron formation on the charge ordering (CO) transition. It is found that for fully ferromagnetically ordered spins the CO…

Strongly Correlated Electrons · Physics 2009-10-31 Qingshan Yuan , Peter Thalmeier

Single Crystals of Nd$_{1-x}$Ca$_{1+x}$MnO$_{4}$ have been prepared by the travelling floating-zone method, and possible evidence of a charge -orbital density wave in this material presented earlier [PRB68,092405 (2003)] using High…

Strongly Correlated Electrons · Physics 2009-11-11 Sher Alam , A. T. M. N. Islam , T. Nagai , M. Xu , Y. Matsui , I. Tanaka

Complex electronic matter exhibit subtle forms of self organization which are almost invisible to the available experimental tools, but which have dramatic physical consequences. One prominent example is provided by the actinide based heavy…

Strongly Correlated Electrons · Physics 2015-05-13 Kristjan Haule , Gabriel Kotliar

Charge disproportionation (CD) and spin differentiation in Na$_{1/2}$CoO$_2$ are studied using the correlated band theory approach. The simultaneous CD and gap opening seen previously is followed through a first order charge…

Strongly Correlated Electrons · Physics 2007-05-23 K. -W. Lee , J. Kunes , P. Novak , W. E. Pickett

$^{59}$Co NMR experiments have been performed on single crystals of the layered cobaltate Na$_{x}$CoO$_{2}$ with x=0.77 which is an antiferromagnet with N\'eel temperature $T_{N}=22$~K. In this metallic phase six Co sites are resolved in…

Strongly Correlated Electrons · Physics 2014-10-07 I. R. Mukhamedshin , A. V. Dooglav , S. A. Krivenko , H. Alloul

The transmission electron microscopy observations of the charge ordering (CO) which governs the electronic polarization in LuFe2O4-x clearly show the presence of a remarkable phase separation at low temperatures. Two CO ground states are…

Strongly Correlated Electrons · Physics 2015-05-14 H. X. Yang , H. F. Tian , Y. Zhang , Y. B. Qin , L. J. Zeng , C. Ma , H. L. Shi , J. B. Lu , J. Q. Li

We present a detailed study of the temperature evolution of the crystal structure, specific heat, magnetic susceptibility and resistivity of single crystals of the paradigmatic valence-fluctuating compound EuIr$_2$Si$_2$. A comparison to…

Strongly Correlated Electrons · Physics 2019-09-04 Silvia Seiro , Yurii Prots , Kurt Kummer , Helge Rosner , Raúl Cardoso Gil , Christoph Geibel

We investigated temperature (T)- and magnetic field-dependent optical conductivity spectra (\s\w) of a La_5/8-yPr_yCa_3/8MnO_3 (y~0.35) single crystal, showing intriguing phase coexistence at low T. At T_C < T < T_CO, a dominant…

Strongly Correlated Electrons · Physics 2009-11-07 H. J. Lee , K. H. Kim , M. W. Kim , T. W. Noh , B. G. Kim , T. Y. Koo , S. -W. Cheong , Y. J. Wang , X. Wei

Single crystals of Ca$_3$(Ir$_{1-x}$Rh$_x$)$_4$Sn$_{13}$ (3-4-13) were synthesized by flux growth and characterized by X-ray diffraction, EDX, magnetization, resistivity and radio frequency magnetic susceptibility tunnel diode resonator…

Synchrotron X-ray diffraction investigations of two single crystals of Na_xCoO_2 from different batches with composition x = 0.525-0.530 reveal homogeneous incommensurate sodium ordering with propagation vector (0.53 0.53 0) at…

Strongly Correlated Electrons · Physics 2010-07-16 R. Feyerherm , E. Dudzik , S. Valencia , A. U. B. Wolter , C. J. Milne , S. Landsgesell , D. Alber , D. N. Argyriou

At ambient temperatures, CeRuSn exhibits an extraordinary structure with a coexistence of two types of Ce ions in a metallic environment, namely trivalent Ce3+ and intermediate valent Ce(4-x)+. Charge ordering produces a doubling of the…

Strongly Correlated Electrons · Physics 2012-02-24 R. Feyerherm , E. Dudzik , S. Valencia , J. A. Mydosh , Y. -K. Huang , W. Hermes , R. Pöttgen

Structural phase transitions often couple to magnetic and electronic degrees of freedom, enabling emergent phenomena in solids. In high-entropy oxides (HEOs), which typically stabilize in highly symmetric cubic phases, such transitions are…