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BaMF4 (M=Fe, Co, Ni and Mn) family are typical multiferroic materials, having antiferromagnetism at around liquid nitrogen temperature. In this work, polycrystalline BaFeF4 has been prepared by solid state reaction. The slight deficiency of…

Perovskite metal-organic frameworks (MOFs) have recently emerged as potential candidates for multiferroicity. However, the compounds synthesized so far possess only weak ferromagnetism and low polarization. Additionally, the very low…

Materials Science · Physics 2018-01-24 Paresh Chandra Rout , Varadharajan Srinivasan

Magnetoelectric multiferroic materials, particularly with the perovskite structure, are receiving a lot of attention because of their inherent coupling between electrical polarization and magnetic ordering. However, very few types of direct…

Applied Physics · Physics 2017-09-07 Hong Jian Zhao , M. N. Grisolia , Yurong Yang , Jorge Iniguez , M. Bibes , Xiang Ming Chen , L. Bellaiche

The promise of a strong magnetoelectric coupling in a multiferroic material is not only of fundamental interest, but also forms the basis of next generation memory devices where the direction of magnetization can be reversed by an external…

Materials Science · Physics 2025-04-03 Urmimala Dey , Emma E. McCabe , Jorge Íñiguez-González , Nicholas C. Bristowe

BiFeO$_3$ is the most famous multiferroic material, but it has no strong spontaneous magnetization due to its antiferromagnetism. Here we show that giant ferroelectric polarization and strong spontaneous magnetization can be both realized…

Materials Science · Physics 2019-06-13 Peng Chen , Bang-Gui Liu

Synthesis and extensive structural, pyroelectric, magnetic, dielectric and magneto-electric characterizations are reported for polycrystalline Co4Nb2O9 towards unraveling the multiferroic state especially in reference to the magnetic spin…

Materials Science · Physics 2016-12-07 P. Srivastava , S. Chaudhary , J. Saha , S. Patnaik

We describe the design of a new magnetic ferroelectric with large spontaneous magnetization and polarization using first-principles density functional theory. The usual difficulties associated with the production of robustly-insulating…

Materials Science · Physics 2011-11-09 Pio Baettig , Nicola Spaldin

Multiferroic BaMnF$_4$ powder were prepared by hydrothermal method. Hysteretic field dependent magnetization curve at 5 K confirms the weak ferromagnetism aroused from the canted antiferromagnetic spins by magnetoelectric coupling. The…

Materials Science · Physics 2015-12-18 Shuang Zhou , Ji Wang , Xiaofeng Chang , Shuangbao Wang , Bin Qian , Zhida Han , Qingyu Xu , Jun Du , Peng Wang , Shuai Dong

Multiferroics where at least two primary ferroic orders are present and coupled in a single system constitute an important class of materials. They attracted special consideration as they present both intriguing fundamental physics problems…

The bulk photovoltaic effect (BPVE), arising from broken inversion symmetry in ferroelectrics, offers a distinct pathway toward high-efficiency next-generation photovoltaics. We propose and investigate A/A$^\prime$-ordered double…

Materials Science · Physics 2025-11-11 Sathiyamoorthy Buvaneswaran , Trilochan Sahoo , Saurabh Ghosh

We report for the first time, that Fe3Se4 is a room temperature, type-II multiferroic with magnetoelectric coupling. We observed the coexistence of coupled ferrimagnetic and ferroelectric ordering in Fe3Se4nanorods well above room…

Strongly Correlated Electrons · Physics 2019-06-13 Mousumi Sen Bishwas , Pankaj Poddar

We report electric polarization and magnetization measurements in single crystals of double perovskite Lu2MnCoO6 using pulsed magnetic fields and optical second harmonic generation (SHG) in DC magnetic fields. we observe well-resolved…

Materials Science · Physics 2016-06-22 S. Chikara , J. Singleton , J. Bowlan , D. A. Yarotski , N. Lee , H. Y. Choi , Y. J. Choi , V. S. Zapf

We present a detailed study of complex dielectric constant and ferroelectric polarization in multiferroic LiCuVO4 as function of temperature and external magnetic field. In zero external magnetic field, spiral spin order with an ab helix…

Strongly Correlated Electrons · Physics 2008-04-15 F. Schrettle , S. Krohns , P. Lunkenheimer , J. Hemberger , N. Büttgen , H. -A. Krug von Nidda , A. V. Prokofiev , A. Loidl

The spin-driven component of electric polarization in a single crystal of multiferroic BiFeO$_{3}$ was experimentally investigated in pulsed high magnetic fields up to 41 T. Sequential measurements of electric polarization for various…

Strongly Correlated Electrons · Physics 2020-01-08 Shiro Kawachi , Shin Miyahara , Toshimitsu Ito , Atsushi Miyake , Nobuo Furukawa , Jun-ichi Yamaura , Masashi Tokunaga

A dielectric anomaly has been found near the incommensurate to commensurate antiferromagnetic phase transition (TN2=230 K) in YBaCuFeO5 ceramics, a compound which crystallizes in an ordered perovskite structure. The existence of electric…

Materials Science · Physics 2009-03-13 B. Kundys , A. Maignan , Ch. Simon

In the last decades, multifunctional single-crystals that show, for example, multiferroic and magnetoelectric responses have attracted considerable attention due to the potential applications and physical phenomena involved in the…

Materials Science · Physics 2024-06-10 W. Ibarra-Hernández , A. Bautista-Hernández , A. C. Garcia-Castro

Numerous authors have referred to room-temperature magnetic switching of large electric polarizations as The Holy Grail of magnetoelectricity.We report this long-sought effect using a new physical process of coupling between magnetic and…

Materials Science · Physics 2009-02-24 Ashok Kumar , G. L. Sharma , R. S. Katiyar R. Pirc , R. Blinc J. F. Scott

From lithium-ion batteries to high-temperature superconductors, oxide materials have been widely used in electronic devices. However, demands of future technologies require materials beyond oxides, as anion chemistries distinct from oxygen…

We report $\alpha$-Cu$_2$V$_2$O$_7$ to be an improper multiferroic with the simultaneous development of electric polarization and magnetization below $T_C$ = 35 K. The observed spontaneous polarization of magnitude 0.55 $\mu$Ccm$^{-2}$ is…

Strongly Correlated Electrons · Physics 2015-06-26 J. Sannigrahi , S. Bhowal , S. Giri , S. Majumdar , I. Dasgupta

Type-II multiferroics, where spin interactions induce a ferroelectric polarization, are interesting for new device functionalities due to large magnetoelectric coupling. We report on a new type of multiferroicity in the quadruple-perovskite…

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