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We present an analytic proof demonstrating the equivalence between the Random Phase Approximation (RPA) to the ground state correlation energy and a ring-diagram simplification of the Coupled Cluster Doubles (CCD) equations. In the CCD…

Other Condensed Matter · Physics 2009-11-13 Gustavo E. Scuseria , Thomas M. Henderson , Danny C. Sorensen

We revisit the connection between equation-of-motion coupled cluster (EOM-CC) and random phase approximation (RPA) explored recently by Berkelbach [J. Chem. Phys. 149, 041103 (2018)] and unify various methodological aspects of these diverse…

Chemical Physics · Physics 2020-12-17 Varun Rishi , Ajith Perera , Rodney J. Bartlett

It is well known that the ground-state correlation energy from the particle-hole channel of the random phase approximation (RPA) is formally equivalent to that from a simplified coupled cluster doubles (CCD) model that includes only ring…

Chemical Physics · Physics 2026-04-10 A. Eugene DePrince , Stephen H. Yuwono , Henk Eshuis

We present an analytical proof and numerical demonstrations of the equivalence of the correlation energy from particle-particle random phase approximation (pp-RPA) and ladder-couple-cluster-doubles (ladder-CCD). These two theories reduce to…

Chemical Physics · Physics 2013-11-01 Degao Peng , Stephan N. Steinmann , Helen van Aggelen , Weitao Yang

The random phase approximation (RPA) for the electron correlation energy, combined with the exact-exchange energy, represents the state-of-the-art exchange-correlation functional within density-functional theory (DFT). However, the standard…

Other Condensed Matter · Physics 2015-05-20 Xinguo Ren , Patrick Rinke , Alexandre Tkatchenko , Matthias Scheffler

The self-consistent random phase approximation (RPA) based on a correlated realistic nucleon-nucleon interaction is used to evaluate correlation energies in closed-shell nuclei beyond the Hartree-Fock level. The relevance of contributions…

Nuclear Theory · Physics 2007-05-23 C. Barbieri , N. Paar , R. Roth , P. Papakonstantinou

The random phase approximation (RPA) for the correlation energy functional of density functional theory has recently attracted renewed interest. Formulated in terms of the Kohn-Sham (KS) orbitals and eigenvalues, it promises to resolve some…

Other Condensed Matter · Physics 2009-11-13 Hong Jiang , Eberhard Engel

The random-phase approximation (RPA) as an approach for computing the electronic correlation energy is reviewed. After a brief account of its basic concept and historical development, the paper is devoted to the theoretical formulations of…

Materials Science · Physics 2017-07-26 Xinguo Ren , Patrick Rinke , Christian Joas , Matthias Scheffler

Random Phase Approximation (RPA) is the theory most commonly used to describe the excitations of many-body systems. In this article, the secular equations of the theory are obtained by using three different approaches: the equation of…

Nuclear Theory · Physics 2023-03-14 Giampaolo Co'

The effects of the correlations in the ground state of $^{16}$O on the octupole and dipole excitations are studied using the extended random phase approximation (ERPA) derived from the time-dependent density-matrix theory. It is found that…

Nuclear Theory · Physics 2015-06-15 Mitsuru Tohyama

The random-phase approximation to the ground state correlation energy (RPA) in combination with exact exchange (EX) has brought Kohn-Sham (KS) density functional theory one step closer towards a universal, "general purpose first principles…

The matrix equations of the random-phase approximation (RPA) are derived for the point-coupling Lagrangian of the relativistic mean-field (RMF) model. Fully consistent RMF plus (quasiparticle) RPA illustrative calculations of the isoscalar…

Nuclear Theory · Physics 2009-11-11 T. Niksic , D. Vretenar , P. Ring

We explore different variants of the random phase approximation (RPA) to the correlation energy derived from closed-shell ring-diagram approximations to coupled cluster doubles theory. We implement these variants in range-separated…

Chemical Physics · Physics 2011-09-01 Julien Toulouse , Wuming Zhu , Andreas Savin , Georg Jansen , János G. Angyán

We present an approximation scheme for the calculation of the principal excitation energies and transition moments of finite many-body systems. The scheme is derived from a first order approximation to the self energy of a recently proposed…

Chemical Physics · Physics 2009-10-30 Joachim Brand , Lorenz S. Cederbaum

Mixing single and triple fermions an exact killing operator of the Coupled Cluster Doubles (CCD) wave function with good symmetry was found in \cite{Tohy13}. Using these operators with the equation of motion (EOM) method the so-called…

Nuclear Theory · Physics 2020-10-26 Mohsen Jemaï , Peter Schuck

We derive the coupled-cluster doubles (CCD) amplitude equations by introduction of the particle-hole-time decoupled electronic self-energy. The resulting analysis leads to an expression for the ground state correlation energy that is…

Strongly Correlated Electrons · Physics 2025-09-09 Christopher J. N. Coveney

Relativistic Continuum Random Phase Approximation (CRPA) is used to investigate collective excitation phenomena in several spherical nuclei along the periodic table. We start from relativistic mean field calculations based on a covariant…

Nuclear Theory · Physics 2011-03-21 J. Daoutidis , P. Ring

We develop a scheme to exactly evaluate the correlation energy in the random-phase approximation, based on linear response theory. It is demonstrated that our formula is completely equivalent to a contour integral representation recently…

Nuclear Theory · Physics 2009-10-31 Y. R. Shimizu , P. Donati , R. A. Broglia

Double excitations are crucial to understanding numerous chemical, physical, and biological processes, but accurately predicting them remains a challenge. In this work, we explore the particle-particle random phase approximation (ppRPA) as…

Chemical Physics · Physics 2024-11-26 Jincheng Yu , Jiachen Li , Tianyu Zhu , Weitao Yang

We perform Random Phase Approximation (RPA) study of collective excitations in the bose-fermi mixed degenerate gas of Alkali-metal atoms at T=0. The calculation is done by diagonalization in a model space composed of particle-hole type…

Condensed Matter · Physics 2009-11-07 T. Sogo , T. Miyakawa , T. Suzuki , H. Yabu
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