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We study the evaporation-induced stratification of a mixture of short and long polymer chains in a drying droplet using molecular simulations. We systematically investigate the effects of hydrodynamic interactions (HI) on this process by…

Soft Condensed Matter · Physics 2020-08-26 Michael P. Howard , Arash Nikoubashman

In drying liquid films of polymer-colloid mixtures, the stratification in which polymers are placed on top of larger colloids is studied. It is often presumed that the formation of segregated polymer-colloid layers is solely due to the…

Soft Condensed Matter · Physics 2020-03-12 Kyoungmun Lee , Siyoung Q. Choi

Large scale molecular dynamics simulations are used to study drying suspensions of a binary mixture of large and small particles in explicit and implicit solvents. The solvent is first modeled explicitly and then mapped to a uniform viscous…

Soft Condensed Matter · Physics 2019-06-12 Yanfei Tang , Gary S. Grest , Shengfeng Cheng

In simulations and experiments, we study the drying of films containing mixtures of large and small colloidal particles in water. During drying, the mixture stratifies into a layer of the larger particles at the bottom with a layer of the…

Hydrodynamic forces may significantly affect the motion of polymers. In sheet-like cavities, such as the cell's cytoplasm and microfluidic channels, the hydrodynamic forces are long-range. It is therefore expected that that hydrodynamic…

Soft Condensed Matter · Physics 2010-08-04 Tsvi Tlusty

In dense colloids it is commonly assumed that hydrodynamic interactions do not play a role. However, a found theoretical quantification is often missing. We present computer simulations that are motivated by experiments where a large…

Soft Condensed Matter · Physics 2015-06-03 Rudolf Weeber , Jens Harting

I model the drying of a liquid film containing small and big colloid particles. Fortini et al. [A. Fortini et al, Phys. Rev. Lett. 116, 118301 (2016)] studied these films with both computer simulation and experiment. They found that at the…

Soft Condensed Matter · Physics 2018-05-09 Richard P Sear

The effect of hydrodynamic interactions on the free-solution electrophoresis of polyelectrolytes is investigated with coarse-grained molecular dynamics simulations. By comparing the results to simulations with switched-off hydrodynamic…

Soft Condensed Matter · Physics 2009-11-13 Kai Grass , Christian Holm

We study the distribution of colloidal particles confined in drying spherical droplets using both dynamic density functional theory (DDFT) and particle-based simulations. In particular, we focus on the advection-dominated regime typical of…

Soft Condensed Matter · Physics 2025-01-24 Mayukh Kundu , Kritika Kritika , Yashraj M. Wani , Arash Nikoubashman , Michael P. Howard

Recent theoretical works exploring the hydrodynamics of soft material in non-equilibrium situations are reviewed. We discuss the role of hydrodynamic interactions for three different systems: i) the deformation and orientation of…

Soft Condensed Matter · Physics 2012-03-08 Manoel Manghi , Xaver Schlagberger , Yong-Woon Kim , Roland R. Netz

We report a numerical study of the diffusiophoresis of short polymers using non-equilibrium molecular dynamics simulations. More precisely, we consider polymer chains in a fluid containing a solute which has a concentration gradient, and…

Soft Condensed Matter · Physics 2020-05-20 Simón Ramírez-Hinestrosa , Hiroaki Yoshida , Lydéric Bocquet , Daan Frenkel

This study examines the impact of turbulent mixing on horizontal density compensation in the upper ocean. A series of simulations model the role of mixing in scenarios initialized with geostrophically-adjusted compensated and uncompensated…

Atmospheric and Oceanic Physics · Physics 2019-06-25 Andrey O. Koch , Robert W. Helber , James G. Richman , Charlie N. Barron

When a liquid film of colloidal solution consisting of particles of different sizes is dried on a substrate, the colloids often stratify, where smaller colloids are laid upon larger colloids. This phenomenon is counter intuitive because…

Soft Condensed Matter · Physics 2017-03-20 Jiajia Zhou , Ying Jiang , Masao Doi

We explore the impact of hydrodynamic interactions on the conformational and dynamical properties of wet tangentially-driven active polymers using multiparticle collision dynamics simulations. By analyzing active filaments with varying…

Soft Condensed Matter · Physics 2024-10-24 Loek van Steijn , Mohammad Fazelzadeh , Sara Jabbari-Farouji

Particle-particle interactions in sedimenting systems have been investigated in the present study considering the many-body hydrodynamic and electrodynamic interactions. These interactions primarily occur in two modes: near-field and…

Fluid Dynamics · Physics 2016-05-04 Sagardip Majumder , Jayabrata Dhar , Suman Chakraborty

This article presents a comprehensive review of the Hydrodynamic Scaling Model for the dynamics of polymers in dilute and nondilute solutions. The Hydrodynamic Scaling Model differs from some other treatments of non-dilute polymer solutions…

Soft Condensed Matter · Physics 2016-07-01 George D. J. Phillies

Microswimmers often exhibit surprising patterns due to the nonequilibrium nature of their dynamics. Collectively, suspensions of microswimmers appear as a liquid whose properties set it apart from its passive counterpart. To understand the…

Soft Condensed Matter · Physics 2019-05-22 Fabian Jan Schwarzendahl , Marco G. Mazza

We consider the statics and dynamics of a flexible polymer confined between parallel plates both in the presence and absence of hydrodynamic interactions. The hydrodynamic interactions are described at the level of the fluctuating,…

Soft Condensed Matter · Physics 2012-11-01 Santtu T. T. Ollila , Colin Denniston , Mikko Karttunen , Tapio Ala-Nissila

A potential strategy for controlling stratification in a drying suspension of bidisperse particles is studied using molecular dynamics simulations. When the suspension is maintained at a constant temperature during fast drying, it can…

Soft Condensed Matter · Physics 2019-03-29 Yanfei Tang , Gary S. Grest , Shengfeng Cheng

We analyzed extensively the dynamics of polymer chains in solutions simulated with dissipative particle dynamics (DPD), with a special focus on the potential influence of a low Schmidt number of a typical DPD fluid on the simulated polymer…

Soft Condensed Matter · Physics 2009-11-11 W. Jiang , J. Huang , Y. Wang , M. Laradji
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