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A non-linear conjugate gradient optimization scheme is used to obtain excitation energies within the Random Phase Approximation (RPA). The solutions to the RPA eigenvalue equation are located through a variational characterization using a…

Materials Science · Physics 2011-11-21 Melissa J. Lucero , Anders M. N. Niklasson , Sergei Tretiak , Matt Challacombe

We present a variational Monte Carlo algorithm for estimating the lowest excited states of a quantum system which is a natural generalization of the estimation of ground states. The method has no free parameters and requires no explicit…

Computational Physics · Physics 2024-09-04 David Pfau , Simon Axelrod , Halvard Sutterud , Ingrid von Glehn , James S. Spencer

This paper presents a hybrid variational quantum algorithm that finds a random eigenvector of a unitary matrix with a known quantum circuit. The algorithm is based on the SWAP test on trial states generated by a parametrized quantum…

Quantum Physics · Physics 2025-01-14 Juan Carlos Garcia-Escartin

The variational quantum eigensolver (VQE), a variational algorithm to obtain an approximated ground state of a given Hamiltonian, is an appealing application of near-term quantum computers. The original work [A. Peruzzo et al.; \textit{Nat.…

Quantum Physics · Physics 2019-11-06 Ken M Nakanishi , Kosuke Mitarai , Keisuke Fujii

A model assuming coherent quadrupole-octupole vibrations and rotations is applied to describe non-yrast energy sequences with alternating parity in several even-even nuclei from different regions, namely $^{152,154}$Sm, $^{154,156,158}$Gd,…

Nuclear Theory · Physics 2012-03-09 N. Minkov , S. Drenska , M. Strecker , W. Scheid , H. Lenske

A new Quasiparticle Random Phase Approximation approach is presented. The corresponding ground state is variationally determined and exhibits a minimum energy. New solutions for the ground state, some with spontaneously broken symmetry, of…

Nuclear Theory · Physics 2008-11-26 F. Simkovic , M. Smotlak , A. A. Raduta

In this paper, we introduce an efficient and end-to-end quantum algorithm tailored for computing the Value-at-Risk (VaR) and conditional Value-at-Risk (CVar) for a portfolio of European options. Our focus is on leveraging quantum…

Quantum Physics · Physics 2024-06-04 Yusen Wu , Jingbo B. Wang , Yuying Li

By exploiting the invariance of the molecular Hamiltonian by a unitary transformation of the orbitals it is possible to significantly shorter the depth of the variational circuit in the Variational Quantum Eigensolver (VQE) algorithm by…

Quantum Physics · Physics 2025-09-03 Leonardo Ratini , Chiara Capecci , Leonardo Guidoni

The computation of small concise and comprehensible excited state wave functions is needed because many electronic processes occur in excited states. But since the excited energies are saddle points in the Hilbert space of wave functions,…

Chemical Physics · Physics 2016-02-04 Naoum C. Bacalis

We apply a variational method devised for the nuclear many--body problem to the 1-dimensional Hubbard--model with nearest neighbor hopping and periodic boundary conditions. The test wave function consist for each state out of a single…

Strongly Correlated Electrons · Physics 2008-11-26 K. W. Schmid , T. Dahm , J. Margueron , H. Müther

Quantum computers are a highly promising tool for efficiently simulating quantum many-body systems. The preparation of their eigenstates is of particular interest and can be addressed, e.g., by quantum phase estimation algorithms. The…

Quantum Physics · Physics 2025-08-28 Xiaoyu Liu , Benjamin F. Schiffer , Jordi Tura

The lowest order constrained variational method is applied to calculate the polarized symmetrical nuclear matter properties with the modern $AV_{18}$ potential performing microscopic calculations. Results based on the consideration of…

Nuclear Theory · Physics 2008-11-26 G. H. Bordbar , M. Bigdeli

This paper considers variational inequalities (VI) defined by the conditional value-at-risk (CVaR) of uncertain functions and provides three stochastic approximation schemes to solve them. All methods use an empirical estimate of the CVaR…

Optimization and Control · Mathematics 2022-11-16 Jasper Verbree , Ashish Cherukuri

In solid-state physics, energies of crystals are usually computed with a plane-wave discretization of Kohn-Sham equations. However the presence of Coulomb singularities requires the use of large plane-wave cut-offs to produce accurate…

Numerical Analysis · Mathematics 2023-01-02 Mi-Song Dupuy

The task of learning a quantum circuit to prepare a given mixed state is a fundamental quantum subroutine. We present a variational quantum algorithm (VQA) to learn mixed states which is suitable for near-term hardware. Our algorithm…

Determining low-energy eigenstates in electronic many-body quantum systems is a key challenge in computational chemistry and condensed-matter physics. Hybrid quantum-classical approaches, such as the Variational Quantum Eigensolver and…

Quantum Physics · Physics 2025-10-27 Hamzat A. Akande , Alexandre Perrin , Bruno Senjean , Matthieu Saubanere

Preparing Gibbs states, which describe systems in equilibrium at finite temperature, is of great importance, particularly at low temperatures. In this work, we propose a new method -- TEPID-ADAPT -- that prepares the thermal Gibbs state of…

We present a symmetry-projected configuration mixing scheme to describe ground and excited states, with well defined quantum numbers, of the two-dimensional Hubbard model with nearestneighbor hopping and periodic boundary conditions.…

Strongly Correlated Electrons · Physics 2013-06-28 R. Rodríguez-Guzmán , K. W. Schmid , Carlos A. Jiménez-Hoyos , Gustavo E. Scuseria

Variational Monte Carlo methods have recently been applied to the calculation of excited states; however, it is still an open question what objective function is most effective. A promising approach is to optimize excited states using a…

Computational Physics · Physics 2023-12-04 William A. Wheeler , Kevin G. Kleiner , Lucas K. Wagner

We introduce a novel hybrid quantum-classical algorithm for the near-term computation of expectation values in quantum systems at finite temperatures. This is based on two stages: on the first one, a mixed state approximating a fiducial…

Quantum Physics · Physics 2024-01-31 Giuseppe Clemente