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Optical frequency comparison of the 40Ca+ clock transition \nu_{Ca} (2S1/2-2D5/2, 729nm) against the 87Sr optical lattice clock transition \nu_{Sr}(1S0-3P0, 698nm) has resulted in a frequency ratio \nu_{Ca} / \nu_{Sr} = 0.957 631 202 358…

Optical spectroscopy of molecular radicals is an important tool in physical chemistry, and is a prerequisite for many experiments which use molecules for quantum science and precision measurement. However, even the simplest molecules have…

Chemical Physics · Physics 2025-05-07 Ashay N. Patel , Madison I. Howard , Timothy C. Steimle , Nicholas R. Hutzler

We report on progress towards implementing mixed ion species quantum information processing for a scalable ion trap architecture. Mixed species chains may help solve several problems with scaling ion trap quantum computation to large…

Collisions with background gas particles can shift the resonance frequencies of atoms in atomic clocks. The internal quantum states of atoms can also become entangled with their motional states due to the recoil imparted by a collision,…

Atomic Physics · Physics 2018-12-05 Amar Vutha , Tom Kirchner , Pierre Dubé

This paper describes the Light-Shift Laser-Lock (LSLL) technique, a novel method intended for compact atomic clocks that greatly simplifies the laser setup by stabilizing the pumping-laser frequency to the atoms involved in the clock,…

Atomic Physics · Physics 2024-04-23 Claudio E. Calosso , Michele Gozzelino , Filippo Levi , Salvatore Micalizio

We identify two metastable excited states in Sm$ ^{10+} $ highly charged ion as candidates for high accuracy optical clocks. Several atomic properties relevant to optical clock development are calculated using relativistic many-body…

High Energy Physics - Phenomenology · Physics 2024-09-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

We study ultranarrow $5s_{1/2}$ - $4f_{5/2}$ transitions in Nd$^{13+}$ and Sm$^{15+}$ and demonstrate that they lie in the optical region. The transitions are insensitive to external perturbations. At the same time they are sensitive to the…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

The advancement of technologies for the precise interrogation of molecules offers exciting possibilities for new studies in the realms of precision spectroscopy and quantum technologies. Experiments in these domains often address molecular…

Optics · Physics 2022-09-15 Mudit Sinhal , Anatoly Johnson , Stefan Willitsch

We excite spin-waves with spatially inhomogeneous pulses and study the resulting frequency shifts of a chip-scale atomic clock of trapped $^{87}$Rb. The density-dependent frequency shifts of the hyperfine transition simulate the s-wave…

Atomic Physics · Physics 2012-07-19 Wilfried Maineult , Christian Deutsch , Kurt Gibble , Jakob Reichel , Peter Rosenbusch

Optical clocks have garnered widespread attention due to their unparalleled precision in time-frequency standards, geodetic measurements, and fundamental physics research. Among emerging developments, highly charged ion (HCI)-based optical…

Atomic Physics · Physics 2025-04-29 Shaolong Chen , Zhiqiang Zhou , Guosheng Zhang , Jun Xiao , Yao Huang , Kelin Gao , Hua Guan

Optical atomic clocks are poised to redefine the SI second, thanks to stability and accuracy more than one hundred times better than the current microwave atomic clock standard. However, the best optical clocks have not seen their…

We present a new platform facilitating quantum logic control of polar molecular ions in a segmented ring ion trap, paving the way for precision measurements. This approach focuses on achieving near-unity state preparation and detection, as…

Atomic Physics · Physics 2023-07-27 Yan Zhou , Joshua O. Island , Matt Grau

Spectroscopy is a powerful tool for studying molecules and is commonly performed on large thermal molecular ensembles that are perturbed by motional shifts and interactions with the environment and one another, resulting in convoluted…

The mid-term fractional frequency stability of miniaturized atomic clocks can be limited by light-shift effects. In this Letter, we demonstrate the implementation of a symmetric Auto-Balanced Ramsey (SABR) interrogation sequence in a…

Atomic Physics · Physics 2022-02-23 M. Abdel Hafiz , C. Carlé , N. Passilly , J. M. Danet , C. E. Calosso , R. Boudot

We have constructed an optical clock with a fractional frequency inaccuracy of 8.6e-18, based on quantum logic spectroscopy of an Al+ ion. A simultaneously trapped Mg+ ion serves to sympathetically laser-cool the Al+ ion and detect its…

Quantum Physics · Physics 2013-05-29 C. -W. Chou , D. B. Hume , J. C. J. Koelemeij , D. J. Wineland , T. Rosenband

We experimentally demonstrate optical spectroscopy of magnetically trapped atoms on an atom chip. High resolution optical spectra of individual trapped clouds are recorded within a few hundred milliseconds. Detection sensitivities close to…

Quantum Physics · Physics 2008-09-16 A. Günther , H. Bender , A. Stibor , J. Fortágh , C. Zimmermann

Optically trapped ensembles are of crucial importance for frequency measurements and quantum memories, but generally suffer from strong dephasing due to inhomogeneous density and light shifts. We demonstrate a drastic increase of the…

We present two methods for characterization of motional-mode configurations that are generally applicable to the weak and strong-binding limit of single or multiple trapped atomic ions. Our methods are essential to realize control of the…

We have studied the general aspects of the dynamics of an ion trapped in an ideal multipolar radiofrequency trap while interacting with a dense cold atomic gas. In particular, we have explored the dynamical stability, the energy relaxation…

Atomic Physics · Physics 2025-06-27 Mateo Londoño , Javier Madroñero , Jesús Pérez-Ríos

Trapped ions in radio-frequency traps are among the leading approaches for realizing quantum computers, due to high-fidelity quantum gates and long coherence times. However, the use of radio-frequencies presents a number of challenges to…

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