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In this paper, we investigate the energy minimization model of the ensemble Kohn-Sham density functional theory for metallic systems, in which a pseudo-eigenvalue matrix and a general smearing approach are involved. We study the invariance…

Numerical Analysis · Mathematics 2022-01-19 Xiaoying Dai , Stefano de Gironcoli , Bin Yang , Aihui Zhou

We present a method to efficiently combine the computation of electron-electron and electron-phonon self-energies, which enables the evaluation of electron-phonon coupling at the $G_0W_0$ level of theory for systems with hundreds of atoms.…

Materials Science · Physics 2021-12-14 Han Yang , Marco Govoni , Arpan Kundu , Giulia Galli

With the goal of obtaining strong relaxations for binary polynomial optimization problems, we introduce the pseudo-Boolean polytope defined as the convex hull of the set of binary points satisfying a collection of equations containing…

Optimization and Control · Mathematics 2024-07-02 Alberto Del Pia , Aida Khajavirad

We start from a seven parameters (six continuous and one discrete) family of non-central exactly solvable potential in three dimensions and construct a wide class of ten parameters (six continuous and four discrete) family of rationally…

Quantum Physics · Physics 2019-08-06 Nisha Kumari , Rajesh Kumar Yadav , Avinash Khare , Bhabani Prasad Mandal

This work proposes a structure-preserving model reduction method for marginally stable linear time-invariant (LTI) systems. In contrast to Lyapunov-stability-based approaches---which ensure the poles of the reduced system remain in the open…

Dynamical Systems · Mathematics 2017-04-24 Liqian Peng , Kevin Carlberg

Pseudo-Boolean constraints are omnipresent in practical applications, and thus a significant effort has been devoted to the development of good SAT encoding techniques for them. Some of these encodings first construct a Binary Decision…

Artificial Intelligence · Computer Science 2014-01-24 Ignasi Abío , Robert Nieuwenhuis , Albert Oliveras , Enric Rodriguez-Carbonell , Valentin Mayer-Eichberger

We introduce a subexponential algorithm for geometric solving of multivariate polynomial equation systems whose bit complexity depends mainly on intrinsic geometric invariants of the solution set. From this algorithm, we derive a new…

alg-geom · Mathematics 2008-02-03 M. Giusti , J. Heintz , K. Hägele , J. E. Morais , L. M. Pardo , J. L. Montaña

This article is an introduction to a new approach to first principles electronic structure calculation. The starting point is the Hartree-Fock-Roothaan equation, in which molecular integrals are approximated by polynomials by way of Taylor…

Computational Physics · Physics 2019-07-18 Akihito Kikuchi

In this paper we propose and analyze a finite difference numerical scheme for the Poisson-Nernst-Planck equation (PNP) system. To understand the energy structure of the PNP model, we make use of the Energetic Variational Approach (EnVarA),…

Numerical Analysis · Mathematics 2020-09-18 Chun Liu , Cheng Wang , Steven M. Wise , Xingye Yue , Shenggao Zhou

Consistency between the exchange-correlation (xc) functional used during pseudopotential construction and planewave-based electronic structure calculations is important for an accurate and reliable description of the structure and…

Within the context of Supersymmetric Quantum Mechanics and its related hierarchies of integrable quantum Hamiltonians and potentials, a general programme is outlined and applied to its first two simplest illustrations. Going beyond the…

Mathematical Physics · Physics 2015-06-11 Daddy Balondo Iyela , Jan Govaerts , M. Norbert Hounkonnou

The approximate numerical method for a calculation of a quantum wave impedance in a case of a potential energy with a complicated spatial structure is considered. It was proved that the approximation of a real potential by a piesewise…

Quantum Physics · Physics 2020-10-19 O. I. Hryhorchak

The perovskite oxides are known to be susceptible to structural distortions over a long wavelength when compared to their parent cubic structures. From an ab initio simulation perspective, this requires accurate calculations including many…

Computational Physics · Physics 2022-02-16 Jack S. Baker , Tsuyoshi Miyazki , David R. Bowler

We report on a theoreticl study of the electronic structure of quasiperiodic, quasi-one-dimensional systems where fully three dimensional interaction potentials are taken into account. In our approach, the actual physical potential acting…

Condensed Matter · Physics 2009-10-28 E. Macia , F. Dominguez-Adame

The present contribution concerns the computation of energy eigenvalues of a perturbed anharmonic coulombic potential with irregular singularities using a combination of the Sinc collocation method and the double exponential transformation.…

Numerical Analysis · Mathematics 2019-01-04 M. Essaouini , B. Abouzaid , P. Gaudreau , H. Safouhi

We present a simple, yet general, end-to-end deep neural network representation of the potential energy surface for atomic and molecular systems. This methodology, which we call Deep Potential, is "first-principle" based, in the sense that…

Computational Physics · Physics 2020-07-20 Jiequn Han , Linfeng Zhang , Roberto Car , Weinan E

We derive a generalized zero-range pseudopotential applicable to all partial wave solutions to the Schroedinger equation based on a delta-shell potential in the limit that the shell radius approaches zero. This properly models all higher…

Quantum Physics · Physics 2009-11-10 Rene Stock , Andrew Silberfarb , Eric L. Bolda , Ivan H. Deutsch

The pseudoperturbative shifted-l expansion technique (PSLET) is introduced to determine nodeless states of the 2D Schrodinger equation with an arbitrary cylindrically symmetric potentials. Exact energy eigenvalues and eigenfunctions for the…

Mathematical Physics · Physics 2007-05-23 Omar Mustafa , Maen Odeh

A novel embedded atom method (EAM) potential for the Xi-phases of Al-Pd-Mn has been determined with the force-matching method. Different combinations of analytic functions were tested for the pair and transfer part. The best results are…

Materials Science · Physics 2012-02-09 Daniel Schopf , Peter Brommer , Benjamin Frigan , Hans-Rainer Trebin

An asymptotic preserving and energy stable scheme for the Euler-Poisson system under the quasineutral scaling is designed and analysed. Correction terms are introduced in the convective fluxes and the electrostatic potential, which lead to…

Numerical Analysis · Mathematics 2023-07-24 K. R. Arun , Rahuldev Ghorai , Mainak Kar