Related papers: Interstellar bromine abundance is consistent with …
Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…
Gas-phase hydroxylamine (NH$_2$OH) has recently been detected within dense clouds in the interstellar medium. However, it is also likely present within interstellar ices, as well as on the icy surfaces of outer Solar System bodies, where it…
The chemical composition of comets is frequently assumed to be directly provided by the observations of the abundances of volatile molecules in the coma. The present work aims to determine the relationship between the chemical composition…
To date, at least three comets -- 2I/Borisov, C/2016 R2 (PanSTARRS), and C/2009 P1 (Garradd) -- have been observed to have unusually high CO concentrations compared to water. We attempt to explain these observations by modeling the effect…
It is not known whether the original carriers of Earth's nitrogen were molecular ices or refractory dust. To investigate this question, we have used data and results of Herschel observations towards two protostellar sources: the high-mass…
Gas-phase complex organic molecules have been detected toward a range of high- and low-mass star-forming regions at abundances which cannot be explained by any known gas-phase chemistry. Recent laboratory experiments show that UV…
Complex organic molecules (COMs) are thought to form on icy dust grains in the earliest phase of star formation. The evolution of these COMs from the youngest Class 0/I protostellar phases toward the more evolved Class II phase is still not…
We use new Space Telescope Imaging Spectrograph (STIS) and archival Goddard High Resolution Spectrograph (GHRS) observations to study interstellar B II 1362 and O I 1355 absorption along seven sightlines. Our new column density…
Oxygen is the third most abundant element in the universe, but its chemistry in the interstellar medium is still not well understood. In order to critically examine the entire oxygen budget, we attempt here initially to estimate the…
Nitrogen-bearing complex organic molecules have been commonly detected in the gas phase but not yet in interstellar ices. This has led to the long-standing question of whether these molecules form in the gas phase or in ices. $\textit{James…
The composition of comets in the Solar System come in multiple groups thought to encode information about their formation in different regions of the outer protosolar disk. The recent discovery of the second interstellar object, 2I/Borisov,…
Comparison of their chemical compositions shows, to first order, a good agreement between the cometary and interstellar abundances. However, a complex O-bearing organic molecule, ethylene glycol (CH$_{2}$OH)$_{2}$, seems to depart from this…
Comet 2I/Borisov is the first true interstellar comet discovered. Here we present results from observational programs at two Indian observatories, 2 m Himalayan Chandra Telescope at the Indian Astronomical Observatory, Hanle (HCT) and 1.2 m…
Methane is one of the simplest stable molecules that is both abundant and widely distributed across space. It is thought to have partial origin from interstellar molecular clouds, which are near the beginning of the star formation cycle.…
Stars and planets form within cold, dark molecular clouds. In these dense regions, where starlight cannot penetrate, cosmic rays (CRs) are the dominant source of ionization -- driving interstellar chemistry(Dalgarno (2006, PNAS, 103,…
We present an extensive analysis of the gas-phase abundances and depletion behaviors of neutron-capture elements in the interstellar medium (ISM). Column densities (or upper limits to the column densities) of Ga II, Ge II, As II, Kr I, Cd…
In this study, abundances of the neutron-capture elements Rb, Sr, and Zr are derived, for the first time, in a sample of nearby M dwarfs. We focus on stars in the metallicity range -0.5<[Fe/H]<+0.3, an interval poorly explored for Rb…
We present a comprehensive survey of B abundances in diffuse interstellar clouds from HST/STIS observations along 56 Galactic sight lines. Our sample is the result of a complete search of archival STIS data for the B II resonance line at…
The isotope ratio, 85Rb/87Rb, places constraints on models of the nucleosynthesis of heavy elements, but there is no precise determination of the ratio for material beyond the Solar System. We report the first measurement of the…
Earth's carbon deficit has been an outstanding problem in our understanding of the formation of our Solar System. A possible solution would be the sublimation of carbon grains at the so-called soot line (~300 K) early in the…