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Optical measurements under externally applied stresses allow us to study the materials' electronic structure by comparing the pressure evolution of optical peaks obtained from experiments and theoretical calculations. We examine the…

Among the family of TMDs, ReS2 takes a special position, which crystalizes in a unique distorted low-symmetry structure at ambient conditions. The interlayer interaction in ReS2 is rather weak, thus its bulk properties are similar to that…

Under pressure many rare earths and actinide metals transform to a-U structure or its lower symmetry distorted forms. We have reinterpreted the diffraction data of Dabos et al for Pu (reference 4) and find that a Am IV type distorted a-U…

Materials Science · Physics 2009-11-10 S. K. Sikka

X-ray diffraction (XRD) experiments have been carried out on quartz-like GaPO4 at high pressure and room temperature. A transition to a high pressure disordered crystalline form occurs at 13.5 GPa. Slight heating using a YAG infrared laser…

Condensed Matter · Physics 2009-10-31 James Badro , Jean-Paul Itie , Alain Polian

We have performed a combined experimental and theoretical study of ethane and methane at high pressures up to 120 GPa at 300 K using x-ray diffraction and Raman spectroscopy and the USPEX ab-initio evolutionary structural search algorithm,…

Using $\textit{ab-initio}$ crystal structure prediction we study the high-pressure phase diagram of $\textit{A}BiO_3$ bismuthates ($A$=Ba, Sr, Ca) in a pressure range up to 100$~$GPa. All compounds show a transition from the low-pressure…

Strongly Correlated Electrons · Physics 2018-10-03 Andriy Smolyanyuk , Cesare Franchini , Lilia Boeri

We report high pressure Raman, synchrotron x-ray diffraction and electrical transport studies on Weyl semimetals NbP and TaP along with first-principles density functional theoretical (DFT) analysis. The frequencies of first-order Raman…

The structural phase transformations of 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (PMN-30%PT) have been studied using x-ray diffraction (XRD) and neutron scattering as a function of temperature and electric field. We observe the phase transformational…

Materials Science · Physics 2009-11-10 Feiming Bai , Naigang Wang , Jiefang Li , D. Viehland , P. M. Gehring , Guangyong Xu , G. Shirane

High pressure synthesis of rhenium nitride pernitride ReN$_2$ with crystal structure unusual for transition metal dinitrides and high values of hardness and bulk modulus attracted significant attention to this system. We investigate the…

The compression behavior of delafossite compound CuCrO2 has been investigated by in-situ x-ray diffraction and Raman spectroscopic measurements upto 23.2 and 34 GPa respectively. X-ray diffraction data shows the stability of ambient…

Materials Science · Physics 2015-06-22 Alka B. Garg , A. K. Mishra , K. K. Pandey , Surinder M. Sharma

We have investigated the structural sequence of the high-pressure phases of silicon and germanium. We have focussed on the cd->beta-tin->Imma->sh phase transitions. We have used the plane-wave pseudopotential approach to the…

Materials Science · Physics 2009-11-10 Katalin Gaal-Nagy , Pasquale Pavone , Dieter Strauch

The first experiments in dynamic rotational diamond anvil cell (dRDAC) on severe plastic deformation (SPD) and BCC<->HCP phase transformation (PT) at pressure up to 27.6 GPa, rotation rates up to 1,500 RPM, and strain rates up to 2,094 /s…

Materials Science · Physics 2025-12-03 Sorb Yesudhas , Mrinmay Sahu , Valery I. Levitas , Dean Smith , Jeffrey T. Lloyd

Synchrotron x-ray diffraction experiments have been carried out on Eu metal at ambient temperature to pressures as high as 92 GPa (0.92 Mbar). Following the well-known bcc-to-hcp transition at 12 GPa, a mixed phase region is observed from…

Materials Science · Physics 2015-05-20 W. Bi , Y. Meng , R. S. Kumar , A. L. Cornelius , W. W. Tipton , R. G. Hennig , Y. Zhang , C. Chen , J. S. Schilling

The confinement of silver selenide was investigated using mesoporous silica. Results from x-ray diffraction and electron microscopy show that the confined material still exhibits a \beta to \alpha transition similar to the one that takes…

Materials Science · Physics 2009-11-13 Vincent Leon , Yang Ren , Marie-Louise Saboungi

The temperature-dependent phase transitions in Ruddlesden-Popper oxides with perovskite bilayers have been under increased scrutiny in recent years due to the so-called hybrid improper ferroelectricity that some chemical compositions…

Materials Science · Physics 2021-12-08 Gabriel Clarke , Dominik Daisenberger , X. Luo , S. W. Cheong , Nicholas C. Bristowe , Mark S. Senn

Recent contrasting observations for halogen (X)-bridged binuclear platinum complexes R_4[Pt_2(P_2O_5H_2)_4X]nH_2O, that is, pressure-induced Peierls and reverse Peierls instabilities, are explained by finite-temperature Hartree-Fock…

Strongly Correlated Electrons · Physics 2009-11-07 Shoji Yamamoto

High pressures allow the synthesis of new metastable compounds that remain intact for a sufficiently long time at normal conditions. Until now, it has not been fully understood how pressure, glass-forming ability and solidification of…

Materials Science · Physics 2022-11-08 S. G. Menshikova , N. M. Chtchelkatchev , V. V. Brazhkin

X-ray diffraction was demonstrated from shock-compressed polycrystalline metal on nanosecond time scales. Laser ablation was used to induce shock waves in polycrystalline foils of Be, 25 to 125 microns thick. A second laser pulse was used…

Other Condensed Matter · Physics 2008-01-23 Damian C. Swift

We studied the effect of external pressure on the electrodynamic properties of $\alpha$-Li$_2$IrO$_3$ single crystals in the frequency range of the phonon modes and the Ir $d$-$d$ transitions. The abrupt hardening of several phonon modes…

Strongly Correlated Electrons · Physics 2019-06-14 V. Hermann , J. Ebad-Allah , F. Freund , A. Jesche , A. A. Tsirlin , P. Gegenwart , C. A. Kuntscher

The Fe-Mn-based alloys are receiving immense attention due to their applications in the third generation of advanced high-strength steels, owing to their high strength and ductility. A detailed in situ high-pressure structural phase…

Materials Science · Physics 2026-01-14 Mrinmay Sahu , Sorb Yesudhas , Valery I. Levitas , Dean Smith