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Strong electron-electron interactions are known to significantly modify the electron-phonon coupling relative to the predictions of density functional theory, but this effect is challenging to calculate with realistic theories of strongly…

Strongly Correlated Electrons · Physics 2025-07-21 David J. Abramovitch , Jennifer Coulter , Sophie Beck , Andrew Millis

Electron-phonon coupling in atoms and molecules adsorbed at metal surfaces gives rise to finite vibrational linewidths in infrared or electron energy loss spectra. When it is the dominant contribution to the vibrational lifetime, it…

Materials Science · Physics 2026-03-09 Nils Hertl , Connor L. Box , Reinhard J. Maurer

Time-resolved vibrational spectroscopy constitutes an invaluable experimental tool for monitoring hot-carrier induced surface reactions. However, the absence of a full understanding on the precise microscopic mechanisms causing the…

Materials Science · Physics 2019-01-14 D. Novko , J. C. Tremblay , M. Alducin , J. I. Juaristi

We present a dynamical mean-field study of the nonperturbative electronic mechanisms, which may lead to significant enhancements of the electron-phonon coupling in correlated electron systems. Analyzing the effects of electronic…

Strongly Correlated Electrons · Physics 2026-03-31 Emin Moghadas , Matthias Reitner , Tim Wehling , Giorgio Sangiovanni , Sergio Ciuchi , Alessandro Toschi

We present a perturbation approach rooted in time-dependent density-functional theory to calculate electron hole (eh)-pair excitation spectra during the non-adiabatic vibrational damping of adsorbates on metal surfaces. Our analysis for the…

Chemical Physics · Physics 2017-11-22 Simon P. Rittmeyer , Jörg Meyer , Karsten Reuter

We investigate electron-phonon coupling in a narrow suspended metallic wire, in which the phonon modes are restricted to one dimension but the electrons behave three-dimensionally. Explicit theoretical results related to the known bulk…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 F. W. J. Hekking , A. O. Niskanen , J. P. Pekola

Molecular adsorbates on metal surfaces exchange energy with substrate phonons and low-lying electron-hole pair excitations. In the limit of weak coupling, electron-hole pair excitations can be seen as exerting frictional forces on…

Materials Science · Physics 2016-09-28 Reinhard J. Maurer , Mikhail Askerka , Victor S. Batista , John C. Tully

A quantum dot molecule doped with a single electron in the presence of diagonal and off-diagonal carrier-phonon couplings is studied by means of a non-perturbative quantum kinetic theory. The interaction with acoustic phonons by deformation…

Mesoscale and Nanoscale Physics · Physics 2010-11-15 A. Grodecka-Grad , J. Förstner

We have studied the lattice dynamics, electron-phonon coupling, and superconducting properties of $\alpha$-MoB$_2$, as a function of applied pressure, within the framework of density functional perturbation theory using a mixed-basis…

Superconductivity · Physics 2023-10-31 Marco-Antonio Carmona-Galván , Rolf Heid , Omar De la Peña-Seaman

The non-equilibrium dynamics of matter excited by light may produce electronic phases that do not exist in equilibrium, such as laser-induced high-transition-temperature superconductivity. Here we simulate the dynamics of a metal driven at…

Strongly Correlated Electrons · Physics 2022-12-05 John Sous , Benedikt Kloss , Dante M. Kennes , David R. Reichman , Andrew J. Millis

In this manuscript, we provide a general theory for how surface phonons couple to molecular adsorbates. Our theory maps the extended dynamics of a surface's atomic vibrational motions to a generalized Langevin equation, and by doing so…

Chemical Physics · Physics 2024-05-03 Ardavan Farahvash , Adam P. Willard

Motivated by recent experiments, we investigate the electron-vibron coupling in suspended carbon nanotube quantum dots, starting with the electron-phonon coupling of the underlying graphene layer. We show that the coupling strength depends…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Eros Mariani , Felix von Oppen

We present a comprehensive first-principles analysis of the non-adiabatic effects due to the electron-phonon interaction on the vibrational spectrum of the electron-doped monolayer MoS$_{2}$. Deep changes in the Fermi surface upon doping…

Materials Science · Physics 2020-02-26 Peio Garcia-Goiricelaya , Jon Lafuente-Bartolome , Idoia G. Gurtubay , Asier Eiguren

We use the dynamical mean field theory to develop a systematic and computationally tractable method for studying electron-phonon interactions in systems with arbitrary electronic correlations. The method is formulated as an adiabatic…

Strongly Correlated Electrons · Physics 2009-10-31 A. Deppeler , A. J. Millis

Coupling between electrons and phonons (lattice vibrations) drives the formation of the electron pairs responsible for conventional superconductivity. The lack of direct evidence for electron-phonon coupling in the electron dynamics of the…

Radio-frequency compressed ultrafast electron diffraction has been used to probe the coherent and incoherent coupling of impulsive electronic excitation at 1.55 eV (800 nm) to optical and acoustic phonon modes directly from the perspective…

Materials Science · Physics 2015-06-23 Robert P. Chatelain , Vance R. Morrison , Bart L. M. Klarenaar , Bradley J. Siwick

The dispersion of the in-plane Cu-O bond-stretching LO phonon mode in the high-$T_{C}$ superconducting cuprates shows strong softening with doping near the zone boundary. We suggest that it can be described with a negative electronic…

Superconductivity · Physics 2009-11-07 Masashi Tachiki , Masahiko Machida , Takeshi Egami

The coupling between electrons and phonons is at the heart of many fundamental phenomena in physics. In nature, this coupling is generally predetermined for both, molecules and solids. Tremendous advances have been made in controlling…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Avishai Benyamini , Assaf Hamo , Silvia Viola Kusminskiy , Felix von Oppen , Shahal Ilani

We propose a mechanism of energy relaxation for carriers confined in a non-polar quantum dot surrounded by an amorphous polar environment. The carrier transitions are due to their interaction with the oscillating electric field induced by…

Mesoscale and Nanoscale Physics · Physics 2008-08-08 A. N. Poddubny , S. V. Goupalov , V. I. Kozub , I. N. Yassievich

The equilibration of electronic carriers in metals after excitation by an ultra-short laser pulse provides an important class of non-equilibrium phenomena in metals and allows measuring the effective electron-phonon coupling parameter.…

Materials Science · Physics 2022-10-06 Peter Kratzer , Laurenz Rettig , Irina Yu. Sklyadneva , Evgueni V. Chulkov , Uwe Bovensiepen
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