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Molecular adsorbates on metal surfaces exchange energy with substrate phonons and low-lying electron-hole pair excitations. In the limit of weak coupling, electron-hole pair excitations can be seen as exerting frictional forces on…

Materials Science · Physics 2016-09-28 Reinhard J. Maurer , Mikhail Askerka , Victor S. Batista , John C. Tully

Nonadiabatic effects that arise from the concerted motion of electrons and atoms at comparable energy and time scales are omnipresent in thermal and light-driven chemistry at metal surfaces. Excited (hot) electrons can measurably affect…

Materials Science · Physics 2020-12-10 Connor L. Box , Yaolong Zhang , Rongrong Yin , Bin Jiang , Reinhard J. Maurer

Nonadiabatic molecular dynamics simulations aim to describe the coupled electron-nuclear dynamics of molecules in excited electronic states. These simulations have been applied to understand a plethora of photochemical and photophysical…

We develop a scattering theory of current-induced forces exerted by the conduction electrons of a general mesoscopic conductor on slow "mechanical" degrees of freedom. Our theory describes the current-induced forces both in and out of…

Mesoscale and Nanoscale Physics · Physics 2011-07-12 Niels Bode , Silvia Viola Kusminskiy , Reinhold Egger , Felix von Oppen

In the mechanics of inviscid conservative fluids, it is classical to generate the equations of dynamics by formulating with adequate variables, that the pressure integral calculated in the time-space domain corresponding to the motion of…

Classical Physics · Physics 2008-07-23 Henri Gouin , Jean-François Debieve

The stability of molecular junctions under transport is of the utmost importance for the field of molecular electronics. This question is often addressed within the paradigm of current-induced heating of nuclear degrees of freedom or…

Mesoscale and Nanoscale Physics · Physics 2022-12-26 André Erpenbeck , Yaling Ke , Uri Peskin , Michael Thoss

The phenomenon of so-called break-away forces, as maximal actuation forces at which a sticking system begins to slide and thus passes over to a steady (macro) motion, is well known from engineering practice but still less understood in its…

Systems and Control · Computer Science 2017-04-13 Michael Ruderman

Molecules in molecular junctions are subject to current-induced forces that can break chemical bonds, induce reactions, destabilize molecular geometry, and halt the operation of the junction. Theories behind current-driven molecular…

Mesoscale and Nanoscale Physics · Physics 2023-01-04 Riley J. Preston , Thomas D. Honeychurch , Daniel S. Kosov

The interaction of metal-molecule-metal junctions with light is considered within a simple generic model. We show, for the first time, that light induced current in unbiased junctions can take place when the bridging molecule is…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan

The friction coefficient of fluids may become a function of the velocity at increased external driving. This non-Newtonian behavior is of general theoretical interest as well as of great practical importance, e.g., for the design of…

Soft Condensed Matter · Physics 2022-05-03 Matthias Post , Steffen Wolf , Gerhard Stock

Quantum friction, the electromagnetic fluctuation-induced frictional force decelerating an atom which moves past a macroscopic dielectric body, has so far eluded experimental evidence despite more than three decades of theoretical studies.…

Quantum Physics · Physics 2017-06-28 J. Klatt , M. B. Farias , D. A. R. Dalvit , S. Y. Buhmann

We present an overview of current-induced effects in nanoscale conductors with emphasis on their description at the atomic level. In particular, we discuss steady-state current fluctuations, current-induced forces, inelastic scattering and…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Neil Bushong , Massimiliano Di Ventra

Stress tensors are derived for the multiparticle collision dynamics algorithm, a particle-based mesoscale simulation method for fluctuating fluids, resembling those of atomistic or molecular systems. Systems with periodic boundary…

Soft Condensed Matter · Physics 2009-11-13 Roland G. Winkler , Chien-Cheng Huang

The effect of nonlinear friction forces in quantum mechanics is studied via dissipative Madelung hydrodynamics. A new thermo-quantum diffusion equation is derived, which is solved for the particular case of quantum Brownian motion with a…

Quantum Physics · Physics 2013-03-12 Roumen Tsekov

Electromagnetic fluctuation-induced forces between atoms and surfaces are generally known as Casimir-Polder interactions. The exact knowledge of these forces is rapidly becoming important in modern experimental set-ups and for technological…

Quantum Physics · Physics 2011-09-28 F. Intravaia , C. Henkel , M. Antezza

The mechanical properties within living cells play a critical role in the adaptive regulation of their biological functions upon environmental and internal stimuli. While these properties exhibit nonequilibrium dynamics due to the thermal…

Biological Physics · Physics 2024-08-14 Yuika Ueda , Shinji Deguchi

Energy transfer during molecular collisions on metal surfaces plays a pivotal role in a host of critical interfacial processes. Despite significant efforts, our understanding of relevant energy transfer mechanisms, even in an…

Chemical Physics · Physics 2025-03-24 Gang Meng , Bin Jiang

Theoretical approaches to nonequilibrium many-body dynamics generally rest upon an adiabatic assumption, whereby the true dynamics is represented as a sequence of equilibrium states. Going beyond this simple approximation is a notoriously…

Soft Condensed Matter · Physics 2014-10-15 Andrea Fortini , Daniel de las Heras , Joseph M. Brader , Matthias Schmidt

An atom moving in a vacuum at constant velocity and parallel to a surface experiences a frictional force induced by the dissipative interaction with the quantum fluctuations of the electromagnetic field. We show that the combination of…

Quantum Physics · Physics 2019-09-26 F. Intravaia , M. Oelschläger , D. Reiche , D. A. R. Dalvit , K. Busch

The Casimir-Polder force is analyzed when an atom is moving at a constant velocity relative to a collection of translationally invariant macroscopic bodies with generic shapes and compositions. The interaction is described within an…

Quantum Physics · Physics 2026-02-19 D. Reiche , B. Beverungen , K. Busch , F. Intravaia