Related papers: Effects of "stuffing" on the atomic and electronic…
The lanthanide pyrochlore oxides Ln$_2$B$_2$O$_7$ are one of the most intensely studied classes of materials within condensed matter physics, firmly centered as one of the pillars of frustrated magnetism. The extensive chemical diversity of…
Pyrochlore magnets of the form $R_2B_2$O$_7$, in which rare-earth ions on the $R$-site form a three-dimensional network of corner-sharing tetrahedra, provide a canonical setting for geometrical frustration. Ho-based pyrochlores host a…
We report the filling control of the pyrochlore oxide Y2Ir2O7. Metallic ground state appears with increasing substitution content x (x >= 0.3). We have revealed that the density of states at the Fermi level rapidly changes with x by this…
In the search for topological phases in correlated electron systems, iridium-based pyrochlores A2Ir2O7 -- materials with 5d transition-metal ions -- provide fertile grounds. Several novel topological states have been predicted but the…
Although materials that exhibit nearest-neighbor-only antiferromagnetic interactions and geometrical frustration theoretically should not magnetically order in the absence of disorder, few such systems have been observed experimentally. One…
Pyrochlore oxides with chemical formula of A2B2O7 exhibit a diverse range of electronic properties as a representative family of quantum materials. These properties mostly stem from strong electron correlations at the transition metal B…
In the pyrochlore compounds, Tb$_2$Ti$_2$O$_7$ and Tb$_2$Sn$_2$O$_7$, only the Tb$^{3+}$ ions are magnetic. They exhibit quite abnormal -- and, in view of their chemical similarity, strikingly different -- magnetic behaviour, as probed by…
We study magnetic behaviour of the Yb$^{3+}$ ions on a frustrated pyrochlore lattice in the spinel {\CYS}. The crystal-electric field parameters deduced from high-energy inelastic neutron scattering reveal well-isolated ytterbium ground…
In this work we present inelastic neutron scattering experiments which probe the single ion ground states of the rare earth pyrochlores $R_2$Ti$_2$O$_7$ ($R$ = Tb, Dy, Ho). Dy$_2$Ti$_2$O$_7$ and Ho$_2$Ti$_2$O$_7$ are dipolar spin ices, now…
We present synchrotron x-ray diffraction, neutron powder diffraction and time-of-flight inelastic neutron scattering measurements on the rare earth pyrochlore oxide Nd2Zr2O7 to study the ordered state magnetic structure and cystal field…
We conduct a comprehensive \textit{ab initio} investigation of electron-electron interactions within the pyrochlore structures of R$_2$Ru$_2$O$_7$, R$_2$Ir$_2$O$_7$, Ca$_2$Ru$_2$O$_7$, and Cd$_2$Ru$_2$O$_7$, where R denotes a rare-earth…
The spin ice system Dy$_{2}$Ti$_{2}$O$_{7}$ exhibits strong frequency-dependent spin-freezing at $\sim$ 16 K temperature. Although it has been a matter of discussion for years, the origin of this unusual spin freezing is still unknown. The…
The pyrochlore antiferromagnet Tb2Ti2O7 has proven to be an enigma to experimentalists and theorists working on frustrated magnetic systems. The experimentally determined energy level structure suggests a local <111> Ising antiferromagnet…
Within the past 20 years or so, there has occurred an explosion of interest in the magnetic behavior of pyrochlore oxides of the type $A_{2}^{3+}$$B_{2}^{4+}$O$_{7}$ where $A$ is a rare-earth ion and $B$ is usually a transition metal. Both…
We report detailed measurements of the low temperature magnetic phase diagram of Er$_2$Ti$_2$O$_7$. Heat capacity and time-of-flight neutron scattering studies of single crystals, subject to magnetic fields applied along the…
Tuning of spin-orbit coupling and electron correlation effects in pyrochlore iridates is considered for many interesting phenomena. We have investigated the temperature evolution of structural, magnetic and electronic properties in doped…
We address the concomitant metal-insulator transition (MIT) and antiferromagnetic ordering in the novel pyrochlore iridate Eu2Ir2O7 by combining x-ray absorption spectroscopy, x-ray and neutron diffractions and density functional theory…
We have investigated electronic structures of antiferromagnetic YBaCo_2O_5 using the local spin-density approximation (LSDA) + U method. The charge and orbital ordered insulating ground state is correctly obtained with the strong on-site…
Neutron scattering and magnetization measurements have been performed on the stuffed pyrochlore system Tb2+xTi2-2xNbxO7. We find that despite the introduction of chemical disorder and increasingly antiferromagnetic interactions, a spin…
The family of magnetic rare-earth pyrochlore oxides R2M2O7 plays host to a diverse array of exotic phenomena, driven by the interplay between geometrical frustration and spin-orbit interaction, which leads to anisotropy in both magnetic…