Related papers: Boundary flow of viscoelastic polyelectrolyte solu…
We investigate theoretically the phase diagram of an insoluble charged surfactant monolayer in contact with a semi-dilute polyelectrolyte solution (of opposite charge). The polyelectrolytes are assumed to have long-range and attractive…
Motivated by experimental evidence of violations of the no-slip boundary condition for liquid flow in micron-scale geometries, we propose a simple, complementary experimental technique that has certain advantages over previous studies.…
The adsorption of highly \textit{oppositely} charged flexible polyelectrolytes (PEs) on a charged planar substrate is investigated by means of Monte Carlo (MC) simulations. We study in detail the equilibrium structure of the first few PE…
We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the…
This work investigates electroviscous effects in presence of charge-dependent slip in steady pressure-driven laminar flow of a symmetric (1:1) electrolyte liquid through a uniformly charged slit contraction - expansion (4:1:4) microfluidic…
We propose a detailed description of the structure of the layer formed by polyelectrolyte chains adsorbed onto an oppositely charged surface in the semi-dilute regime. We combine the mean-field Poisson-Boltzmann-Edwards theory and the…
We study experimentally the interfacial instability between a layer of dilute polymer solution and water flowing in a thin capillary. The use of microfluidic devices allows us to observe and quantify in great detail the features of the…
Polyelectrolytes under confinement are crucial for energy storage and for understanding biomolecular functions. Using molecular dynamics simulations, we analyze a polyelectrolyte solution confined between two oppositely charged planar…
The velocity and friction properties of laminar pipe flow of a viscoelastic solution are bounded by the corresponding values for two Newtonian fluids, namely, the solvent and a fluid with a viscosity identical to the total viscosity of the…
When a fluid flows past a solid surface, its macroscopic motion arises from a subtle interplay between microscopic hydrodynamic and thermodynamic effects at the fluid-solid interface. Classical hydrodynamic models often rely on an…
Thin liquid films on surfaces are part of our everyday life, they serve e.g. as coatings or lubricants. The stability of a thin layer is governed by interfacial forces, described by the effective interface potential, and has been subject of…
Controlling the motion of non-Newtonian drops on surfaces is crucial for applications ranging from inkjet printing to biomedical devices and food processing. While the macroscopic behavior of viscoelastic drops sliding on tilted hydrophobic…
We propose a two-dimensional flow model of a viscous fluid between two close moving surfaces. We show, using a formal asymptotic expansion of the solution, that its asymptotic behavior, when the distance between the two surfaces tends to…
We derive general conditions of slip of a fluid on the boundary. Under these conditions the velocity of the fluid on the immovable boundary is a function of the normal and tangential components of the force acting on the surface of the…
We present comprehensive numerical studies of the motion of a buoyant or a nearly neutrally buoyant nano-sized ellipsoidal particle in a fluid filled cylindrical tube without or with the presence of imposed pressure gradient (weak…
We propose a two-dimensional flow model of a viscous fluid between two close moving surfaces. We show that its asymptotic behavior, when the distance between the two surfaces tends to zero, is the same as that of the the Navier-Stokes…
We derive an effective boundary condition for granular flow taking into account the effect of the heterogeneity of the force network on sliding friction dynamics. This yields an intermediate boundary condition which lies in the limit…
The molecular mechanism of slip at the interface between polymer melts and weakly attractive smooth surfaces is investigated using molecular dynamics simulations. In agreement with our previous studies on slip flow of shear-thinning fluids,…
Controlling the structure of polymer solutions near a solid surface is crucial for many industrial processes, as it significantly impacts solution flow and influences slip at the interface. To date, only a few techniques have been developed…
Using self-assembly techniques, x-ray reflectivity measurements, and computer simulations, we study the effective interaction between charged polymer rods and surfaces. Long-time Brownian dynamics simulations are used to measure the…