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$\alpha$-graphyne is a two-dimensional sheet of $sp$-$sp^2$ hybridized carbon atoms in a honeycomb lattice. While the geometrical structure is similar to that of graphene, the hybridized triple bonds give rise to electronic structure that…

Materials Science · Physics 2017-08-04 Hyeondeok Shin , Jeongnim Kim , Hoonkyung Lee , Olle Heinonen , Anouar Benali , Yongkyung Kwon

Carbon nanoscroll is a unique topologically open configuration of graphene nanoribbon possessing outstanding properties and application perspectives due to its morphology. However molecular dynamics study of nanoscrolls with more than a few…

Mesoscale and Nanoscale Physics · Physics 2015-07-15 Alexander V. Savin , Elena A. Korznikova , Sergey V. Dmitriev

Single-layer and bilayer carbon and hexagonal boron nitride nanoscrolls as well as nanoscrolls made of bilayer graphene/hexagonal boron nitride heterostructure are considered. Structures of stable states of the corresponding nanoscrolls…

Graphene-based nanofolds (GNFs) are edge-connected 2D stacked monolayers originated from single-layer graphene. Graphene-based nanoscrolls (GNSs) are nanomaterials with geometry resembling graphene layers rolled up into a spiral…

Materials Science · Physics 2021-09-23 Marcelo Lopes Pereira Junior , Luiz Antonio Ribeiro Junior

Graphyne is a planar two-dimensional carbon allotrope formed by atoms in sp, sp2, and sp3 hybridized states. Topologically graphyne nanotubes (GNTs) can be considered as cylindrically rolled up graphyne sheets, similarly as carbon nanotubes…

Mesoscale and Nanoscale Physics · Physics 2015-09-30 Jose M. de Sousa , Gustavo Brunetto , Vitor R. Coluci , Douglas S. Galvao

Graphene nanoribbons are semiconductor nanostructures with great potentials in nanoelectronics. Their realization particularly with small lateral dimensions below a few nanometers, however, remains challenging. Here we theoretically analyze…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Valentina Tozzini , Vittorio Pellegrini

We report the mechanical properties of different two-dimensional carbon heterojunctions (HJs) made from graphene and various stable graphene allotropes, including {\alpha}-, {\beta}-, {\gamma}- and 6612-graphyne (GY), and graphdiyne (GDY).…

Materials Science · Physics 2015-11-12 Kang Xia , Haifei Zhan , Yuantong Gu

Recently, a new two-dimensional carbon allotrope, named biphenylene network (BPN) was experimentally realized. The BPN structure is composed of four-, six-, and eight-membered rings of sp$^2$-hybridized carbon atoms. In this work, we…

Two experimental studies reported the spontaneous formation of amorphous and crystalline structures of C60 intercalated between graphene and a substrate. They observed interesting phenomena ranging from reaction between C60 molecules under…

Mesoscale and Nanoscale Physics · Physics 2019-10-21 Alexandre F. Fonseca , Sócrates O. Dantas , Douglas S. Galvão , Difan Zhang , Susan B. Sinnott

Graphdiynes (GDYs) represent a class of 2D carbon materials based on sp-sp$^2$ hybridization with appealing properties and potential applications. Recent advances have demonstrated the experimental self-assembly of GDYs on metal substrates.…

The formation of graphen-nanotube composites addresses a few basic problems. First, both partners are good donors and acceptors of electrons, which significantly complicates the intermolecular interaction between them leading to a two-well…

Materials Science · Physics 2009-01-26 Elena F. Sheka , Leonid A. Chernozatonskii

We conducted density functional theory (DFT) and molecular dynamics simulations to explore the mechanical/failure, thermal conductivity and stability, electronic and optical properties of three N-graphdiyne nanomembranes. Our DFT results of…

Computational Physics · Physics 2018-05-14 Bohayra Mortazavi , Meysam Makaremi , Masoud Shahrokhi , Zheyong Fan , Timon Rabczuk

Graphyne is a two-dimensional carbon allotrope of graphene. Its structure is composed of aromatic rings and/or carbon-carbon bonds connected by one or more acetylene chains. As some graphynes present the most of the excellent properties of…

Materials Science · Physics 2023-03-21 Guilherme B. Kanegae , Alexandre F. Fonseca

$\gamma$-Graphyne is the most symmetric sp2/sp1 allotrope of carbon, which can be viewed as graphene uniformly expanded through insertion of two-carbon acetylenic units between all the aromatic rings. To date, synthesis of bulk…

Carbon nanoribbons (CNRs) are graphene (planar) structures with large aspect ratio. Carbon nanobelts (CNBs) are small graphene nanoribbons rolled up into spiral-like structures, i. e., carbon nanoscrolls (CNSs) with large aspect ratio. In…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 B. V. C. Martins , D. S. Galvão

Graphene-based nanostructured systems and van-der-Waals heterostructures comprise a material class of growing technological and scientific importance. Joining materials with vastly different properties, polymer-graphene heterosystems…

Soft Condensed Matter · Physics 2020-08-26 Max Gulde , Anastassia N. Rissanou , Vagelis Harmandaris , Marcus Müller , Sascha Schäfer , Claus Ropers

As a new carbon allotrope, the recently fabricated graphdiyne has attracted much attention due to its interesting two-dimensional character. Here we demonstrate by multiscale computations that, unlike graphene, graphdiyne has a natural band…

Mesoscale and Nanoscale Physics · Physics 2015-04-30 L. Sun , P. H. Jiang , H. J. Liu , D. D. Fan , J. H. Liang , J. Wei , L. Cheng , J. Zhang , J. Shi

At present, Pt nanoparticle catalysts in fuel cells suffer from aggregation and loss of chemical activity. In this work, graphdiyne, which has natural porous structure, was proposed as substrate with high adsorption ability to stabilize Pt…

Mesoscale and Nanoscale Physics · Physics 2015-03-03 Zheng-Zhe Lin

The understanding of the structural and thermal properties of membranes, low-dimensional flexible systems in a space of higher dimension, is pursued in many fields from string theory to chemistry and biology. The case of a two-dimensional…

Mesoscale and Nanoscale Physics · Physics 2013-02-08 Mikhail I. Katsnelson , Annalisa Fasolino

The behavior of nanostructures under high strain-rate conditions has been object of interest in recent years. For instance, recent experimental investigations showed that at high velocity impacts carbon nanotubes can unzip resulting into…