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We use an off-lattice microscopic model for solutions of equilibrium polymers (EP) in a lamellar shear flow generated by means of a self-consistent external field between parallel hard walls. The individual conformations of the chains are…

Soft Condensed Matter · Physics 2009-10-31 A. Milchev , J. P. Wittmer , D. P. Landau

Although the stretching of polymers and biomolecules is important in numerous settings, their response when confined to two-dimensions is relatively poorly-studied. In this paper, we derive closed-form analytical expressions for the…

Soft Condensed Matter · Physics 2013-05-28 Sara Iliafar , Dmitri Vezenov , Anand Jagota

We present exact and analytically accurate results for the problem of a flexible polymer chain in shear flow. Under such a flow the polymer tumbles, and the probability distribution of the tumbling times $\tau$ of the polymer decays…

Statistical Mechanics · Physics 2008-11-13 Dibyendu Das , Sanjib Sabhapandit

The spatial correlations of entangled polymer dynamics are examined by molecular dynamics simulations and neutron spin-echo spectroscopy. Due to the soft nature of topological constraints, the initial spatial decays of intermediate…

Auto-correlation functions in an equilibrium stochastic process are well-characterized by Bochner's theorem as Fourier transforms of a finite symmetric Borel measure. The existence of a long-time limit of these correlation functions depends…

Statistical Mechanics · Physics 2014-08-01 Thomas Franosch

We study the fluctuations of the directed polymer in 1+1 dimensions in a Gaussian random environment with a finite correlation length {\xi} and at finite temperature. We address the correspondence between the geometrical transverse…

Statistical Mechanics · Physics 2012-10-03 Elisabeth Agoritsas , Sebastian Bustingorry , Vivien Lecomte , Gregory Schehr , Thierry Giamarchi

The transport coefficients of dense polymeric fluids are approximately calculated from the microscopic intermolecular forces. The following finite molecular weight effects are discussed within the Polymer-Mode-Coupling theory (PMC) and…

Condensed Matter · Physics 2009-10-30 Matthias Fuchs , Kenneth S. Schweizer

We analyze the dynamics of concentrated polymer solutions modeled by a 2D Smoluchowski equation. We describe the long time behavior of the polymer suspensions in a fluid. When the flow influence is neglected the equation has a gradient…

Analysis of PDEs · Mathematics 2025-09-17 Xingyu Li , Arghir Zarnescu

The concept of time correlation functions is a very convenient theoretical tool in describing relaxation processes in multiparticle systems because, on one hand, correlation functions are directly related to experimentally measured…

Statistical Mechanics · Physics 2019-09-05 Anatolii V. Mokshin

The aim of this paper is to investigate the distribution of a continuous polymer in the presence of an attractive finitely supported potential. The most intricate behavior can be observed if we simultaneously and independently vary two…

Mathematical Physics · Physics 2020-12-04 L. Koralov , S. Molchanov , B. Vainberg

Dilute or semi-dilute solutions of non-intersecting self-avoiding walk (SAW) polymer chains are mapped onto a fluid of ``soft'' particles interacting via an effective pair potential between their centers of mass. This mapping is achieved by…

Soft Condensed Matter · Physics 2009-10-31 P. G. Bolhuis , A. A. Louis , J. P. Hansen , E. J. Meijer

The theory of the dynamics of polymers in solution is developed coming from the hydrodynamic theory of the Brownian motion (BM) and the Rouse-Zimm (RZ) model. It is shown that the time correlation functions describing the polymer motion…

Soft Condensed Matter · Physics 2007-05-23 V. Lisy , J. Tothova , B. Brutovsky , A. V Zatovsky

The freely rotating chain is one of the classic discrete models of a polymer in dilute solution. It consists of a broken line of N straight segments of fixed length such that the angle between adjacent segments is constant and the N-1…

Probability · Mathematics 2017-11-15 Philip Kilanowski , Peter March , Marko Samara

We investigate the short-time dynamic relaxation of the two-dimensional XY model in the high temperature phase. Starting from the ordered state, we measure the autocorrelation function and determine the autocorrelation time. It is shown…

Statistical Mechanics · Physics 2009-10-31 Andreas Jaster

Understanding the decay of correlations in time for (1+1)-dimensional polymer models in the KPZ universality class has been a challenging topic. Following numerical studies by physicists, concrete conjectures were formulated by Ferrari and…

Probability · Mathematics 2025-08-08 Riddhipratim Basu , Timo Seppäläinen , Xiao Shen

We examine entanglements using monomer contacts between pairs of chains in a Brownian-dynamics simulation of a polymer melt. A map of contact positions with respect to the contacting monomer numbers (i,j) shows clustering in small regions…

Condensed Matter · Physics 2009-10-28 E. Ben-Naim , G. S. Grest , T. A. Witten , A. R. C. Baljon

Exact solutions for the elastic and thermodynamic properties for the wormlike chain model are elaborated in terms of Mathieu functions. The smearing of the classical Euler buckling instability for clamped polymers is analyzed for the…

Soft Condensed Matter · Physics 2017-05-10 Christina Kurzthaler , Thomas Franosch

Exact relaxation times and eigenfunctions for a simple mechanical model of polymer dynamics are obtained using supersymmetry methods of quantum mechanics. The model includes the finite extensibility of the molecule and does not make use of…

Soft Condensed Matter · Physics 2009-10-31 P. Ilg , I. V. Karlin , S. Succi

A method is presented that, when used in conjunction with single molecule experimental techniques, allows for the extraction of rates and mechanical properties of a biomolecule undergoing transitions between mechanically distinct states.…

Biomolecules · Quantitative Biology 2009-09-29 Darren E. Segall

We derive an exact formula for the covariance of cartesian distances in two simple polymer models, the freely-jointed chain and a discrete flexible model with nearest-neighbor interaction. We show that even in the interaction-free case…

Soft Condensed Matter · Physics 2009-04-17 Johannes-Geert Hagmann , Karol K. Kozlowski , Nikos Theodorakopoulos , Michel Peyrard