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We report neutron scattering measurements of the structural correlations associated with the apparent relaxor transition in K$_{1-x}$Li$_x$TaO$_3$ for $x=0.02$ (KLT(0.02)). This compound displays a broad and frequency-dependent peak in the…

Materials Science · Physics 2015-05-27 C. Stock , P. M. Gehring , G. Xu , D. Lamago , D. Reznik , M. Russina , J. Wen , L. A. Boatner

Dielectric measurements on 0.65[Pb(Ni_1/3Nb_2/3)O_3]-0.35PbTiO_3 ceramic in the temperature range 90K to 470K shows a relaxor ferroelectric transition around 350K with a Vogel-Fulcher freezing temperature of 338K and appearance of a…

Materials Science · Physics 2007-06-08 Satendra Pal Singh , Akhilesh Kumar Singh , Dhananjai Pandey , S. M. Yusuf

A novel lead-free tungsten bronze type ceramic Sr5BiTi3Nb7O30, was prepared by a conventional solid-state reaction route. The room-temperature crystal structure shows an average structure with centro-symmetric space group P4/mbm identified…

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

We discovered a near room temperature lead-free relaxor-ferroelectric (Ba0.6Bi0.2Li0.2)TiO3 (BBLT) having A-site compositional disordered ABO3 perovskite structure. Microstructure-property relations revealed that the chemical…

Materials Science · Physics 2016-06-22 Hitesh Borkar , Vaibhav Rao , Soma Dutta , Arun Barvat , Prabir Pal , M Tomar , Vinay Gupta , J. F. Scott , Ashok Kumar

Relaxor ferroelectric PbMg_1/3Ta_2/3O_3 ceramics and thin films were investigated by means of broad-band dielectric, time-domain terahertz (THz) and Fourier-transform infrared (IR) spectroscopy in the frequency range 100 Hz - 90 THz at…

Materials Science · Physics 2009-11-13 S. Kamba , D. Nuzhnyy , S. Veljko , V. Bovtun , J. Petzelt , Y. L. Wang , J. Levoska , M. Tyunina , J. Macutkevic , N. Setter , J. Banys

The dielectric and magnetic polarizations of quantum paraelectrics and paramagnetic materials have in many cases been found to initially increase with increasing thermal disorder and hence exhibit peaks as a function of temperature. A…

Materials Science · Physics 2020-06-04 M J Coak , C R S Haines , C Liu , S E Rowley , G G Lonzarich , S S Saxena

Materials tuned to the neighbourhood of a zero temperature phase transition often show the emergence of novel quantum phenomena. Much of the effort to study these new effects, like the breakdown of the conventional Fermi-liquid theory of…

Strongly Correlated Electrons · Physics 2014-05-06 S. E. Rowley , L. J. Spalek , R. P. Smith , M. P. M. Dean , G. G. Lonzarich , J. F. Scott , S. S. Saxena

Lead-free Ba0.85Ca0.15Zr0.10Ti0.90O3 (BCZT) ceramic exhibits excellent dielectric, ferroelectric and piezoelectric properties at the Morphotropic Phase Boundary (MPB). Previously, we demonstrated that the use of the anionic surfactant…

Dielectric study over a broadband was carried out from 10 to 70 K on ceramic Gd1-xYxMnO3 (x= 0.2, 0.3, and 0.4). For all the compositions, a prominent sharp peak about ~18K was observed in the temperature dependence of both {\epsilon}'(T)…

Materials Science · Physics 2017-06-28 R. M. Sarguna , V. Sridahran , A. M. Awasthi , N. Subramanian

Motivated by a recent proposal by O. P. Sushkov and co-workers to search for a P,T-violating Schiff moment of the $^{207}$Pb nucleus in a ferroelectric solid, we have carried out a high-field nuclear magnetic resonance study of the…

Other Condensed Matter · Physics 2013-01-15 L. -S. Bouchard , A. O. Sushkov , D. Budker , J. J. Ford , A. S. Lipton

(1-x)Li0.12Na0.88NbO3-xBaTiO3 (0 to x to 0.40) ferroelectric ceramics were prepared using conventional ceramics route and their phase transitional behavior is investigated by using dielectric spectroscopy. The temperature-dependent…

Materials Science · Physics 2014-12-17 Supratim Mitra , Ajit R. Kulkarni

Some of (1-x)NaNbO_3-(x)ABO_3 perovskite solid solutions exhibit a dramatic diffusion of the dielectric permittivity epsilon' maximum and relaxor-type behavior when the second component concentration exceeds a threshold value x_0. The…

Materials Science · Physics 2009-11-07 I. P. Raevski , S. A. Prosandeev

We study the spin dynamics in the quasi-2D spin-$1/2$ dimer compound Ba$_2$CuSi$_2$O$_6$Cl$_2$, which exhibits a magnetic field-induced Bose-Einstein condensate (BEC) of triplons. Using nuclear magnetic resonance (NMR) spin-lattice…

We present high energy x-ray (67 keV) and neutron scattering measurements on a single crystal of K$_{1-x}$Li$_x$TaO$_3$ for which the Li content ($x=0.02$) is less than $x_c = 0.022$, the critical value below which no structural phase…

Materials Science · Physics 2008-10-09 Jinsheng Wen , Guangyong Xu , C. Stock , P. M. Gehring , Z. Zhong , L. A. Boatner , E. L. Venturini , G. A. Samara

New relaxor ferroelectric system has been synthesized. BLTN exhibits a smeared maximum of permittivity, characteristic of classic relaxor behaviour, with a peak shift from 185 K at 100 Hz to 300 K at 1 GHz. BNTN undergoes a first order…

Materials Science · Physics 2007-05-23 S. Kamba , S. Veljko , M. Kempa , M. Savinov , V. Bovtun , P. Vanek , J. Petzelt , M. C. Stennett , I. M. Reaney , A. R. West

The behavior of matter near a quantum critical point (QCP) is one of the most exciting and challenging areas of physics research. Emergent phenomena such as high-temperature superconductivity are linked to the proximity to a QCP. Although…

Relaxor behavior and lattice dynamics have been studied for a single crystal of K$_{1-x}$Li$_x$TaO$_3$ $(x=0.05)$, where a small amount of a Ca impurity ($\sim 15$~ppm) was incorporated. The dielectric measurements revealed Debye-like…

Materials Science · Physics 2009-11-11 S. Wakimoto , G. A. Samara , R. K. Grubbs , E. L. Venturini , L. A. Boatner , G. Xu , G. Shirane , S. -H. Lee

Broadband dielectric spectroscopy from Hz up to the infrared (IR) range and temperature interval 10-300 K was carried out for xBaZrO3-(1-x)BaTiO3 (BZT-x, x = 0.6, 0.7, 0.8) solid solution ceramics and compared with similar studies for x =…

Materials Science · Physics 2013-12-12 J. Petzelt , D. Nuzhnyy , M. Savinov , V. Bovtun , M. Kempa , T. Ostapchuk , J. Hlinka , G. Canu , V. Buscaglia

Dielectric, anelastic and ^139La NMR relaxation measurements have been made on the relaxor ferroelectric Pb(1-3x/2)La(x)Zr(0.2)Ti(0.8)O(3) (PLZT) with x = 0.22. The dielectric susceptibility exihibits the frequency dispersive maximum due to…

Materials Science · Physics 2010-07-23 F. Cordero , M. Corti , F. Craciun , C. Galassi , D. Piazza , F. Tabak
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