Related papers: Coupling between criticality and gelation in "stic…
Computer simulations of the fluid-to-solid phase transition in the hard sphere system were instrumental for our understanding of crystallization processes. But while colloid experiments and theory have been predicting the stability of…
The effects of particle roughness and short-ranged non-central forces on colloidal gels are studied using computer simulations in which particles experience a sinusoidal variation in energy as they rotate. The number of minima $n$ and…
Attractive colloids diffuse and aggregate to form gels, solid-like particle networks suspended in a fluid. Gravity is known to strongly impact the stability of gels once they are formed. However, its effect on the process of gel formation…
We demonstrate that the spatial correlations of microscopic stresses in 2D model colloidal gels obtained in computer simulations can be quantitatively described by the predictions of a theory for emergent elasticity of pre-stressed solids…
Shear relaxation and dynamic density fluctuations are studied within a Rouse model, generalized to include the effects of permanent random crosslinks. We derive an exact correspondence between the static shear viscosity and the resistance…
The onset and growth of rigid clusters in a two-dimensional (2D) suspension in shear flow are studied by numerical simulations. The suspension exhibits the lubricated-to-frictional rheology transition, but the key results here are for…
The rotational Brownian motion of colloidal spheres in dense suspensions reflects local hydrodynamics and friction, both key to non-linear rheological phenomena such as shear-thickening and jamming, and transport in crowded environments,…
One major goal in condensed matter physics is identifying the physical mechanisms that lead to arrested states of matter, especially gels and glasses. The complex nature and microscopic details of each particular system are relevant.…
We have carried out molecular dynamics simulations of the crystallization of hard spheres modelling colloidal systems that are studied in conventional and space-based experiments. We use microscopic probes to investigate the effects of…
Colloidal gels are out-of-equilibrium structures, made up of a rarefied network of colloidal particles. Comparing experiments to numerical simulations, with hydrodynamic interactions switched off, we demonstrate the crucial role of the…
We study numerically the crystallization of a hard-sphere mixture with 8\% polydispersity. Although often used as a model glass former, for small system sizes we observe crystallization in molecular dynamics simulations. This opens the…
Using computer simulations, we study the dynamic arrest in a schematic model of colloid-polymer mixtures combining short-ranged attractions with long-ranged repulsions. The arrested gel is a dilute rigid network of colloidal particles…
Cavitation in solids can be caused by tensile dead-load traction or impulse traction. The two different types of boundary conditions lead to different static and dynamic solutions. In addition, if the material is stochastic, i.e., the model…
Systems with long-range interactions when quenced into a metastable state near the pseudo-spinodal exhibit nucleation processes that are quite different from the classical nucleation seen near the coexistence curve. In systems with…
Dynamic particle-scale numerical simulations are used to show that the shear thickening observed in dense colloidal, or Brownian, suspensions is of a similar nature to that observed in non-colloidal suspensions, i.e., a stress-induced…
We report a detailed simulation and classical density functional theory study of the drying transition in a realistic model fluid at a smooth substrate. This transition (in which the contact angle $\theta\to 180^\circ$) is shown to be…
We determined bulk crystal nucleation rates in aqueous suspensions of charged spheres at low metastability. Experiments were performed in dependence on electrolyte concen-tration and for two different particle number densities. The…
Active systems of self-rotating elements inherently exhibit chirality, making them of fundamental interest due to parity violation. Using large-scale hydrodynamic simulations, we investigate the gelation of adhesive spinners confined to…
The way granular materials response to an applied shear stress is of the utmost relevance to both human activities and natural environment. One of the their most intriguing and less understood behavior, is the stick-instability, whose most…
Surface effects are generally prevailing in confined colloidal systems. Here we report on dispersed nanoparticles close to a fluid membrane. Exact results regarding the static organization are derived for a dilute solution of non-adhesive…