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We describe in detail how attosecond delays in laser-assisted photoionization can be computed using perturbation theory based on two-photon matrix elements. Special emphasis is laid on above-threshold ionization, where the electron…

Atomic Physics · Physics 2015-06-19 J. M. Dahlström , E. Lindroth

Reconstruction of attosecond beating by interference of two-photon transitions (RABBITT) is a powerful photoelectron spectroscopy, offering direct access to internal dynamics of the target. It is being increasingly applied to molecular…

Chemical Physics · Physics 2023-04-10 Serguei Patchkovskii , Jakub Benda , Dominik Ertel , David Busto

One of the most ubiquitous techniques within attosecond science is the so-called Reconstruction of Attosecond Bursts by Interference of Two-Photon Transitions (RABBITT). Originally proposed for the characterization of attosecond pulses, it…

Phase and time delays of atomic above-threshold ionization are usually experimentally explored by the reconstruction of attosecond harmonic beating by interference of two-photon transitions (RABBIT) technique. Theoretical studies of RABBIT…

Atomic Physics · Physics 2024-03-25 Sebastián D. López , Matias L. Ocello , Diego G. Arbó

We present an analytical model capable of describing two-photon ionization of atoms with attosecond pulses in the presence of intermediate and final isolated autoionizing states. The model is based on the finite-pulse formulation of…

Atomic Physics · Physics 2016-03-02 Álvaro Jiménez Galán , Fernando Martín , Luca Argenti

We theoretically explore a variant of RABBITT spectroscopy in which the attosecond-pulse train comprises isolated pairs of consecutive harmonics of the fundamental infrared probe frequency. In this scheme, one-photon and two-photon…

Atomic Physics · Physics 2019-05-15 Bejan Ghomashi , Nicolas Douguet , Luca Argenti

First-principles methods for time-resolved angular resolved photoelectron spectroscopy play a pivotal role in providing interpretation and microscopic understanding of the complex experimental data and in exploring novel observables or…

Materials Science · Physics 2021-12-28 Umberto De Giovannini , Shunsuke A. Sato , Hannes Hübener , Angel Rubio

The implementation of attosecond photoelectron-photoion coincidence spectroscopy for the investigation of atomic and molecular dynamics calls for a high-repetition-rate driving source combined with experimental setups characterized by…

Molecular absorption and photo-electron spectra can be efficiently predicted with real-time time-dependent density-functional theory (TDDFT). We show here how these techniques can be easily extended to study time-resolved pump-probe…

Atomic and Molecular Clusters · Physics 2013-01-10 Umberto De Giovannini , Gustavo Brunetto , Alberto Castro , Jessica Walkenhorst , Angel Rubio

Realistic attosecond wave packets have complex profiles that, in dispersive conditions, rapidly broaden or split into multiple components. Such behaviors are encoded in sharp features of the wave packet spectral phase. Here, we exploit the…

Extracting single photoionization time delays associated with atomic (or molecular) species from attosecond time scale two-photon experiments usually relies on the theoretical description of continuum-continuum transitions. The available…

Atomic Physics · Physics 2022-08-29 D. I. R. Boll , L. Martini , O. A. Fojón

Attosecond photoionisation time delays reveal information about the potential energy landscape an outgoing electron wavepacket probes upon ionisation. In this study we experimentally quantify, for the first time, the dependence of the time…

Attosecond ionization time-delays at photoelectron energies above typically 10 eV are usually interpreted using the so called asymptotic approximation as a sum of the atomic or molecular delays with a universal laser-induced contribution.…

We present a novel theoretical approach to simulate spin, time and angular-resolved photoelectron spectroscopy (ARPES) from first principles that is applicable to surfaces, thin films, few layer systems, and low-dimensional nanostructures.…

Computational Physics · Physics 2017-01-03 Umberto De Giovannini , Hannes Hübener , Angel Rubio

We theoretically study time-resolved photoemission in atoms as probed by attosecond streaking. We review recent advances in the study of the photoelectric effect in the time domain and show that the experimentally accessible time shifts can…

Atomic Physics · Physics 2015-03-06 Stefan Nagele , Renate Pazourek , Michael Wais , Georg Wachter , Joachim Burgdörfer

The reconstruction of attosecond beating by interference of two-photon transitions (RABBIT) is one of the most widely used techniques for obtaining both the relative phases of harmonics forming an attosecond pulse train and the phase of…

Optics · Physics 2023-09-13 R. E. F. Silva , Á. Jiménez-Galán

Nonequilibrium electron dynamics in solids is an important subject from both fundamental and technological points of view. The recent development of laser technology has enabled us to study ultrafast electron dynamics in the time domain.…

Materials Science · Physics 2020-11-04 Shunsuke A. Sato

We study laser-assisted photoionization by attosecond pulses using a time-independent formalism based on diagrammatic many-body perturbation theory. Our aim is to provide an ab inito route to the "delays" for this above-threshold ionization…

Atomic Physics · Physics 2015-06-12 J. M. Dahlström , T. Carette , E. Lindroth

Measured photoionization time delays may exhibit large variations as a function of the emission angles, even for spherically symmetric targets, as shown in recent RABBITT (reconstruction of attosecond beating by interference of two-photon…

Atomic Physics · Physics 2022-12-29 D. I. R. Boll , L. Martini , A. Palacios , O. A. Fojón

We have calculated the resonant and nonresonant contributions to attosecond impulsive stimulated electronic Raman scattering (SERS) in regions of autoionizing transitions. Comparison with Multiconfiguration Time-Dependent Hartree-Fock…

Atomic Physics · Physics 2016-10-06 Matthew R. Ware , Philip H. Bucksbaum , James P. Cryan , Daniel J. Haxton
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