Related papers: Climbing the rotational ladder to chirality
Achiral molecules can be made temporarily chiral by excitation with electric fields, in the sense that an average over molecular orientations displays a net chiral signal [Tikhonov et al., Sci. Adv. 8, eade0311 (2022)]. Here, we go beyond…
We analyze two simple model planar molecules: an ionic molecule with D3 symmetry and a covalent molecule with D6 symmetry. Both symmetries allow the existence of chiral molecular orbitals and normal modes that are coupled to each other in a…
Chirality is a fundamental concept in physics that underpins various phenomena in nonlinear optics, quantum physics, and topological photonics. Although the spin of a photon naturally brings chirality, orbital angular momentum can also…
In chemistry and biochemistry, chirality represents the structural asymmetry characterized by non-superimposable mirror images for a material like DNA. In physics, however, chirality commonly refers to the spin-momentum locking of a…
Chirality describes the asymmetry between an object and its mirror image and manifests itself in diverse functionalities across all scales of matter - from molecules and aggregates to thin films and bulk chiral materials. A particularly…
Chirality is a fundamental property of great importance in physics, chemistry, and biology, and has recently been found to generate unexpected spin polarization for electrons passing through organic molecules, known as chirality-induced…
Chirality is ubiquitous in nature and of fundamental importance in science. The present work focuses on understanding the conditions required to modify the chirality during ultrafast electronic motion by bringing enantiomers…
Chirality is a pervasive form of symmetry that is intimately connected to the physical properties of solids, as well as the chemical and biological activity of molecular systems. However, its control with light is challenging, because…
Chirality-induced spin selectivity (CISS) describes how chiral molecules and materials generate spin polarization even at thermal equilibrium. This observation has challenged established principles of microscopic reversibility and Onsager…
We propose a predictive building-up of tetrahedral molecules, based on a previously derived chirality index, which characterizes a tetrahedral molecule, with n chiral centers, as achiral, diastereoisomer, or enantiomer as a function of the…
Molecular chirality is a key design property for many technologies including bioresponsive imaging, circularly polarized light detection and emission, molecular motors and switches. Imaging and manipulating the primary steps of transient…
Chirality is ubiquitous in nature and fundamental in science, from particle physics to metamaterials.The most established technique of chiral discrimination - photoabsorption circular dichroism - relies on the magnetic properties of a…
Chiral induced spin selectivity is a phenomenon that has been attributed to chirality, spin-orbit interactions, and non-equilibrium conditions, while the role of electron exchange and correlations have been investigated only marginally…
Chiral molecules form a number of non-chiral structures, the simplest being an isotropic fluid phase. In a mesophase of achiral molecules the fluctuations will on average be achiral as well: left-handed twists and right-handed twists will…
We introduce chiral rotational spectroscopy: a new technique that enables the determination of the orientated optical activity pseudotensor components $B_{XX}$, $B_{YY}$ and $B_{ZZ}$ of chiral molecules, in a manner that reveals the…
Chirality pervades multiple scientific domains-physics, chemistry, biology, and astronomy-and profoundly influences their foundational principles. Recently, the chirality-induced spin selectivity (CISS) phenomenon has captured significant…
Chirality is a ubiquitous phenomenon in the natural world. Many biomolecules without inversion symmetry such as amino acids and sugars are chiral molecules. Measuring and controlling molecular chirality at a high precision down to the…
Chirality is of primary importance in many areas of chemistry and has been extensively investigated since its discovery. We introduce here the description of central chirality for tetrahedral molecules using a geometrical approach based on…
Chirality-induced spin selectivity (CISS) refers to an ability to induce a spin polarization of an electron transmitted through chiral materials. An important experimental observation is that incredibly large spin polarization is realized…
Chiral excited electronic states of molecules have an intrinsic sense of handedness, or twist, and are the active component in energy efficient display technologies and in new photosynthetic routes to produce pharmaceuticals. Creating…