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We investigate the impact of combined electric and magnetic fields on the structure of ultralong-range polar Rydberg molecules. Our focus is hereby on the parallel as well as the crossed field configuration taking into account both the…

Atomic Physics · Physics 2014-09-11 Markus Kurz , Peter Schmelcher

Triatomic molecule RaOH combines the advantages of laser-coolability and the spectrum with close opposite-parity doublets. This makes it a promising candidate for experimental study of the $\mathcal{P}$,$\mathcal{T}$-violation. Previous…

Atomic Physics · Physics 2021-03-17 Anna Zakharova , Alexander Petrov

We introduce mapping-variable ring polymer molecular dynamics (MV-RPMD), a model dynamics for the direct simulation of multi-electron processes. An extension of the RPMD idea, this method is based on an exact, imaginary time path-integral…

Statistical Mechanics · Physics 2015-06-17 Nandini Ananth

Variational methods are used to calculate structural and thermodynamical properties of a titrating polyelectrolyte in a discrete representation. The Coulomb interactions are emulated by harmonic repulsive forces, the force constants being…

chem-ph · Physics 2008-02-03 B. Jönsson , M. Ullner , C. Peterson , O. Sommelius , B. Söderberg

According to the Schiff theorem, the atomic electrons completely screen the atomic nucleus from an external static electric field. However, this is not the case if the field is time-dependent. Electronic orbitals in atoms either shield the…

Atomic Physics · Physics 2019-01-30 H. B. Tran Tan , V. V. Flambaum , I. B. Samsonov

Vibrational-excitation cross sections of ground electronic state of carbon dioxide molecule by electron-impact through the CO2-(2\Pi) shape resonance is considered in the separation of the normal modes approximation. Resonance curves and…

Chemical Physics · Physics 2016-11-01 V. Laporta , J. Tennyson , R. Celiberto

By using the wave function ansatz method, we study the energy eigenvalues and wave function for any arbitrary $m$-state in two-dimensional Schr\"{o}dinger wave equation with various power interaction potentials in constant magnetic and…

Quantum Physics · Physics 2014-12-23 Sameer M. Ikhdair , Babatunde J. Falaye , Majid Hamzavi

The spectra (rotational, rotation-vibrational or electronic) of diatomic molecules due to transitions involving only closed-shell ($^1\Sigma$) electronic states follow very regular, simple patterns and their theoretical analysis is usually…

Chemical Physics · Physics 2016-05-10 Jonathan Tennyson , Lorenzo Lodi , Laura K. McKemmish , Sergei N Yurchenko

In the context of Frenkel exciton dynamics in aggregated molecules the polaron transformation technique facilitates a treatment where diagonal elements attributed to electronic excited-state populations are decoupled from fluctuations…

Chemical Physics · Physics 2021-08-30 Joachim Seibt , Oliver Kühn

The QED vacuum polarization in external monochromatic plane-wave electromagnetic fields is calculated with spatial and temporal variations of the external fields being taken into account. We develop a perturbation theory to calculate the…

High Energy Physics - Phenomenology · Physics 2019-12-06 Akihiro Yatabe , Shoichi Yamada

A full set of vibrationally-resolved cross sections for electron impact excitation of NO(X2{\Pi}, v) molecules is calculated from ab initio molecular dynamics, in the framework of the local-complex-potential approach. Electron-vibration…

Atomic Physics · Physics 2024-11-15 V Laporta , L Vialetto , V Guerra

Investigations of electromagnetic interactions between test-charged and magnetized particles are important in the dynamics of the particles in strong gravitational fields around black holes. Here, we study the dynamics of a particle having…

General Relativity and Quantum Cosmology · Physics 2023-10-13 Sardor Murodov , Javlon Rayimbaev , Bobomurat Ahmedov , Abdullo Hakimov

Accurate low and high-lying bound states of Tietz-Hua oscillator potential are presented. The radial Schr\"odinger equation is solved efficiently by means of the generalized pseudospectral method that enables optimal spatial discretization.…

Chemical Physics · Physics 2014-09-10 Amlan K. Roy

We theoretically explore the effect of a transverse electric field on the frictional response of a bi-layer of packed zwitterionic molecules. The dipole-moment reorientation promoted by the electric field can lead to either stick-slip or…

Soft Condensed Matter · Physics 2024-04-16 Melisa M. Gianetti , Roberto Guerra , Andrea Vanossi , Michael Urbakh , Nicola Manini

Achiral molecules can be made temporarily chiral by excitation with electric fields, in the sense that an average over molecular orientations displays a net chiral signal [Tikhonov et al., Sci. Adv. 8, eade0311 (2022)]. Here, we go beyond…

Electrostatic hexapoles are revealed as a powerful tool in the rotational state-selection and alignment of molecules to be utilized in beam experiments on collisional and photoinitiated processes. In the paper, we report results on the…

This article covers few selected aspects of quantum theory of molecular rotations and vibrations. Triatomic molecules are the simplest systems, which show qualitative characteristics of larger polyatomic molecules. On the minimal example of…

Chemical Physics · Physics 2022-03-18 Emil J. Zak

We present a theoretical study of the impact of an electric field combined with a magnetic field on the rotational dynamics of open shell diatomic molecules. Within the rigid rotor approximation, we solve the time-independent Schr\"odinger…

Chemical Physics · Physics 2015-06-12 Martin Gärttner , Juan J. Omiste , Peter Schmelcher , Rosario González-Férez

The chiral source and its mechanism in the molecular system are of great significance in many fields. In this work, we proposed visualized methods to investigate physical mechanism of chiral molecule, where the electric and magnetic…

Chemical Physics · Physics 2019-05-29 Jingang Wang , Xiangtao Chen , Jizhe Song , Xijiao Mu , Mengtao Sun

Understanding the quantum dynamics of strongly coupled molecule-cavity systems remains a significant challenge in molecular polaritonics. This work develops a comprehensive self-consistent model simulating electromagnetic interactions of…

Chemical Physics · Physics 2025-01-29 Maxim Sukharev , Joseph E. Subotnik , Abraham Nitzan