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We have studied thermodynamics of the Mg-B system with the modeling technique CALPHAD using a computerized optimization procedure. Temperature-composition, pressure-composition, and pressure-temperature phase diagrams under different…

Materials Science · Physics 2009-11-07 Zi-Kui Liu , D. G. Schlom , Qi Li , X. X. Xi

Bulk superconductor samples of YBa2Cu3-xCoxO7-{\delta} with x = 0, 0.01, 0.03, 0.05 are synthesized by solid-state reaction route. Both x-ray diffraction and electron microscopy have been employed to study the phase identification,…

Superconductivity · Physics 2011-07-07 Sushant Gupta , R. S. Yadav , N. P. Lalla , G. D. Verma , B. Das

The temperature dependence of the relaxation dynamics in the bilayer thin film heterostructure composed of multiferroic BiFeO$_{3}$ (BFO) and superconducting YBa$_{2}$Cu$_{3}$O$_{7}$ (YBCO) grown on a (001) SrTiO$_{3}$ substrate is studied…

The oxygenation process at constant temperature of YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) was systematically investigated in the temperature range from 300 $^o$C to 800 $^o$C. With this purpose, fully deoxygenated powder samples was exposed to…

Superconductivity · Physics 2026-04-02 R. F. Luccas , L. Gallo

We report on the temperature-dependent optical response of thin films of YBa2Cu3O7-{\delta} (YBCO) in the visible spectral range under cryogenic conditions. Specifically, we observe an increase in transmittance near the superconducting…

Superconducting thick films (200$\mu$m-300$\mu$m) of YBCO have been fabricated successfully on MgO substrates by a new approach. The precursor powders (YBa2Cu3O7-$\delta$(Y123)+0.1molY2BaCuO5(Y211)) are placed between two MgO (10mm x 10mm)…

Superconductivity · Physics 2007-05-23 Y. B. Zhu , J. W. Xiong , S. F. Wang , Y. L. Zhou , Q. Zhang , S. Y. Dai , Z. H. Chen , H. B. Lu , G. Z. Yang

The oxygen deficiency $\delta$ in YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) plays a crucial role for affecting high-temperature superconductivity. We applied (coincident) Doppler broadening spectroscopy of the electron-positron annihilation line…

Superconductivity · Physics 2018-04-11 M. Reiner , T. Gigl , R. Jany , G. Hammerl , C. Hugenschmidt

It is known that solid-state reaction in high-pressure oxygen can stabilize high-oxidation phases of Y-Ba-Cu-O superconductors in powder form. We extend this superoxygenation concept of synthesis to thin films which, due to their large…

Superconductivity · Physics 2018-04-04 H. Zhang , N. Gauquelin , C. McMahon , D. G. Hawthorn , G. A. Botton , J. Y. T. Wei

More than a quarter century after the discovery of the high temperature superconductor (HTS) YBa$_2$Cu$_3$O$_{6+\delta}$ (YBCO) studies continue to uncover complexity in its phase diagram. In addition to HTS and the pseudogap there is…

We have investigated the thermodynamic and kinetic barriers involved in the synthesis of MgB2 films. This work refines our initial conjectures predicting optimal MgB2 thin film growth conditions as a consequence of the unusually large…

Superconductivity · Physics 2018-07-04 Jihoon Kim , Rakesh K. Singh , Nathan Newman , John M. Rowell

In the reported low-fluorine MOD-YBCO studies, the lowest F/Ba mole ratio of the precursor solution was 4.5. However, further lowering the F/Ba ratio is important according to the researches of YBCO thick film. On the other hand, the F/Ba…

The effect of thermal phase fluctuations (TPF's) on the ab-plane penetration depth, lambda(T), of thin YBa2Cu3O(7-delta) (YBCO) films is found to be much smaller than expected from the paradigm of cuprates as weakly-coupled 2D…

Superconductivity · Physics 2007-05-23 Yuri Zuev , John A. Skinta , Mun-Seog Kim , Thomas R. Lemberger , E. Wertz , K. Wu , Q. Li

The thermal stability of MgB2 has been studied experimentally to determine the role of thermodynamic and kinetic barriers in the decomposition process. The MgB2 decomposition rate approaches one monolayer per second at 650 C and has an…

Superconductivity · Physics 2009-11-07 Z. Y. Fan , D. G. Hinks , N. Newman , J. M. Rowell

Solid-state synthesis from powder precursors is the primary processing route to advanced multicomponent ceramic materials. Designing ceramic synthesis routes is usually a laborious, trial-and-error process, as heterogeneous mixtures of…

In this work, we report a strengthened superheating effect caused by a buffering YBa2Cu3Oy (Y123 or YBCO) layer in the Nd1+xBa2-xCu3O7-y (Nd123 or NdBCO) thin film with MgO substrate (i.e., NdBCO/YBCO/MgO thin film). In the cold-seeding…

Superconductivity · Physics 2015-06-03 H. H. Xu , Y. Y. Chen , L. Cheng , S. B. Yan , D. J. Yu , X. Yao

Thin films of the superconductor YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) were modified by low-energy light-ion irradiation employing collimated or focused He$^+$ beams, and the long-term stability of irradiation-induced defects was investigated.…

The thermal properties are one of the key parameters to control phase purity and microstructure of polycrystalline materials. The melting point of the iron-based BaFe2As2 superconductor (Ba122), which foresees high-field applications,…

Superconductivity · Physics 2021-01-15 Shinnosuke Tokuta , Akiyasu Yamamoto

A new method for preparation of single crystals of the superconducting intermetallic MgB2 compound from a Mg-Cu-B melt flux is presented. The high vapour pressure of Mg at elevated temperature is a serious challenge of the preparation…

Superconductivity · Physics 2007-05-23 D. Souptel , G. Behr , W. Loser , W. Kopylov , M. Zinkevich

We have grown and characterized 30 nm thick YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) films, deposited by pulsed laser deposition on both MgO (110) and SrTiO$_3$ (001) substrates, which induce opposite strain to the superconducting layer. By…

Superconductivity · Physics 2018-03-05 Riccardo Arpaia , Eric Andersson , Edoardo Trabaldo , Thilo Bauch , Floriana Lombardi

In this letter, we present the superconducting property characterization of a phase pure reasonably good quality YBa2Cu3O7-{\delta} sample. Studied compound is crystallized in orthorhombic Pmmm space group with lattice parameters a, b, and…

Superconductivity · Physics 2014-01-21 Rajveer Jha , Poonam Rani , V. P. S Awana
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