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Related papers: $GW$ self-screening error and its correction using…

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In local effective potential theories of electronic structure, the electron correlations due to the Pauli exclusion principle, Coulomb repulsion, and correlation-kinetic effects, are all incorporated in the local electron-interaction…

Materials Science · Physics 2007-05-23 Zhixin Qian , Viraht Sahni

We test the Coulomb exchange and correlation energy density functionals of electron systems for atomic nuclei in the local density approximation (LDA) and the generalized gradient approximation (GGA). For the exchange Coulomb energies, it…

Nuclear Theory · Physics 2018-04-25 Tomoya Naito , Ryosuke Akashi , Haozhao Liang

Disorder-induced localization of electrons and electron-electron interaction are among the most fundamental problems in condensed matter physics. In two-dimensional electron systems, extensive studies have led to the emergence of a scaling…

Mesoscale and Nanoscale Physics · Physics 2026-05-29 C. T. Tai , P. T. Madathil , A. Gupta , L. N. Pfeiffer , K. W. Baldwin , M. Shayegan

In the exact Kohn-Sham density-functional theory (DFT), the total energy versus the number of electrons is a series of linear segments between integer points. However, commonly used approximate density functionals produce total energies…

Materials Science · Physics 2013-04-03 Eli Kraisler , Leeor Kronik

The good performance of the GW approximation for band-structure calculations in solids was long taken as a sign that the sum of self-energy diagrams is converged and that all omitted terms are small. However, with modern computational…

Materials Science · Physics 2007-05-23 Arno Schindlmayr

The vertex function ($\Gamma$) within the Green's function formalism encapsulates information about all higher-order electron-electron interaction beyond those mediated by density fluctuations. Herein, we present an efficient approach that…

Chemical Physics · Physics 2023-03-28 Guorong Weng , Rushil Mallarapu , Vojtech Vlcek

In a previous paper we suggested that a macroscopic force field applied across a two-dimensional electron gas channel could induce a microscopic charge density wave as soon as the proper compressibility becomes negative, which happens at…

Mesoscale and Nanoscale Physics · Physics 2020-11-24 Erica Hroblak , Mohammad Zarenia , Giovanni Vignale

First-principles descriptions of correlated quantum materials require a simultaneous treatment of strong local many-body effects and nonlocal dynamical screening. We present an efficient fully self-consistent implementation of $GW$+EDMFT…

Strongly Correlated Electrons · Physics 2026-03-16 Chia-Nan Yeh , Francesco Petocchi , Alexander Hampel , Philipp Werner , Olivier Parcollet , Antoine Georges , Miguel Morales

We calculate the electronic structure of several atoms and small molecules by direct minimization of the Self-Interaction Corrected Local Density Approximation (SIC-LDA) functional. To do this we first derive an expression for the gradient…

Condensed Matter · Physics 2009-10-28 S. Goedecker , C. J. Umrigar

Dielectrically confined Coulomb systems are widely employed in molecular dynamics (MD) simulations. Despite extensive efforts in developing efficient and accurate algorithms for these systems, rigorous and accurate error estimates, which…

Numerical Analysis · Mathematics 2025-03-25 Xuanzhao Gao , Qi Zhou , Zecheng Gan , Jiuyang Liang

Corrections to elastic moduli, including the effective shear modulus, of a solid neutron star crust due to electron screening are calculated. At any given mass density, the crust is modelled as a body-centred cubic Coulomb crystal of fully…

Solar and Stellar Astrophysics · Physics 2016-03-23 D. A. Baiko

In this article, we investigate the role of the self-interaction error in the simulation of collisions using time-dependent density functional theory (TDDFT) and Ehrenfest dynamics. We compare many different approximations of the exchange…

Chemical Physics · Physics 2017-05-03 Edwin E. Quashie , Bidhan C. Saha , Xavier Andrade , Alfredo A. Correa

We present GW calculations of molecules, ordered and disordered solids and interfaces, which employ an efficient contour deformation technique for frequency integration, and do not require the explicit evaluation of virtual electronic…

Materials Science · Physics 2015-01-14 Marco Govoni , Giulia Galli

By using the quantum Ising chain as a test bed and treating the spin polarization along the external transverse field as the "generalized density", we examine the performance of different levels of density functional approximations parallel…

Computational Physics · Physics 2021-10-27 Jiahao Mao , Haifeng Tang , Wenhui Duan , Zheng Liu

An efficient all-electron G$^0$W$^0$ method and a quasiparticle selfconsistent GW (QSGW) method for molecules are proposed in the molecular orbital space with the full random phase approximation. The convergence with basis set is examined.…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 San-Huang Ke

Approximate functionals used in practical density functional theory (DFT) deviate from the piecewise linear behavior of the exact functional for fractional charges. This deviation causes excess charge delocalization, which leads to…

Chemical Physics · Physics 2018-10-23 Diptarka Hait , Martin Head-Gordon

In principle, the electronic Coulomb interaction among the correlated orbitals is frequency-dependent. Though it is generally believed that the dynamically screened interaction may play a crucial role in understanding the subtle electronic…

Strongly Correlated Electrons · Physics 2013-03-13 Li Huang , Yilin Wang

We extend some of the well established self-interaction correction (SIC) schemes of density-functional theory to the case of systems with noncollinear magnetism. Our proposed SIC schemes are tested on a set of molecules and metallic…

Chemical Physics · Physics 2023-10-31 Nicolas Tancogne-Dejean , Martin Lüders , Carsten A. Ullrich

In the framework of the grand-canonical ensemble of statistical mechanics, we give an exact diagrammatic representation of the density profiles in a classical multicomponent plasma near a dielectric wall. By a reorganization of Mayer…

Statistical Mechanics · Physics 2007-05-23 Jean-Noel Aqua , Francoise Cornu

Employing a local formula for the electron-electron interaction energy, we derive a self-consistent approximation for the total energy of a general $N$-electron system. Our scheme works as a local variant of the Thomas-Fermi approximation…

Chemical Physics · Physics 2013-10-31 E. Rasanen , A. Odriazola , I. Makkonen , A. Harju