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We predict a large in-plane polarization response to bending in a broad class of trigonal two-dimensional crystals. We define and compute the relevant flexoelectric coefficients from first principles as linear-response properties of the…

Materials Science · Physics 2023-08-01 Matteo Springolo , Miquel Royo , Massimiliano Stengel

Symmetry breaking at surfaces and interfaces and the capability to support large strain gradients in nanoscale systems enable new forms of electromechanical coupling. Here we introduce the concept of quantum flexoelectricity, a phenomenon…

Materials Science · Physics 2009-11-13 Sergei V. Kalinin , Vincent Meunien

A real-space representation of the current response of many-electron systems with possible applications to x-ray nonlinear spectroscopy and magnetic susceptibilities is developed. Closed expressions for the linear, quadratic and third-order…

Strongly Correlated Electrons · Physics 2009-11-10 Oleg Berman , Shaul Mukamel

We demonstrate the existence of different density-density functionals designed to retain selected properties of the many-body ground state in a non-interacting solution starting from the standard density functional theory ground state. We…

Other Condensed Matter · Physics 2009-11-13 F. A. Reboredo , P. R. C. Kent

In the current density functional theory of linear and nonlinear time-dependent phenomena, the treatment of exchange and correlation beyond the level of the adiabatic local density approximation is shown to lead to the appearance of…

Condensed Matter · Physics 2009-10-30 G. Vignale , C. A. Ullrich , S. Conti

The flexoelectric (FE) effect provides a linear coupling between electric polarization and orientational deformation in liquid crystals. It influences many electrooptical phenomena and it is used in some bistable nematic devices. A…

Soft Condensed Matter · Physics 2023-07-19 A. Kapanowski

Piezoelectricity is a technologically important property of certain insulators in which mechanical strain induces an electrical polarization. However, the rate at which a piezoelectric response can be established over a macroscopic volume…

Advancements in modern semiconductor devices increasingly depend on the utilization of amorphous materials and the reduction of material thickness, pushing the boundaries of their physical capabilities. The mechanical properties of these…

Applied Physics · Physics 2024-05-31 C. Pashartis , M. J. van Setten , M. Houssa , G. Pourtois

We present for static density functional theory and time-dependent density functional theory calculations an all-electron method which employs high-order hierarchical finite element bases. Our mesh generation scheme, in which structured…

Materials Science · Physics 2009-08-06 Lauri Lehtovaara , Ville Havu , Martti Puska

The fractional quantum Hall effect remains a captivating area in condensed matter physics, characterized by strongly correlated topological order, which manifests as fractionalized excitations and anyonic statistics. Numerical simulations,…

Strongly Correlated Electrons · Physics 2025-10-27 Yi Yang , Yayun Hu , Zi-Xiang Hu

The package "fhi96md" is an efficient code to perform density-functional theory total-energy calculations for materials ranging from insulators to transition metals. The package employs first-principles pseudopotentials, and a plane-wave…

Condensed Matter · Physics 2009-10-30 Michel Bockstedte , Alexander Kley , Joerg Neugebauer , Matthias Scheffler

Current-density-functional theory is used to perturbatively calculate single-particle energies of open-shell atoms prepared in a current-carrying state. We focus on the highest occupied such energy, because its negative is, in principle,…

Chemical Physics · Physics 2015-06-26 E. Orestes , A. B. F. da Silva , K. Capelle

Because of the flexoelectric effect, dielectric materials usually polarize in response to a strain gradient. Soft materials are good candidates for developing large strain gradient because of their good deformability. However, they always…

Soft Condensed Matter · Physics 2019-04-17 Xin Wen , Dongfan Li , Kai Tan , Qian Deng , Shengping Shen

The basic idea of Frozen-Density Embedding Theory (FDET) is the constrained minimisation of the Hohenberg-Kohn density functional $E^{HK}[\rho]$ performed using the auxiliary functional $E_{v_{AB}}^{FDET}[\Psi_A,\rho_B]$, where $\Psi_A$ is…

Chemical Physics · Physics 2020-06-22 Niccolò Ricardi , Michelle Ernst , Piero Macchi , Tomasz A. Wesolowski

The operation of a novel nonvolatile memory device based on a conductive ferroelectric/non-ferroelectric thin film multilayer stack is simulated numerically. The simulation involves the self-consistent steady state solution of Poisson's…

Materials Science · Physics 2007-05-23 Rene Meyer , Hermann Kohlstedt

Recent work shows that density functional theory calculations accurately describe materials exhibiting turbostratic disorder between layers of incommensurate constituents. These calculations approximate one of the constituents as a finite…

Materials Science · Physics 2016-11-23 Sven P. Rudin

It is highly desirable to discover an electromechanical coupling that allows a dielectric material to generate curvature in response to a uniform electric field, which would add a new degree of freedom for designing actuators.…

Soft Condensed Matter · Physics 2021-01-27 X. Wen , K. Tan , Q. Deng , S. Shen

We present an ab initio method to calculate the clamped Pockels tensor of ferroelectric materials from density-functional theory, the modern theory of polarization exploiting the electric-enthalpy functional, and automated first- and…

Soft robotics requires materials that are capable of large deformation and amenable to actuation with external stimuli such as electric fields. Energy harvesting, biomedical devices, flexible electronics and sensors are some other…

Soft Condensed Matter · Physics 2021-05-27 Matthew Grasinger , Kosar Mozaffari , Pradeep Sharma

The flexoelectric and electronic properties of zig-zag graphene nanoribbons are explored under mechanical bending using state of the art first principles calculations. A linear dependence of the bending induced out of plane polarization on…

Materials Science · Physics 2021-06-03 Tribhuwan Pandey , Lucian Covaci , Francois M. Peeters