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Through machine learning force field accelerated structure search combined with first-principles calculations, we have studied the structures of new C-N compounds with different stoichiometric ratios, and found twelve new superhard C-N…

Materials Science · Physics 2022-12-09 Yunlong Wang , Chi Ding , Jianan Yuan , Jian Sun

Here we report the synthesis of metallic, ultraincompressible (bulk modulus $K_{0}$ = 428(10) GPa) and very hard (nanoindentation hardness 36.7(8) GPa) rhenium (V) nitride pernitride Re$_{2}$(N$_{2}$)N$_{2}$. While the empirical chemical…

Search of materials with C-N composition hold a great promise in creating materials which would rival diamond in hardness due to the very strong and relatively low-ionic C-N bond. Early experimental and theoretical works on C-N compounds…

The current search for room-temperature superconductivity is inspired by the unique properties of the electron-phonon interaction in metal superhydrides. Encouraged by the recently found highest-$T_C$ superconductor fcc-$LaH_{10}$, here we…

Two-dimensional (2D) transition metal nitrides (TMNs) are new members in the 2D materials family with a wide range of applications. Particularly, highly crystalline and large area thin films of TMNs are potentially promising for…

Materials Science · Physics 2019-10-07 Jun Cao , Tianshu Li , Hongze Gao , Yuxuan Lin , Xingzhi Wang , Haozhe Wang , Tomás Palacios , Xi Ling

Transition metal nitrides have attracted much interest of the scientific community for their intriguing properties and technological applications. Here we focus on yttrium dinitride (YN$_{2}$) and its formation and structural transition…

Materials Science · Physics 2020-12-18 Francesca Menescardi , Emma Ehrenreich-Petersen , Davide Ceresoli

We search for new superhard B-N-O compounds with an iterative machine learning (ML) procedure, where ML models are trained using sample crystal structures from evolutionary algorithm. We first use cohesive energy to evaluate the…

Materials Science · Physics 2022-06-22 Wei-Chih Chen , Yogesh K. Vohra , Cheng-Chien Chen

Amorphous materials offer unique functional characteristics, which are often not observed in their crystalline counterparts. This makes them invaluable for many technological applications, such as diffusion barriers in semiconductor…

Materials Science · Physics 2024-12-03 O. V. Pshyk , S. Zhuk , J. Patidar , A. Wieczorek , A. Sharma , J. Michler , C. Cancellieri , V. Stevanovic , S. Siol

Layered transition-metal tellurides have attracted considerable attention because of their rich physics; for example, tungsten ditelluride WTe2 exhibits extremely large magnetoresistance; the tritelluride ZrTe3 shows a charge density wave…

Binary transition metal nitride with a graphene-like structure and strong magnetic properties is rare. Based on the first-principles calculations, we design two kinds of $M$N$_4$ ($M$ =transition metal) monolayers, which are transition…

Materials Science · Physics 2024-06-19 Shuo Zhang , Panjun Feng , Dapeng Liu , Hongfen Wu , Miao Gao , Tongshuai Xu , Xun-Wang Yan , Z. Y. Xie

Using the data on the superconducting critical temperature ($T_{C}$) for a number of metal hydrides, we found a rule that makes it possible to predict the maximum $T_{C}$ based only on the information about the electronic structure of metal…

Hydrogen-rich hydrides attract great attention due to recent theoretical (1) and then experimental discovery of record high-temperature superconductivity in H3S (Tc = 203 K at 155 GPa (2)). Here we search for stable uranium hydrides at…

Transition Metal Nitrides are a versatile class of materials, combining chemical robustness, high hardness, and superconducting behaviour with critical temperatures between 2 to 10 K. While several binary TMNs have been explored,…

The theoretical exploration of the phase diagrams of binary hydrides under pressure using \emph{ab initio} crystal structure prediction techniques coupled with first-principles calculations has led to the \emph{in silico} discovery of…

Superconductivity · Physics 2019-02-25 Eva Zurek , Tiange Bi

Over the past decade, a combination of crystal structure prediction techniques and experimental synthetic work has thoroughly explored the phase diagrams of binary hydrides under pressure. The fruitfulness of this dual approach is…

Superconductivity · Physics 2022-02-21 Katerina P. Hilleke , Eva Zurek

The abundant chemical compositions in ternary hydrides bring much more possibility to explore high temperature superconductors under lower pressure. Here we constructed 115 ternary hydrides on the basis of the elements substitution using 16…

Superconductivity · Physics 2024-11-19 Bangshuai Zhu , Dexi Shao , Cuiying Pei , Qi Wang , Juefei Wu , Yanpeng Qi

Recent high-throughput computational searches have predicted many novel ternary nitride compounds providing new opportunities for materials discovery in under explored phase spaces. Nevertheless, there are hardly any predictions and/or…

Recent discovery of superconductive rare earth/actinide superhydrides has ushered in a new era of superconductivity research at high pressures. This distinct type of clathrate metal hydrides was first proposed for alkaline-earth-metal…

Stable compounds in the V-N system are systematically searched and four new high-pressure phases are found, including C2/m-V$_9$N, Pbam-V$_5$N$_2$, Pnma-V$_2$N and I4/mcm-VN$_2$. V$_2$N undergoes a phase transition from…

Materials Science · Physics 2020-03-03 Jin Zhang , Xinfeng Li , Xiao Dong , Huafeng Dong , Artem R. Oganov

We survey the landscape of binary hydrides across the entire periodic table from 10 to 500 GPa using a crystal structure prediction method. Building a critical temperature ($T_c$) model, with inputs arising from density of states…

Superconductivity · Physics 2021-08-11 Alice M. Shipley , Michael J. Hutcheon , Richard J. Needs , Chris J. Pickard