Related papers: Equilibrium contact angle and adsorption layer pro…
The study of wetting phenomena is of great interest due to the multifaceted technological applications of hydrophobic and hydrophilic surfaces. The theoretical approaches proposed by Wenzel and later by Cassie and Baxter to describe the…
With most of the focus to date having been on the coalescence of freely suspended droplets, much less is known about the coalescence of sessile droplets, especially in the case of droplets laden with surfactant. Here, we employ large-scale…
We examine the nanoscale behavior of an equilibrium three-phase contact line in the presence of long-ranged intermolecular forces by employing a statistical mechanics of fluids approach, namely density functional theory (DFT) together with…
The equilibrium shape of liquid drops on elastic substrates is determined by minimising elastic and capillary free energies, focusing on thick incompressible substrates. The problem is governed by three length scales: the size of the drop…
We derive a continuum sharp-interface model for moving contact lines with soluble surfactants in a thermodynamically consistent framework. The model consists of the isothermal two-phase incompressible Navier-Stokes equations for the fluid…
We present a model based on the lattice Boltzmann equation that is suitable for the simulation of dynamic wetting. The model is capable of exhibiting fundamental interfacial phenomena such as weak adsorption of fluid on the solid substrate…
Wettability is the affinity of a liquid for a solid surface. For energetic reasons, macroscopic drops of liquid are nearly spherical away from interfaces with solids, and any local deformations due to molecular-scale surface interactions…
In this paper, we investigate the dynamics of an incompressible viscous Navier-Stokes fluid evolving above a one-dimensional flat surface. The fluid is subject to a uniform gravitational field and capillary forces acting along the free…
Wettability quantifies the affinity of a liquid over a substrate, and determines whether the surface is repellent or not. When both the liquid and the solid phases are made of the same chemical substance and are at thermal equilibrium,…
We study the dynamics of contact angle of a droplet of binary solution evaporating on a super wetting surface. Recent experiments show that although equilibrium contact angle of such droplet is zero, the contract angle can show complex time…
The contact angle of a liquid drop on a rigid surface is determined by the classical theory of Young-Laplace. For chemically homogeneous surfaces, this angle is a constant. We study the minimal-energy configurations of liquid drops on rough…
Viscoelasticity and rate-dependent adhesion of soft matter lead to difficulties in modeling the 'relatively simple' problem of a rigid sphere in contact with a viscoelastic half-space. For this reason, approximations in describing surface…
We consider the spreading of a thin two-dimensional droplet on a solid substrate. We use a model for viscous fluids where the evolution is governed by Darcy's Law. At the triple point where air and liquid meet the solid substrate, the…
We study the dynamics and equilibrium profile shapes of contact lines for wetting in the case of a spatially inhomogeneous solid wall with stripe defects. Using a phase-field model with conserved dynamics, we first numerically determine the…
Young's classic analysis of the equilibrium of a three-phase contact line ignores the out-of-plane component of the liquid-vapor surface tension. While it has long been appreciated that this unresolved force must be balanced by elastic…
In the classic theory of solid adhesion, surface energy drives deformation to increase contact area while bulk elasticity opposes it. Recently, solid surface stress has been shown also to play an important role in opposing deformation of…
The contact line (CL) is where solid, liquid and vapor phases meet, and Young's equation describes the macroscopic force balance of the interfacial tensions between these three phases. These interfacial tensions are related to the nanoscale…
The line tension of an electrolyte wetting a non-polar substrate is computed analytically and numerically. The results show that, depending on the value of the apparent contact angle, positive or negative line tension values may be…
When a drop of liquid comes into contact with a solid surface, it relaxes towards an equilibrium configuration, either wetting the surface or remaining in a droplet-like shape with a finite contact angle. The force driving the process…
Quantifying wettability at the nanoscale remains challenging, as macroscopic contact-angle measurements fail to capture the molecular interactions that define hydrophilic and hydrophobic behavior. We derive an analytical relation linking…