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The work is necessitated by search for new materials to detect ionizing radiation. The rare-earth ions doped with ternary alkali earth-halide systems are promising scintillators showing high efficiency and energy resolution. Some aspects of…

Materials Science · Physics 2017-08-01 R. Shendrik , A. Myasnikova , A. Shalaev , A. Bogdanov , E. Kaneva , A. Rusakov , A. Vasilkovskyi

Luminescence in Eu$^{2+}$ activated materials corresponds to a transition from an excited state where the lowest Eu 5$d$ level is filled with one electron (often called the (Eu$^{2+}$)$^*$ state) to the ground state with half-filled 4$f$…

Materials Science · Physics 2014-08-12 A. Chaudhry , R. Boutchko , S. Chourou , G. Zhang , N. Grønbech-Jensen , A. Canning

TlSr2I5: Eu2+ is a newly discovered scintillator and show promising scintillation properties for X- and {\gamma}-rays spectroscopy applications. Two zones vertical Bridgman technique is used for the growth of this scintillator. Luminescence…

Instrumentation and Detectors · Physics 2017-09-18 H. J. Kim , Gul Rooh , Arshad Khan , H. Park , Sunghwan Kim

Within the framework of the virtual crystal method implemented in the shell model and pair potential approximation the crystal structure of mixed fluorites Ca(1-x)Sr(x)F(2) and Sr(1-x)Ba(x)F(2) has been calculated. The impurity center…

Materials Science · Physics 2009-11-07 A. E. Nikiforov , A. Yu. Zaharov , V. A. Chernyshev , M. Yu. Ougrumov , S. V. Kotomanov

The luminescence of fifteen representative Eu$^{2+}$-doped phosphors used for white-LED and scintillation applications is studied through a Constrained Density Functional Theory. Transition energies and Stokes shift are deduced from…

Materials Science · Physics 2017-09-20 Yongchao Jia , Anna Miglio , Samuel Poncé , Masayoshi Mikami , Xavier Gonze

We investigated the Li+ ion incorporation in Ba2GdNbO6:Eu3+ perovskite by atomistic simulations based on energy minimization. We predicted the most probable sites occupied by Eu3+ and Li+ ions and the related charge-compensation mechanisms…

We investigate native point defects and rare-earth (co)dopants in SrAl$_2$O$_4$ using hybrid density-functional defect calculations. Europium (Eu) and dysprosium (Dy) are found to be mixed valence and energetically most favorable at the Sr…

Materials Science · Physics 2023-02-24 Khang Hoang

The incorporation of Eu into the diamond lattice is investigated in a combined theoretical-experimental study. The large size of the Eu ion induces a strain on the host lattice, which is minimal for the Eu-vacancy complex. The oxidation…

Materials Science · Physics 2019-04-24 Danny E. P. Vanpoucke , Shannon S. Nicley , Jorne Raymakers , Wouter Maes , Ken Haenen

Lanthanides are vital components in lighting, imaging technologies and future quantum memory applications due to their narrow optical transitions and long spin coherence times. Recently, diamond has become a preeminent platform for…

Materials Science · Physics 2015-06-18 Andrew Magyar , Wenhao Hu , Toby Shanley , Michael E. Flatte , Evelyn Hu , Igor Aharonovich

We present measurements of the optical spectra on single crystals of spinel-type compound \cis. This material undergoes a sharp metal-insulator transition at 230 K. Upon entering the insulating state, the optical conductivity shows an…

Strongly Correlated Electrons · Physics 2009-11-10 N. L. Wang , G. H. Cao , P. Zheng , G. Li , Z. Fang , T. Xiang , H. Kitazawa , T. Matsumoto

In the present study, structural changes due to gradual doping of Sr in BaTiO3 were investigated by both x-ray and neutron powder diffraction techniques. Ba1-xSrxTiO3 (x=0.0, 0.5 and 1.0) samples were synthesized by PVA evaporation method…

Materials Science · Physics 2020-07-03 I. B. Elius , B. M. Asif , J. Maudood , T. K. Datta , A. K. M. Zakaria , S. Hossain , M. S. Aktar , I. Kamal

K$_2$YF$_5$ crystals doped with lanthanide ions have a variety of possible optical applications. Owing to the low symmetry of the system, the crystal structure cannot be unambiguously determined by x-ray diffraction. However,…

Materials Science · Physics 2024-09-27 Pratik S. Solanki , Michael F. Reid , Jon-Paul R. Wells

The enhancement of Er$^{3+}$-based up-conversion for photovoltaics in multilayer porous silicon photonic structures is considered theoretically and experimentally. Transfer matrix simulations are used to assess the increased photonic…

Optics · Physics 2012-09-06 Craig M. Johnson , Peter J. Reece , Gavin J. Conibeer

First principles calculations of rare earth (RE)-doped LaSi3N5 host lattice are performed to obtain the electronic structure, the band gap (BG), and the character of electronic transitions. Doping with both trivalent and bivalent RE cations…

Materials Science · Physics 2015-06-23 Ismail A. M. Ibrahim , Zoltan Lences , Pavol Sajgalik , Lubomir Benco , Martijn Marsman

Lanthanide-doped Y$_{2}$SiO$_{5}$ microcrystals were prepared using the solution combustion, solid state and sol-gel synthesis techniques. Of these, the sol-gel method yields the most reliable and high-quality X2 phase Y$_{2}$SiO$_{5}$…

Materials Science · Physics 2024-09-26 Jamin L. B. Martin , Lily F. Williams , Michael F. Reid , Jon-Paul R. Wells

Single-layer TaS$_2$ is epitaxially grown on Au(111) substrates. The resulting two-dimensional crystals adopt the 1H polymorph. The electronic structure is determined by angle-resolved photoemission spectroscopy and found to be in excellent…

A strontium iodide crystal doped by europium (SrI2(Eu)) was produced by using the Stockbarger growth technique. The crystal was subjected to a characterization that includes relative photoelectron output and energy resolution for gamma…

The band gap energy as well as the possibility of cross luminescence processes in alkaline-earth dihalide crystals have been calculated using the ab initio Perturbed-Ion (PI) model. The gap is calculated in several ways: as a difference…

Materials Science · Physics 2009-10-31 Andres Aguado , Andres Ayuela , Jose M. Lopez , Julio A. Alonso

Electronic band structure and optical properties of zinc monochalcogenides with zinc-blende- and wurtzite-type structures were studied using the ab initio density functional method within the LDA, GGA, and LDA+U approaches. Calculations of…

Soft Condensed Matter · Physics 2009-11-13 S. Zh. Karazhanov , P. Ravindran , A. Kjekshus , H. Fjellvag , B. G. Svensson

The electrodynamic properties of Ba(Fe$_{0.92}$Co$_{0.08})_2$As$_{2}$ and Ba(Fe$_{0.95}$Ni$_{0.05})_As$_{2}$ single crystals have been investigated by reflectivity measurements in a wide frequency range. In the metallic state, the optical…

Superconductivity · Physics 2010-10-22 N. Barišić , D. Wu , M. Dressel , L. J. Li , G. H. Cao , Z. A. Xu
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