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We present a numerical implementation of the gauge-invariant time-dependent configuration interaction singles (TDCIS) method [Appl. Sci. 8, 433 (2018)] for three-dimensional atoms. In our implementation, orbital-like quantity called channel…

Atomic Physics · Physics 2019-10-09 Takuma Teramura , Takeshi Sato , Kenichi L. Ishikawa

The time-dependent multiconfiguration self-consistent-field method based on the occupation-restricted multiple active space model is proposed (TD-ORMAS) for multielectron dynamics in intense laser fields. Extending the previously proposed…

Atomic Physics · Physics 2015-06-23 Takeshi Sato , Kenichi L. Ishikawa

Time-dependent quantum chemical methods coupled to Gaussian basis sets are gaining popularity in modeling the electron dynamics of atoms and molecules interacting with intense laser fields. Two approaches most widely used for this purpose,…

Chemical Physics · Physics 2023-01-18 Aleksander P. Woźniak , Maciej Lewenstein , Robert Moszyński

Gauge invariance was discovered in the development of classical electromagnetism and was required when the latter was formulated in terms of the scalar and vector potentials. It is now considered to be a fundamental principle of nature,…

We present a wave-function based method to solve the time-dependent many-electron Schr\"odinger equation (TDSE) with special emphasis on strong-field ionization phenomena. The theory builds on the configuration-interaction (CI) approach…

Quantum Physics · Physics 2014-12-11 Sebastian Bauch , Lasse Kragh Sørensen , Lars Bojer Madsen

In this work, a derivation and implementation of the relativistic time-dependent configuration interaction singles (RTDCIS) method is presented. Various observables for krypton and xenon atoms obtained by RTDCIS are compared with…

Atomic Physics · Physics 2022-01-12 Felipe Zapata , Jimmy Vinbladh , Anton Ljungdahl , Eva Lindroth , Jan Marcus Dahlström

The time-dependent restricted-active-space self-consistent-field singles (TD-RASSCF-S) method is presented for investigating TD many-electron dynamics in atoms and molecules. Adopting the SCF notion from the muticonfigurational TD…

Atomic Physics · Physics 2014-05-22 Haruhide Miyagi , Lars Bojer Madsen

Time-dependent coupled-cluster method with time-varying orbital functions, called time-dependent optimized coupled- cluster (TD-OCC) method, is formulated for multielectron dynamics in an intense laser field. We have successfully derived…

Chemical Physics · Physics 2018-03-14 Takeshi Sato , Himadri Pathak , Yuki Orimo , Kenichi L. Ishikawa

We present a new formulation of the time-dependent self-interaction correction (TDSIC). It is derived variationally obeying explicitly the constraints on orthonormality of the occupied single-particle orbitals. The thus emerging rather…

Quantum Physics · Physics 2009-03-02 J. Messud , P. M. Dinh , P. -G. Reinhard , E. Suraud

The time-dependent restricted-active-space self-consistent-field (TD-RASSCF) method is formulated based on the TD variational principle. In analogy with the configuration-interaction singles (CIS), singles-and-doubles (CISD),…

Quantum Physics · Physics 2014-06-26 Haruhide Miyagi , Lars Bojer Madsen

We present the extension of the time-dependent configuration interaction singles (TDCIS) method to the computation of the electron kinetic-energy spectrum in photoionization processes. Especially for strong and long ionizing light pulses…

Atomic Physics · Physics 2014-04-17 Antonia Karamatskou , Stefan Pabst , Yi-Jen Chen , Robin Santra

Gauge invariance is one of the more important concepts in physics. We discuss this concept in connection with the unitary evolution of discrete-time quantum walks in one and two spatial dimensions, when they include the interaction with…

Quantum Physics · Physics 2025-02-28 Iván Márquez-Mártin , Pablo Arnault , Giuseppe Di Molfetta , Armando Pérez

We present the time-dependent complete-active-space self-consistent-field (TD-CASSCF) method to simulate multielectron dynamics in ultrafast intense laser fields from the first principles. While based on multiconfiguration expansion, it…

Atomic Physics · Physics 2018-04-24 Takeshi Sato , Yuki Orimo , Takuma Teramura , Oyunbileg Tugs , Kenichi L. Ishikawa

Simulations of laser-induced electron dynamics in a molecular system are performed using time-dependent (TD) equation-of-motion (EOM) coupled-cluster (CC) theory. The target system has been chosen to highlight potential shortcomings of…

Chemical Physics · Physics 2023-08-09 Stephen H. Yuwono , Brandon C. Cooper , Tianyuan Zhang , Xiaosong Li , A. Eugene DePrince

The time-dependent equation-of-motion coupled cluster (TD-EOM-CC) and time-dependent coupled cluster (TDCC) methods are compared by simulating Rabi oscillations for different numbers of non-interacting atoms in a classical electromagnetic…

Chemical Physics · Physics 2023-10-02 Andreas S. Skeidsvoll , Henrik Koch

Quantum simulations of High Energy Physics, and especially of gauge theories, is an emerging and exciting direction in quantum simulations. However, simulations of such theories, compared to simulations of condensed matter physics, must…

Quantum Physics · Physics 2013-08-29 Erez Zohar , J. Ignacio Cirac , Benni Reznik

We investigate the Dirac time-dependent variational method using a Gaussian trial functional for an infinite one dimensional system of Bosons interacting through a repulsive contact interaction. The method produces a set of non-linear time…

Condensed Matter · Physics 2009-10-30 Arthur K. Kerman , Paolo Tommasini

Variational symplectic algorithms have recently been developed for carrying out long-time simulation of charged particles in magnetic fields. As a direct consequence of their derivation from a discrete variational principle, these…

Plasma Physics · Physics 2015-06-18 Jonathan Squire , Hong Qin , William M. Tang

We calculate the high-harmonic generation (HHG) spectra, strong-field ionization, and time-dependent dipole-moment of Ne using explicitly time-dependent optimized second-order many-body perturbation method (TD-OMP2) where both orbitals and…

Chemical Physics · Physics 2020-08-18 Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa

We present a new method to describe the kinetics of driven lattice gases with particle-particle interactions beyond hard-core exclusions. The method is based on the time-dependent density functional theory for lattice systems and allows one…

Statistical Mechanics · Physics 2015-05-20 Marcel Dierl , Philipp Maass , Mario Einax
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