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Speed of state transitions in macroscopic systems is a crucial concept for foundations of nonequilibrium statistical mechanics as well as various applications in quantum technology represented by optimal quantum control. While extensive…

Statistical Mechanics · Physics 2022-04-29 Ryusuke Hamazaki

Thermoelectric efficiency is defined as the ratio of power delivered to the load of a device to the rate of heat flow from the source. Till date, it has been studied in presence of thermodynamic constraints set by the Onsager reciprocal…

Mesoscale and Nanoscale Physics · Physics 2015-12-17 Hangbo Zhou , Juzar Thingna , Peter Hänggi , Jian-Sheng Wang , Baowen Li

We show that the system entropy change for the transitions between non-equilibrium steady states arbitrarily far from equilibrium for any constituting process is given by the relative entropy of the distributions of these steady states.…

Statistical Mechanics · Physics 2012-05-29 G. Baris Bagci , Ugur Tirnakli , Juergen Kurths

A stochastic process, when subject to resetting to its initial condition at a constant rate, generically reaches a non-equilibrium steady state. We study analytically how the steady state is approached in time and find an unusual relaxation…

Statistical Mechanics · Physics 2015-05-29 Satya N. Majumdar , Sanjib Sabhapandit , Gregory Schehr

Using the recently derived Dissipation Theorem and a corollary of the Transient Fluctuation Theorem (TFT), namely the Second Law Inequality, we derive the unique time independent, equilibrium phase space distribution function for an ergodic…

Statistical Mechanics · Physics 2015-05-13 Denis J. Evans , Debra J. Searles , Stephen R. Williams

We build a rigorous nonequilibrium thermodynamic description for open chemical reaction networks of elementary reactions. Their dynamics is described by deterministic rate equations satisfying mass action law. Our most general framework…

Statistical Mechanics · Physics 2017-01-13 Riccardo Rao , Massimiliano Esposito

A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The…

Quantum Physics · Physics 2007-10-25 Dorje C. Brody , Daniel W. Hook , Lane P. Hughston

Near equilibrium, thermodynamic intuition suggests that fast, irreversible processes will dissipate more energy and entropy than slow, quasistatic processes connecting the same initial and final states. Here, we test the hypothesis that…

Statistical Mechanics · Physics 2022-12-07 Rebecca A. Bone , Daniel J. Sharpe , David J. Wales , Jason R. Green

In the real world, one almost never knows the parameters of a thermodynamic process to infinite precision. Reflecting this, here we investigate how to extend stochastic thermodynamics to systems with uncertain parameters, including…

Statistical Mechanics · Physics 2021-03-17 Jan Korbel , David H. Wolpert

Adiabaticity is a cornerstone of many promising approaches to quantum control, computing, and simulation. In practice, however, there is always a trade-off. Although the deleterious effects of noise can be diminished by running a control…

Quantum Physics · Physics 2025-06-23 Pavel Zhelnin , Lucas Johns , Carlos A. Argüelles

The study of feedback control inspired by Maxwell's demon is central to the understanding of the relationship between thermodynamics and information. In this paper, we establish fundamental lower limits on the work costs of system…

Quantum Physics · Physics 2026-03-10 Kaiyuan Ji , Gilad Gour , Mark M. Wilde

A stochastic procedure is developed which allows one to express Pontryagin's maximum principle for dissipative quantum system solely in terms of stochastic wave functions. Time-optimal controls can be efficiently computed without computing…

Quantum Physics · Physics 2020-11-09 Chungwei Lin , Dries Sels , Yanting Ma , Yebin Wang

For a two-level quantum mechanical system, we derive microscopically the exact expression for the fluctuation of microscopic work in a multi-step non-equilibrium process, and we rigorously prove that in an isothermal process, the…

Statistical Mechanics · Physics 2008-08-19 H. T. Quan , S. Yang , C. P. Sun

The study of thermodynamic fluctuations allows one to relate the free energy difference between two equilibrium states with the work done on a system through processes far from equilibrium. This finding plays a crucial role in the quantum…

The most complicated phenomena of equilibrium statistics, phase separations and transitions of various order and critical phenomena, can clearly and sharply be seen even for small systems in the topology of the curvature of the…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

It is well-known in thermodynamics that the creation of correlations costs work. It seems then a truism that if a thermodynamic transformation A->B is impossible, so will be any transformation that in sending A to B also correlates among…

Quantum Physics · Physics 2015-10-13 Matteo Lostaglio , Markus P. Mueller , Michele Pastena

This paper aims to establish second order necessary conditions for optimal control in quantum stochastic systems. We employ a variational approach, analogous to methods in classical stochastic control, to analyze systems governed by quantum…

Optimization and Control · Mathematics 2026-03-17 Penghui Wang , Shan Wang

We study the convergence to equilibrium of an underdamped Langevin equation that is controlled by a linear feedback force. Specifically, we are interested in sampling the possibly multimodal invariant probability distribution of a Langevin…

Optimization and Control · Mathematics 2022-01-12 Tobias Breiten , Carsten Hartmann , Lara Neureither , Upanshu Sharma

Thermodynamic speed limits are a set of classical uncertainty relations that, so far, place global bounds on the stochastic dissipation of energy as heat and the production of entropy. Here, instead of constraints on these thermodynamic…

Statistical Mechanics · Physics 2023-02-13 Erez Aghion , Jason R. Green

The real-time dynamics of the Fermi-Hubbard model, driven out of equilibrium by quenching or ramping the interaction parameter, is studied within the framework of the nonequilibrium self-energy functional theory. A dynamical impurity…

Strongly Correlated Electrons · Physics 2016-06-03 Felix Hofmann , Martin Eckstein , Michael Potthoff