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We study the enantio-specific state transfer in a four-level model for symmetric-top chiral molecules. Such a model is formed by coupling the electric-dipole transitions among four appropriate working states with three electromagnetic…

Quantum Physics · Physics 2022-04-27 Bo Liu , Chong Ye , C. P. Sun , Yong Li

We explore the spatial enantioseparation of gaseous chiral molecules for the cyclic three-level systems coupled with three electromagnetic fields. Due to molecular rotations, the specific requirements of the polarization directions of the…

Atomic Physics · Physics 2021-11-16 Bo Liu , Chong Ye , C. P. Sun , Yong Li

Enantio-conversion with the help of electromagnetic fields is an essential issue due to the chirality-dependence of many chemical, biological, and pharmaceutical processes. Here, we propose a method for this issue based on a five-level…

Quantum Physics · Physics 2021-03-03 Chong Ye , Bo Liu , Yu-Yuan Chen , Yong Li

Three-wave mixing spectroscopy of chiral molecules, which exist in left-handed and right-handed conformations, allows for enantio-selective population transfer despite random orientation of the molecules. This is based on constructive…

Quantum Physics · Physics 2019-07-09 Monika Leibscher , Thomas F. Giesen , Christiane P. Koch

Based on cyclic three-level systems of chiral molecules, we propose two methods to realize highly efficient inner-state enantio-separations of a chiral mixture with the two enantiomers initially prepared in their ground states. Our methods…

Optics · Physics 2019-10-16 Chong Ye , Quansheng Zhang , Yu-Yuan Chen , Yong Li

We propose an enantio-detection method of chiral molecules in a cavity with external drive. The chiral molecules are coupled with a quantized cavity field and two classical light fields to form the cyclic three-level systems. The…

Quantum Physics · Physics 2022-02-15 Yu-Yuan Chen , Jian-Jian Cheng , Chong Ye , Yong Li

We propose to discriminate chiral molecules by combining one- and two-photon processes in a closed-loop configuration. The one-photon-coupling intrinsic {\pi}-phase difference between two enantiomers leads to their different superposition…

Quantum Physics · Physics 2020-02-20 Jin-Lei Wu , Yan Wang , Jie Song , Yan Xia , Shi-Lei Su , Yong-Yuan Jiang

We derive a pulse-area theorem for a cyclic three-level system, an archetypal model for exploring enantioselective state transfer (ESST) in chiral molecules driven by three linearly polarized microwave pulses. By dividing the closed-loop…

Quantum Physics · Physics 2022-01-12 Yu Guo , Xun Gong , Songshan Ma , Chuan-Cun Shu

Enantiodetection is an important and challenging task across natural science. Nowadays, some chiroptical methods of enantiodetection based on decoherence-free cyclic three-level models of chiral molecules can reach the ultimate limit of the…

Quantum Physics · Physics 2022-11-29 Chong Ye , Xiaowei Mu , Yifan Sun , Libin Fu , Xiangdong Zhang

Based on the four-level double-$\Delta$ model composed of two degenerated (left- and right-handed) chiral ground states and two achiral excited states, we propose a purely optical method for enantio-conversion of chiral mixture. By choosing…

Optics · Physics 2020-08-05 Chong Ye , Quansheng Zhang , Yu-Yuan Chen , Yong Li

Chiral discrimination that is efficient to tiny amounts of chiral substances, especially at the single-molecule level, is highly demanded. Here, we propose a single-shot nondestructive quantum sensing method addressing such an issue. Our…

Quantum Physics · Physics 2023-10-05 Chong Ye , Yifan Sun , Yong Li , Xiangdong Zhang

Microwave three-wave mixing allows for enantiomer-selective excitation of randomly oriented chiral molecules into rotational states with different energy. The random orientation of molecules is reflected in the degeneracy of the rotational…

Quantum Physics · Physics 2022-08-02 Monika Leibscher , Jonas Kalveram , Christiane P. Koch

We propose a method to realize enantiodiscrimination of chiral molecules based on quantum correlation function in a driven cavity-molecule system, where the chiral molecule is coupled with a quantized cavity field and two classical light…

Quantum Physics · Physics 2022-08-12 Fen Zou , Yu-Yuan Chen , Bo Liu , Yong Li

An interesting class of molecules is that in which the molecules do not possess a stereogenic center but can become chiral due to their spatial arrangement. These molecules can be seen as chiral conformers, whose two non-superimposable…

Chemical Physics · Physics 2021-06-11 Cristóbal Pérez , Amanda L. Steber , Anna Krin , Melanie Schnell

We present a new coil design paradigm for magnetic confinement in stellarators. Our approach directly optimizes coil shapes and coil currents to produce a vacuum quasi-symmetric magnetic field with a target rotational transform on the…

Plasma Physics · Physics 2022-03-17 Andrew Giuliani , Florian Wechsung , Antoine Cerfon , Georg Stadler , Matt Landreman

Pulse flip angles are calculated for three wave mixing, three state cycles of chiral molecules to produce optimized free induction decay amplitudes proportional to the enantiomeric excess of a sample, and to produced optimized degree of…

Chemical Physics · Physics 2018-11-02 Kevin K. Lehmann

We propose a new type of a chiral metamaterial based on an ensemble of artificial molecules formed by three identical quantum-dots in a triangular arrangement. A static magnetic field oriented perpendicular to the plane breaks mirror…

Mesoscale and Nanoscale Physics · Physics 2014-12-04 Panagiotis Kotetes , Pei-Qing Jin , Michael Marthaler , Gerd Schön

Chiral molecules with broken parity symmetries can be modeled as quantum systems with cyclic-transition structures. By using these novel properties, we design two-step laser pulses to distinguish left- and right-handed molecules from the…

Quantum Physics · Physics 2015-05-19 W. Z. Jia , L. F. Wei

We present a systematic understanding of the rotational structure of a long-range (vibrationally highly-excited) diatomic molecule. For example, we show that depending on a quantum defect, the least-bound vibrational state of a diatomic…

Atomic Physics · Physics 2009-11-10 Bo Gao

Optical methods of enantiomeric-specific state transfer had been proposed theoretically based on a cyclic three-level system of chiral molecule. According to these theoretical methods, recently the breakthrough progress has been reported in…

Quantum Physics · Physics 2020-11-16 Quansheng Zhang , Chong Ye , Yu-Yuan Chen , Yong Li
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