Related papers: Dual free energies in Poisson-Boltzmann theory
The Poisson-Boltzmann (PB) theory is widely used to depict ionic systems. As a mean-field theory, the PB theory neglects the correlation effect in the ionic atmosphere and leads to deviations from experimental results as the concentration…
A new method ( PI-DFT ) which combines path integrals and density functional theory is proposed as a pathway to many fields of physics. Within path integral theory it is possible to construct particle densities without explicitly…
We study in this paper the ground state energy of a free bosonic theory on a finite interval of length $R$ with either a pair of sine-Gordon type or a pair of Kondo type interactions at each boundary. This problem has potential applications…
Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…
We present a continuation of our theoretical research into the influence of co-solvent polarizability on a differential capacitance of the electric double layer [EPL 111, 28002 (2015)]. We formulate a modified Poisson-Boltzmann theory,…
Poisson-Boltzmann (PB) theory is the classic approach to soft matter electrostatics which has been applied to numerous problems of physical chemistry and biophysics. Its essential limitations are the neglect of correlation effects and of…
The description of a conducting medium in thermal equilibrium, such as an electrolyte solution or a plasma, involves nonlinear electrostatics, a subject rarely discussed in the standard electricity and magnetism textbooks. We consider in…
This paper presents the perturbation theory for the double--sine--Gordon equation. We received the system of differential equations that shows the soliton parameters modification under perturbation's influence. In particular case…
We formulate the non-linear field theory for a fluctuating counter-ion distribution in the presence of a fixed, arbitrary charge distribution. The Poisson-Boltzmann equation is obtained as the saddle-point, and the effects of fluctuations…
Poisson-Boltzmann theory is the cornerstone for soft matter electrostatics. We provide novel exact analytical solutions to this non-linear mean-field approach, for the diffuse layer of ions in the vicinity of a planar or a cylindrical…
An effective field theory exists describing a very large class of biophysically interesting Coulomb gas systems: the lowest order (mean-field) version of this theory takes the form of a generalized Poisson-Boltzmann theory. Interaction…
We develop a general theory of a boson decomposition for both local and non-local interactions in lattice fermion models which allows us to describe fermionic degrees of freedom and collective charge and spin excitations on equal footing.…
We present an exact field theoretical representation of an ionic solution made of charged hard spheres. The action of the field theory is obtained by performing a Hubbard-Stratonovich transform of the configurational Boltzmann factor. It is…
We consider a dilute homogeneous mixture of bosons and spin-polarized fermions at zero temperature. We first construct the formal scheme for carrying out systematic perturbation theory in terms of single particle Green's functions. We…
The classical Poisson-Boltzmann equation (CPBE), which is a mean field theory by averaging the ion fluctuation, has been widely used to study ion distributions in charged fluids. In this study, we derive a modified Poisson-Boltzmann…
We introduce and study one parameter family of integrable quantum field theories. This family has a Lagrangian description in terms of massive Thirring fermions $\psi,\psi^{\dagger}$ and charged bosons $\chi,\bar{\chi}$ of complex…
The Poisson-Boltzmann (PB) equation provides a mean-field theory of electrolyte solutions at interfaces and in confinement, describing how ions reorganize close to charged surfaces to form the so-called electrical double layer (EDL), with…
A manifestly gauge-invariant hamiltonian formulation of classical electrodynamics has been shown to be relativistic invariant by the construction of the adequate generators of the Poincare Lie algebra [Physica, 76, No. 3, 421-444 (1974)].…
We consider the two-dimensional quantum field theory of a scalar field self-interacting via two periodic terms of frequencies $\alpha$ and $\beta$. Looking at the theory as a perturbed Sine-Gordon model, we use Form Factor Perturbation…
Given a Hamiltonian system on a fiber bundle, there is a Poisson covariant formulation of the Hamilton equations. When a Lie group G acts freely, properly, preserving the fibers of the bundle and the Hamiltonian density is G-invariant, we…