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39 detailed mechanisms for combustion of hydrogen, carbon monoxide and methanol are investigated using ReactionKinetics, a Mathematica based package. The obtained results in most cases do not depend on the choice of reaction rate…

Chemical Physics · Physics 2013-08-06 J. Tóth , A. L. Nagy , I. Zsély

Forest fires pose a natural threat with devastating social, environmental, and economic implications. The rapid and highly uncertain rate of spread of wildfires necessitates a trustworthy digital tool capable of providing real-time…

The limited availability of accurate experimental data in wide ranges of pressure, temperature, and composition is the main constraining factor for the proper development and assessment of thermodynamic models and equations of state. In the…

Simulations of pulverised coal combustion rely on various models, required in order to correctly approximate the flow, chemical reactions, and behavior of solid particles. These models, in turn, rely on multiple model parameters, which are…

Chemical Physics · Physics 2021-02-24 Ahmed Hassan , Taraneh Sayadi , Vincent LeChenadec , Heinz Pitsch , Antonio Attili

In this work, we introduce DeepFlame, an open-source C++ platform with the capabilities of utilising machine learning algorithms and pre-trained models to solve for reactive flows. We combine the individual strengths of the computational…

Fluid Dynamics · Physics 2023-07-17 Runze Mao , Minqi Lin , Yan Zhang , Tianhan Zhang , Zhi-Qin John Xu , Zhi X. Chen

Numerical computations employing detailed chemistry are used to characterize the different combustion modes emerging in mixing layers separating nitrogen-diluted counterflowing planar streams of hydrogen and oxygen. Attention is focused on…

Fluid Dynamics · Physics 2024-07-01 Jaime Carpio , Prabakaran Rajamanickam , Antonio L. Sánchez , Forman A. Williams

We examine several different simplified approaches for modelling the chemistry of CO in three-dimensional numerical simulations of turbulent molecular clouds. We compare the different models both by looking at the behaviour of integrated…

Astrophysics of Galaxies · Physics 2015-05-27 S. C. O. Glover , P. C. Clark

A basic model of hydrogen bonds related to $\rm{H}_2\rm{O}$, which is adapted from the Jaynes--Cummings model, is suggested, and its different dynamic features are studied theoretically. In this model, the making and breaking of hydrogen…

Quantum Physics · Physics 2025-08-14 Jiangchuan You , Ran Chen , Wanshun Li , Hui-hui Miao , Yuri Igorevich Ozhigov

We use local diffusion maps to assess the quality of two types of collective variables (CVs) for a recently published hydrogen combustion benchmark dataset~\cite{guan2022benchmark} that contains ab initio molecular dynamics trajectories and…

Chemical Physics · Physics 2023-04-20 Taehee Ko , Joseph Heindel , Xingyi Guan , Teresa Head-Gordon , David Williams-Young , Chao Yang

The use of machine learning algorithms to predict behaviors of complex systems is booming. However, the key to an effective use of machine learning tools in multi-physics problems, including combustion, is to couple them to physical and…

Lattice dynamics and molecular dynamics studies of the oxides UO2 and Li2O in their normal as well as superionic phase are reported. Lattice dynamics calculations have been carried out using a shell model in the quasiharmonic approximation.…

Materials Science · Physics 2011-11-10 Prabhatasree Goel , N. Choudhury , S. L. Chaplot

Aims. We define a small and large chemical network which can be used for the quantitative simultaneous analysis of molecular emission from the near-IR to the submm. We revise reactions of excited molecular hydrogen, which are not included…

Solar and Stellar Astrophysics · Physics 2017-11-15 Inga Kamp , Wing-Fai Thi , Peter Woitke , Christian Rab , Sietske Bouma , Francois Menard

Light-matter interactions lie at the heart of our exploration of exoplanetary atmospheres. Interpreting data obtained by remote sensing is enabled by meticulous, time- and resource-consuming work aiming at deepening our understanding of…

Earth and Planetary Astrophysics · Physics 2025-03-06 Laurent Wiesenfeld , Prajwal Niraula , Julien de Wit , Nejmeddine Jaïdane , Iouli E. Gordon , Robert J. Hargreaves

Astrochemical surface reactions are thought to be responsible for the formation of complex organic molecules, which are of potential importance for the origin of life. In a situation, when the chemical composition of dust surfaces is not…

Chemical Physics · Physics 2022-11-09 Thomas K. Henning , Serge A. Krasnokutski

This paper introduces WhereWulff, a semi-autonomous workflow for modeling the reactivity of catalyst surfaces. The workflow begins with a bulk optimization task that takes an initial bulk structure, and returns the optimized bulk geometry…

Materials Science · Physics 2023-03-01 Rohan Yuri Sanspeur , Javier Heras-Domingo , John R. Kitchin , Zachary Ulissi

We present a model-based real-time method to monitor a counterflow heat exchanger's thermal performance for all operating conditions. A first principle reference model that describes the reference counterflow process in an accurate manner…

Systems and Control · Electrical Eng. & Systems 2021-02-16 Maik Gentsch , Rudibert King

The decomposition and chemical dynamics for vibrationally excited syn-CH$_3$CHOO is followed based on statistically significant numbers of molecular dynamics simulations. Using a neural network-based reactive potential energy surface,…

Chemical Physics · Physics 2023-07-07 Meenu Upadhyay , Kai Töpfer , Markus Meuwly

For the design and optimization of CO2 recovery from alcoholic fermentation processes by distillation, models for vapor-liquid equilibria (VLE) are needed. Two such thermodynamic models, the Peng-Robinson equation of state (EOS) and a model…

Chemical Physics · Physics 2015-05-13 J. Vrabec , G. K. Kedia , U. Buchhauser , R. Meyer-Pittroff , H. Hasse

Large quantifies of online user activity data, such as weekly web search volumes, which co-evolve with the mutual influence of several queries and locations, serve as an important social sensor. It is an important task to accurately…

Social and Information Networks · Computer Science 2022-09-20 Taichi Murayama , Yasuko Matsubara , Yasushi Sakurai

We present a history matching (HM) workflow applied to the International FluidFlower benchmark study dataset, which features high-resolution images of CO$_2$ storage in a meter-scale, geologically complex reservoir. The dataset provides…