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If a local Hamiltonian eigenstate is mapped to another state by local operators commuting with the Hamiltonian terms, the latter is also an eigenstate. This basic observation implies a no-go result for both being a unique ground state and…

Quantum Physics · Physics 2025-10-31 Jose Garre Rubio

We demonstrate the existence of different density-density functionals designed to retain selected properties of the many-body ground state in a non-interacting solution starting from the standard density functional theory ground state. We…

Other Condensed Matter · Physics 2009-11-13 F. A. Reboredo , P. R. C. Kent

An ensemble Green's function formalism, based on the von Neumann density matrix approach, to calculate one-electron excitation spectra of a many-electron system with degenerate ground states is proposed. A set of iterative equations for the…

Strongly Correlated Electrons · Physics 2019-12-24 Erik Linnér , Ferdi Aryasetiawan

We consider an isolated macroscopic quantum system in a pure state $\psi_t$ evolving unitarily in a separable Hilbert space $\mathcal{H}$ and take for granted that different macro states $\nu$ correspond to mutually orthogonal subspaces…

Mathematical Physics · Physics 2026-01-05 Cornelia Vogel

Recent work has established Moreau-Yosida regularization as a mathematical tool to achieve rigorous functional differentiability in density-functional theory. In this article, we extend this tool to paramagnetic current-density-functional…

In systems subject to periodic boundary conditions, Haldane has shown that states at arbitrary filling fraction possess a degeneracy with respect to center of mass translations. An analysis is carried out for multi-component electron…

Condensed Matter · Physics 2009-10-22 I. A. McDonald

A framework for developing new approximate electronic structure methods is presented, in which the correlation energy of a many-electron system in the ground state is computed as in the single-reference second-order many-body perturbation…

Chemical Physics · Physics 2011-06-15 Dimitri Laikov

We present modified Wang-Landau algorithm for models with continuous degrees of freedom. We demonstrate this algorithm with the calculation of the joint density of states $g(M,E)$ of ferromagnet Heisenberg models. The joint density of…

Statistical Mechanics · Physics 2009-11-11 Chenggang Zhou , T. C. Schulthess , Stefan Torbrügge , D. P. Landau

We reexamine the recently introduced basis-set correction theory based on density-functional theory consisting in correcting the basis-set incompleteness error of wave-function methods using a density functional. We use a one-dimensional…

Chemical Physics · Physics 2022-02-16 Diata Traore , Emmanuel Giner , Julien Toulouse

A degenerate variant of mean field perturbation theory for the on-site Bose-Hubbard Hamiltonian is presented. We split the perturbation into two terms and perform exact diagonalization in the two-dimensional subspace corresponding to the…

Quantum Gases · Physics 2016-05-11 A. M. Belemuk , V. N. Ryzhov

We begin by deriving bounds for the entanglement of a spin with an (adjacent and non-adjacent) interval of spins in an arbitrary pure Finitely Correlated States (FCS). The bounds we derive become exact in the case where one considers the…

Quantum Physics · Physics 2008-07-31 Spyridon Michalakis

Wavefunction structure is analyzed for dense interacting many-boson systems using Hamiltonian $H$, which is a sum of one-body $h(1)$ and an embedded GOE of $k$-body interaction $V(k)$ with strength $\lambda$. In the first analysis, a…

Statistical Mechanics · Physics 2021-04-07 Priyanka Rao , N. D. Chavda

Strong correlations within a symmetry-unbroken ground-state wavefunction can show up in approximate density functional theory as symmetry-broken spin-densities or total densities, which are sometimes observable. They can arise from soft…

Strongly Correlated Electrons · Physics 2021-04-28 John P. Perdew , Adrienn Ruzsinszky , Jianwei Sun , Niraj K. Nepal , Aaron D. Kaplan

We calculate the electronic states of Al$_x$Ga$_{1-x}$As/GaAs/Al$_x$Ga$_{1-x}$As double heterojunctions subjected to a magnetic field parallel to the quasi two-dimensional electron gas. We study the energy dispersion curves, the density of…

Materials Science · Physics 2014-01-03 C. Simserides

We study the pairing Hamiltonian in a set of non degenerate levels. First, we review in the path integral framework the spontaneous breaking of the U(1) symmetry occurring in such a system for the degenerate situation. Then the behaviors…

Nuclear Theory · Physics 2008-11-26 M. B. Barbaro , R. Cenni , S. Chiacchiera , A. Molinari , F. Palumbo

The standard model of classical Density Functional Theory for pair potentials consists of a hard-sphere functional plus a mean-field term accounting for long ranged attraction. However, most implementations using sophisticated Fundamental…

Computational Physics · Physics 2021-01-04 James F. Lutsko , Cédric Schoonen

A density-matrix formalism is developed based on the one-particle density-matrix of a single-determinantal reference-state. The v-representable problem does not appear in the proposed method, nor the need to introduce functionals defined by…

Chemical Physics · Physics 2009-11-10 James P. Finley

Sun et al. [J. Chem. Phys. 144, 191101 (2016)] suggested that common density functional approximations (DFAs) should exhibit large energy errors for excited states as a necessary consequence of orbital nodality. Motivated by…

Computational Physics · Physics 2022-11-09 Sebastian Schwalbe , Kai Trepte , Susi Lehtola

From known phase diagram regions of different model Hamiltonians describing strongly correlated systems we deduced new domains of the ground state phase diagram of the same model by an unitary transformation. Different types of extended…

Strongly Correlated Electrons · Physics 2017-08-23 E Kovacs , Zs. Gulacsi

One of the central problems in quantum mechanics is to determine the ground state properties of a system of electrons interacting via the Coulomb potential. Since its introduction by Hohenberg, Kohn, and Sham, Density Functional Theory…

Quantum Physics · Physics 2010-09-28 Norbert Schuch , Frank Verstraete
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