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We introduce ELECTRAFI, a fast, end-to-end differentiable model for predicting periodic charge densities in crystalline materials. ELECTRAFI constructs anisotropic Gaussians in real space and exploits their closed-form Fourier transforms to…

Materials Science · Physics 2026-01-29 Jonas Elsborg , Felix Ærtebjerg , Luca Thiede , Alán Aspuru-Guzik , Tejs Vegge , Arghya Bhowmik

This paper is concerned with the fast computation of Fourier integral operators of the general form $\int_{\R^d} e^{2\pi\i \Phi(x,k)} f(k) d k$, where $k$ is a frequency variable, $\Phi(x,k)$ is a phase function obeying a standard…

Numerical Analysis · Mathematics 2008-09-05 Emmanuel Candes , Laurent Demanet , Lexing Ying

The commutator direct inversion of the iterative subspace (commutator DIIS or C-DIIS) method developed by Pulay is an efficient and the most widely used scheme in quantum chemistry to accelerate the convergence of self consistent field…

Computational Physics · Physics 2017-08-23 Wei Hu , Lin Lin , Chao Yang

While quantum computers have shown significant promise for electronic structure calculations, their potential to accelerate density functional theory (DFT) calculations remains unclear. In this work, we present a qubit-efficient encoding…

The energy density functional (EDF) method is very widely used in nuclear physics, and among the various existing functionals those based on the relativistic Hartree (RH) approximation are very popular because the exchange contributions…

Nuclear Theory · Physics 2014-05-16 Nguyen Van Giai , Haozhao Liang , Huai-Qiang Gu , Wenhui Long , Jie Meng

Quantum ESPRESSO is an integrated suite of open-source computer codes for quantum simulations of materials using state-of-the art electronic-structure techniques, based on density-functional theory, density-functional perturbation theory,…

In this paper, we develop a robust fast method for mobile-immobile variable-order (VO) time-fractional diffusion equations (tFDEs), superiorly handling the cases of small or vanishing lower bound of the VO function. The valid fast…

Numerical Analysis · Mathematics 2022-06-22 Jia-Li Zhang , Zhi-Wei Fang , Hai-Wei Sun

For many-body methods such as MCSCF and CASSCF, in which the number of one-electron orbitals are optimized and independent of basis set used, there are no problems with using plane-wave basis sets. However, for methods currently used in…

Computational Physics · Physics 2020-09-02 Eric J. Bylaska , Duo Song , Nicholas P. Bauman , Karol Kowalski , Daniel Claudino , Travis S. Humble

Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…

Chemical Physics · Physics 2015-06-12 Jason D. Goodpaster , Taylor A. Barnes , Frederick R. Manby , Thomas F. Miller

The rapid adoption of low-precision arithmetic in artificial intelligence and edge computing has created a strong demand for energy-efficient and flexible floating-point multiply-accumulate (MAC) units. This paper presents a dual-precision…

Hardware Architecture · Computer Science 2026-04-10 Shubham Kumar , Vijay Pratap Sharma , Vaibhav Neema , Santosh Kumar Vishvakarma

We propose an adaptive planewave method for eigenvalue problems in electronic structure calculations. The method combines a priori convergence rates and accurate a posteriori error estimates into an effective way of updating the energy…

Computational Physics · Physics 2021-07-30 Beilei Liu , Huajie Chen , Geneviève Dusson , Jun Fang , Xingyu Gao

We introduce an energy functional for ground-state electronic structure calculations. Its variables are the natural spin-orbitals of singlet many-body wave functions and their joint occupation probabilities deriving from controlled…

Chemical Physics · Physics 2016-12-04 Ralph Gebauer , Morrel H. Cohen , Roberto Car

We discuss our new implementation of the Real-space Electronic Structure method for studying the atomic and electronic structure of infinite periodic as well as finite systems, based on density functional theory. This improved version which…

Materials Science · Physics 2009-10-31 U. V. Waghmare , Hanchul Kim , I. J. Park , Normand Modine , P. Maragakis , Efthimios Kaxiras

We present an approach to accelerate real-space electronic structure methods several fold, without loss of accuracy, by reducing the dimension of the discrete eigenproblem that must be solved. To accomplish this, we construct an efficient,…

Computational Physics · Physics 2018-05-01 Qimen Xu , Phanish Suryanarayana , John E. Pask

Kohn-Sham density functional theory (DFT) is nowadays widely used for electronic structure theory simulations, and the accuracy and efficiency of DFT rely on approximations of the exchange-correlation functional. By inclusion of the kinetic…

Materials Science · Physics 2023-06-01 Renxi Liu , Daye Zheng , Xinyuan Liang , Xinguo Ren , Mohan Chen , Wenfei Li

As the performance gains from accelerating quantized matrix multiplication plateau, the softmax operation becomes the critical bottleneck in Transformer inference. This bottleneck stems from two hardware limitations: (1) limited data…

Machine Learning · Computer Science 2026-02-03 Zisheng Ye , Xiaoyu He , Maoyuan Song , Guoliang Qiu , Chao Liao , Chen Wu , Yonggang Sun , Zhichun Li , Xiaoru Xie , Yuanyong Luo , Hu Liu , Pinyan Lu , Heng Liao

We introduce an approximate phase-space technique to simulate the quantum dynamics of interacting bosons. With the future goal of treating Bose-Einstein condensate systems, the method is designed for systems with a natural separation into…

Quantum Physics · Physics 2009-11-13 Scott E. Hoffmann , Joel F. Corney , Peter D. Drummond

Hybrid density functional (HDF) approximations usually deliver higher accuracy than local and semilocal approximations to the exchange-correlation functional, but this comes with drastically increased computational cost. Practical…

Materials Science · Physics 2022-10-12 Yuyang Ji , Peize Lin , Xinguo Ren , Lixin He

In this paper, we propose Fourier pseudospectral methods to solve the variable-order space fractional wave equation and develop an accelerated matrix-free approach for its effective implementation. In constant-order cases, our methods can…

Numerical Analysis · Mathematics 2024-02-06 Yanzhi Zhang , Xiaofei Zhao , Shiping Zhou

This paper proposes several explicit and implicit multistep frequency response optimized integrators considering first or second order derivative. A prediction-based method aiming at accelerating a novel power system transient simulation…

Systems and Control · Electrical Eng. & Systems 2021-02-16 Sheng Lei , Alexander Flueck