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We present a density functional theory (DFT) based supercell approach for modeling small polarons with proper account for the long-range elastic response of the material. Our analysis of the supercell dependence of the polaron properties…

Materials Science · Physics 2018-04-18 Sebastian Kokott , Sergey V Levchenko , Patrick Rinke , Matthias Scheffler

We propose a harmonic linear response (HLR) method to calculate the phonon dispersion relations of two-dimensional (2D) layers from equilibrium simulations at finite temperature. This HLR approach is based on the linear response of the…

Mesoscale and Nanoscale Physics · Physics 2020-01-14 R. Ramirez , C. P. Herrero

Molecular-level understanding of the interactions between the constituents of an atomic structure is essential for designing novel materials in various applications. This need goes beyond the basic knowledge of the number and types of…

There is enormous recent interest in weak, van der Waals-type (vdW) interactions due to their fundamental relevance for two-dimensional materials and the so-called vdW heterostructures. Tackling this problem using computer simulation is…

Materials Science · Physics 2019-08-20 Fabian Schulz , Peter Liljeroth , Ari Paavo Seitsonen

Density functional theory (DFT) is notorious for the absence of gradient corrections to the two-dimensional (2D) Thomas-Fermi kinetic-energy functional; it is widely accepted that the 2D analog of the 3D von Weizs\"acker correction…

We present the full in-plane phonon dispersion of graphite obtained from inelastic x-ray scattering, including the optical and acoustic branches, as well as the mid-frequency range between the $K$ and $M$ points in the Brillouin zone, where…

Materials Science · Physics 2009-11-13 M. Mohr , J. Maultzsch , E. Dobardzic , S. Reich , I. Milosevic , M. Damnjanovic , A. Bosak , M. Krisch , C. Thomsen

On the basis of the self-consistent phonon theory and the special displacement method, we develop an approach for the treatment of anharmonicity in solids. We show that this approach enables the efficient calculation of…

Materials Science · Physics 2023-08-09 Marios Zacharias , George Volonakis , Feliciano Giustino , Jacky Even

At the heart of current information nanotechnology lies the search for ideal platforms hosting the smallest possible magnets, i.e. single atoms with magnetic moments pointing out-of-plane, as requested in a binary-type of memory. For this…

Density functional theory (DFT) can run into serious difficulties with localized states in elements such as transition metals with occupied-d states and oxygen. In contrast, Hartree-Fock (HF) method can be a better approach for such…

Materials Science · Physics 2018-08-01 Hengxin Tan , Yuanchang Li , S. B. Zhang , Wenhui Duan

The simultaneous influence of electronic correlations and magnetic ordering on the theoretical estimation of phonons and related properties of Ni is investigated. The work includes a comparative DFT and DFT+U study, where on-site Coulomb…

Strongly Correlated Electrons · Physics 2023-07-13 Shivani Bhardwaj , Sudhir K. Pandey

We study the principal aspects of the interaction between acoustic phonons and two-dimensional electrons in quantizing magnetic fields corresponding to even denominator fractions. Using the composite fermion approach we derive the vertex of…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 D. V. Khveshchenko , M. Reizer

Density functional theory (DFT), the most widely adopted method in modern computational chemistry, fails to describe accurately the electronic structure of strongly correlated systems. Here we show that DFT can be formally and practically…

Chemical Physics · Physics 2022-04-18 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

Interest in the bulk transition metal dichalcogenides for their electronic, photovoltaic, and optical properties has grown and led to their use in many technological applications. We present a systematic investigation of their interlinked…

Using density functional theory (DFT), Hartree-Fock, exact diagonalization, and numerical renormalization group methods we study the electronic structure of diluted hydrogen atoms chemisorbed on graphene. A comparison between DFT and…

Mesoscale and Nanoscale Physics · Physics 2012-03-07 J. O. Sofo , Gonzalo Usaj , P. S. Cornaglia , A. M. Suarez , A. D. Hernández-Nieves , C. A. Balseiro

The radiative heat transfer between two dielectrics can be strongly enhanced in the near field in the presence of surface phonon-polariton resonances. Nevertheless, the spectral mismatch between the surface modes supported by two dissimilar…

Mesoscale and Nanoscale Physics · Physics 2017-07-07 Riccardo Messina , Philippe Ben-Abdallah , Brahim Guizal , Mauro Antezza

In this paper I show how the statistics of the gravitational field is changed when the system is characterized by a non-uniform distribution of particles. I show how the distribution functions W(dF/dt) giving the joint probability that a…

Astrophysics · Physics 2009-11-13 A. Del Popolo

A real-space formalism for density-functional perturbation theory (DFPT) is derived and applied for the computation of harmonic vibrational properties in molecules and solids. The practical implementation using numeric atom-centered…

Materials Science · Physics 2017-03-08 Honghui Shang , Christian Carbogno , Patrick Rinke , Matthias Scheffler

Phonons play a critical role in determining various material properties, but conventional methods for phonon calculations are computationally intensive, limiting their broad applicability. In this study, we present an approach to accelerate…

Materials Science · Physics 2024-07-16 Huiju Lee , Vinay I. Hegde , Chris Wolverton , Yi Xia

Anharmonic effects in an atomic monolayer thin crystal with honeycomb lattice structure are investigated by analytical and numerical lattice dynamical methods. Starting from a semi-empirical model for anharmonic couplings of third and…

Materials Science · Physics 2015-05-20 K. H. Michel , S. Costamagna , F. M. Peeters

Classical density functional theory (DFT) is a statistical mechanical theory for calculating the density profiles of the molecules in a liquid. It is widely used, for example. to calculate the density distribution of the molecules in the…

Statistical Mechanics · Physics 2015-07-08 Adam P. Hughes , Uwe Thiele , Andrew J. Archer