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Motivated from recent experiments in kappa-(BEDT-TTF)_2Cu_2(CN)_3, dielectric and magnetic properties in a dimer-Mott insulator are studied. We derive the effective Hamiltonian where the number of electron per dimer is taken to be one.…

Strongly Correlated Electrons · Physics 2010-03-01 Makoto Naka , Sumio Ishihara

We report a detailed examination the magnetic structure of anhydrous cupric chloride CuCl2 carried out by powder neutron diffraction, magnetic susceptibility and specific heat measurements on polycrystalline and single crystal samples as…

Strongly Correlated Electrons · Physics 2009-04-21 M. G. Banks , R. K. Kremer , C. Hoch , A. Simon , B. Ouladdiaf , J. -M. Broto , H. Rakoto , C. Lee , M. -H. Whangbo

A new-type structural transition has been found in Li2RuO3 with honeycomb lattice of edge-sharing RuO6-octahedra. With decreasing temperature T, the electrical resistivity exhibits an anomalous increase at T=Tc~540 K, suggesting the (metal…

Strongly Correlated Electrons · Physics 2015-06-25 Yoko Miura , Yukio Yasui , Masatoshi Sato , Naoki Igawa , Kazuhisa Kakurai

In RuCl$_3$, inelastic neutron scattering and Raman spectroscopy reveal a continuum of non-spin-wave excitations that persists to high temperature, suggesting the presence of a spin liquid state on a honeycomb lattice. In the context of the…

The layered Mott insulator ${\alpha}$-RuCl${_3}$ has been extensively studied as a potential Kitaev quantum spin liquid candidate. Here, by constructing heterostructures with graphite, we employed electron tunneling measurements on…

Strongly Correlated Electrons · Physics 2023-05-08 Xiaohu Zheng , Ke Jia , Junhai Ren , Chongli Yang , Xingjun Wu , Youguo Shi , Katsumi Tanigaki , Rui-Rui Du

GdFe3(BO3)4 exhibits a structural phase transition at 156 K, antiferromagnetic order of the Fe3+ moments at 36 K followed by a spin reorientation phase transition at 9 K. The reorientation phase transition is studied through dielectric,…

Strongly Correlated Electrons · Physics 2009-11-11 F. Yen , B. Lorenz , Y. Y. Sun , C. W. Chu , L. N. Bezmaternykh , A. N. Vasiliev

The low-temperature magnetic phases in the layered honeycomb lattice material $\alpha$-RuCl$_3$ have been studied as a function of in-plane magnetic field. In zero field this material orders magnetically below 7 K with so-called zigzag…

Strongly Correlated Electrons · Physics 2017-06-07 J. A. Sears , Y. Zhao , Z. Xu , J. W. Lynn , Young-June Kim

We perform Raman spectroscopy studies on $\alpha$-RuCl$_3$ at room temperature to explore its phase transitions of magnetism and chemical bonding under pressures. The Raman measurements resolve two critical pressures, about $p_1=1.1$~GPa…

Creating heterostructures with graphene/graphite is a practical method for charge-doping $\alpha$-RuCl$_3$, but not sufficient to cause the insulator-to-metal transition. In this study, detailed scanning tunneling microscopy/spectroscopy…

Strongly Correlated Electrons · Physics 2024-01-05 Xiaohu Zheng , Ogasawara Takuma , Huaxue Zhou , Chongli Yang , Xin Han , Gang Wang , Junhai Ren , Youguo Shi , Katsumi Tanigaki , Rui-Rui Du

We present initial Raman spectroscopy experiments on exfoliated flakes of $\alpha$-RuCl$_3$, from tens of nm thick down to single layers. Besides unexpectedly finding this material to be air stable, in the thinnest layers we observe the…

Strongly Correlated Electrons · Physics 2019-12-11 Boyi Zhou , Yiping Wang , Gavin B. Osterhoudt , Paige Kelly , David Mandrus , Rui He , Kenneth S. Burch , Erik A. Henriksen

Low-temperature thermal conductivity (\kappa), as well as magnetization (M) and electric polarization (P), of multiferroic orthoferrite DyFeO_3 single crystals are studied with H \parallel c. When the crystal is cooled in zero field, M, P,…

Strongly Correlated Electrons · Physics 2014-06-11 Z. Y. Zhao , X. Zhao , H. D. Zhou , F. B. Zhang , Q. J. Li , C. Fan , X. F. Sun , X. G. Li

Measurements of ferroelectric polarization and dielectric constant were done on $R$Mn$_2$O$_5$ ($R$=Tb, Dy, and Ho) with applied hydrostatic pressures of up to 18 kbar. At ambient pressure, distinctive anomalies were observed in the…

Strongly Correlated Electrons · Physics 2009-11-13 C. R. dela Cruz , B. Lorenz , Y. Y. Sun , Y. Wang , S. Park , S-W. Cheong , M. M. Gospodinov , C. W. Chu

The crystallographic and magnetic properties of the cleavable 4d3 transition metal compound a-MoCl3 are reported, with a focus on the behavior above room temperature. Crystals were grown by chemical vapor transport and characterized using…

The authors of paper commented claim that trimethylammonium tetrachlorozincate crystal shows at 282 K the ferroelectric-paraelectric phase transition. But no ferroelectric hysteresis loop was observed below this temperature. Moreover, in…

Materials Science · Physics 2016-04-07 Zbigniew Tylczynski

The magnetic susceptibility between 1.5 and 800 K, the infrared reflectivity at room temperature and the temperature dependence of the dielectric constant at mm-wavelengths are reported for single crystalline BiFeO3. A well developed…

Strongly Correlated Electrons · Physics 2010-07-22 Jun Lu , M Schmidt , P Lunkenheimer , A Pimenov , A A Mukhin , V D Travkin , A Loidl

Motivated by the possibility of an intermediate U(1) quantum spin liquid phase in out-of-plane magnetic fields and enhanced magnetic fluctuations in exfoliated {\alpha}-RuCl3 flakes, we study magneto-Raman spectra of exfoliated multilayer…

The magnetism of Kitaev materials has been widely studied, but their charge properties and the coupling to other degrees of freedom are less known. Here we investigate the charge states of $\alpha$-RuCl$_3$, a promising Kitaev quantum spin…

Strongly Correlated Electrons · Physics 2024-08-27 Xiaohu Zheng , Zhengxin Liu , Cuiwei Zhang , Huaxue Zhou , Chongli Yang , Youguo Shi , Katsumi Tanigaki , Rui-Rui Du

Magnetization and high-resolution x-ray diffraction measurements of the Kitaev-Heisenberg material alpha-RuCl3 reveal a pressure-induced crystallographic and magnetic phase transition at a hydrostatic pressure of p=0.2 GPa. This structural…

In the class of materials called spin liquids, a magnetically ordered state cannot be attained even at milliKelvin temperatures because of conflicting constraints on each spin (for e.g. from geometric or exchange frustration). The resulting…

$\alpha$-RuCl$_3$ is a candidate Kitaev material that exhibits zigzag antiferromagnetic ordering below 7 K. One contentious issue regarding this material is its bulk structure in the low-temperature phase. Recently, it has become generally…

Materials Science · Physics 2026-01-27 Seung-Ju Hong , Tae Yun Kim , Cheol-Hwan Park