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Kondo insulator like material FeSb2 was found to exhibit colossal Seebeck coefficient. It would have had huge potential in thermoelectric applications in cryogenic temperature range if it had not been for the large thermal conductivity.…

Materials Science · Physics 2011-02-03 Kefeng Wang , Rongwei Hu , C. Petrovic

We present measurements of resistivity and thermopower of Fe1+xTe1-ySey single crystalline samples with y=0, 0.1, 0.2, 0.3 and 0.45 in zero field and in a magnetic field B=8T. We propose a qualitative analysis of the temperature behavior of…

Superconductivity · Physics 2009-12-10 I. Pallecchi , G. Lamura , M. Tropeano , M. Putti , R. Viennois , E. Giannini , D. Van der Marel

Organic semiconductors have attracted increasing interest as thermoelectric converters in recent years due to their intrinsically low thermal conductivity compared to inorganic materials. This boom has led to encouraging practical results,…

Materials Science · Physics 2021-03-08 Dorothea Scheunemann , Martijn Kemerink

Thermoelectrics are a promising class of materials for renewable energy owing to their capability to generate electricity from waste heat, with their performance being governed by a competition between charge and thermal transport. A…

We use first-principles electronic structure methods to calculate the electronic thermoelectric properties (i.e. due to electronic transport only) of single-crystalline bulk $n$-type silicon-germanium alloys vs Ge composition, temperature,…

Materials Science · Physics 2025-02-03 F. Murphy-Armando

The thermoelectric transport properties of CaMg2Bi2, EuMg2Bi2, and YbMg2Bi2 were characterized between 2 and 650K. As synthesized, the polycrystalline samples are found to have lower p-type carrier concentrations than single-crystalline…

Materials Science · Physics 2012-01-13 A. F. May , M. A. McGuire , J. Ma , O. Delaire , A. Huq , D. J. Singh , W. Cai , H. Wang

We report the thermoelectric (TE) properties of Na$_{0.74}$Co$_{0.95}$Nb$_{0.05}$O$_{2}$ in the temperature range $300-1200$ K, as a potential candidate for p-type thermoelectric material. The experimental values of Seebeck coefficient (S)…

Strongly Correlated Electrons · Physics 2019-11-18 Arzena Khatun , Shamim Sk , Jayashree Pati , R. S. Dhaka , Sudhir K. Pandey

The unique structure of Zintl phase makes it an ideal system to realize the concept of phonon-glass and electron-crystal in the thermoelectric community. In this work, by combining first-principles calculations and Boltzmann transport…

Materials Science · Physics 2017-08-01 S. Huang , H. J. Liu , D. D. Fan , P. H. Jiang , J. H. Liang , G. H. Cao , J. Shi

We present systematic theoretical results on thermoelectric effects in semimetals based on the variational method of the linearized Boltzmann equation. Inelastic electron-hole scattering is known to play an important role in the unusual…

Strongly Correlated Electrons · Physics 2023-03-31 Keigo Takahashi , Hiroyasu Matsuura , Hideaki Maebashi , Masao Ogata

The efficiency of energy conversion in thermoelectric generators (TEGs) is directly proportional to electrical conductivity and Seebeck coefficient while inversely to thermal conductivity. The challenge is to optimize these interdependent…

By using a first-principles approach, monolayer PbI$_2$ is found to have great potential in thermoelectric applications. The linear Boltzmann transport equation is applied to obtain the perturbation to the electron distribution by different…

Materials Science · Physics 2021-05-24 Bo Peng , Haodong Mei , Hao Zhang , Hezhu Shao , Ke Xu , Gang Ni , Qingyuan Jin , Costas M. Soukoulis , Heyuan Zhu

The thermopower $\alpha$ (also known as the Seebeck coefficient) is one of the most fundamental material characteristics for understanding charge carrier transport in thermoelectric materials. Here, we revisit the Pisarenko formula for the…

Materials Science · Physics 2025-12-16 Andrei Novitskii , Takao Mori

Silicon carbide nanoparticles with diameters around 8 nm and with narrow size distribution have been finely mixed with doped silicon nanopowders and sintered into bulk samples to investigate the influence of nanoinclusions on electrical and…

Materials Science · Physics 2021-10-27 S. Aria Hosseini , Devin Coleman , Sabah Bux , P. Alex Greaney , Lorenzo Mangolini

Substitution of Sb in FeSb$_2$ by less than 0.5% of Te induces a transition from a correlated semiconductor to an unconventional metal with large effective charge carrier mass $m^*$. Spanning the entire range of the semiconductor-metal…

Materials Science · Physics 2016-08-14 P. Sun , M. Søndergaard , Y. Sun , S. Johnsen , B. B. Iversen , F. Steglich

Recently, $\mathrm{BaSn_2}$ is predicted to be a strong topological insulator by the first-principle calculations. It is well known that topological insulator has a close connection to thermoelectric material, such as $\mathrm{Bi_2Te_3}$…

Materials Science · Physics 2016-12-21 San-Dong Guo , Liang Qiu

Bipolar carrier transport is often a limiting factor in the thermoelectric efficiency of narrow bandgap materials at high temperatures due to the reduction in the Seebeck coefficient and the introduction of an additional term to the thermal…

Materials Science · Physics 2019-03-27 Samuel Foster , Neophytos Neophytou

A polycrystalline sample of the MgB_2 superconductor was investigated by measurements of the electrical resistivity, the thermopower and the thermal conductivity in the temperature range between 1.8K and 300K in zero magnetic field. The…

We examined the electrical transport properties of densified LaOBiS2-xSex, which constitutes a new family of thermoelectric materials. The power factor increased with increasing concentration of Se, i.e., Se substitution led to an enhanced…

Materials Science · Physics 2016-06-22 Atsuhiro Nishida , Hirotaka Nishiate , Chul-Ho Lee , Osuke Miura , Yoshikazu Mizuguchi

We report a strategy based on introduction of point defects for improving the thermoelectric properties of FeSb2, a promising candidate for low temperature applications. Introduction of Sb deficiency to the tune of 20% leads to enhancement…

Materials Science · Physics 2015-05-01 Anup V. Sanchela , Ajay D. Thakur , C. V. Tomy

We report here metal to insulator transition, colossal Seebeck coefficient and ultralow thermal conductivity (0.0057th of its bulk value, significantly smaller than many well-known thermoelectric materials and silicon, showing potential…

Materials Science · Physics 2020-01-28 Vikash Sharma , Gunadhor Singh Okram , Yung-Kang Kuo
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