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The equilibrium phase behaviour of hard spheres with size polydispersity is studied theoretically. We solve numerically the exact phase equilibrium equations that result from accurate free energy expressions for the fluid and solid phases,…

Soft Condensed Matter · Physics 2007-05-23 M. Fasolo , P. Sollich

Population heterogeneity is ubiquitous among active living systems, but little is known about its role in determining their spatial organization and large-scale dynamics. Combining evidence from synthetic active fluids assembled from…

Soft Condensed Matter · Physics 2023-11-27 Samadarshi Maity , Alexandre Morin

A thin polymeric film in contact with a fluid body may leach low-molecular-weight compounds into the fluid. If this fluid is a small droplet, the compound concentration within the liquid increases due to ongoing leaching in combination with…

Soft Condensed Matter · Physics 2019-10-09 Thijs W. G. van der Heijden , Anton A. Darhuber , Paul van der Schoot

We investigate - with Monte Carlo computer simulations - the phase behaviour of dimeric colloidal molecules on periodic substrates with square symmetry. The molecules are formed in a two-dimensional suspension of like charged colloids…

Soft Condensed Matter · Physics 2015-06-04 Samir El Shawish , Emmanuel Trizac , Jure Dobnikar

From experimental studies it is well-known that colloidal particles suspended in a near-critical binary solvent exhibit interesting aggregation phenomena, often associated with colloidal phase transitions, and assumed to be driven by…

Soft Condensed Matter · Physics 2015-06-19 John R. Edison , Nikos Tasios , Simone Belli , Robert Evans , Rene van Roij , Marjolein Dijkstra

We consider a ternary mixture of hard colloidal spheres, ideal polymer spheres, and rigid vanishingly thin needles, which model stretched polymers or colloidal rods. For this model we develop a geometry-based density functional theory,…

Soft Condensed Matter · Physics 2009-11-07 Matthias Schmidt , Alan R. Denton

We consider the formation of finite-size domains in lipid bilayers consisting of saturated and hybrid lipids. First, we describe a monolayer model that includes a coupling between a compositional scalar field and a two-dimensional vectorial…

Soft Condensed Matter · Physics 2012-08-21 Yuichi Hirose , Shigeyuki Komura , David Andelman

Concentrated colloidal suspensions are a well-tested model system which has a glass transition. Colloids are suspensions of small solid particles in a liquid, and exhibit glassy behavior when the particle concentration is high; the…

Soft Condensed Matter · Physics 2010-10-01 Luca Cipelletti , Eric R. Weeks

This study uses a coarse-grained Monte Carlo algorithm to model and simulate the coadsorption of a binary mixture of counterionic colloids in Gibbs monolayers. These monolayers form at a idealized air-water interface, with one non-soluble…

Soft Condensed Matter · Physics 2024-03-25 J. M. Gómez-Verdú , B. Martínez-Haya , A. Cuetos

We investigate with Monte Carlo computer simulations the capillary phase behaviour of model colloid-polymer mixtures confined between a flat wall and a corrugated wall. The corrugation is modelled via a sine wave as a function of one of the…

Soft Condensed Matter · Physics 2014-06-20 Andrea Fortini , Matthias Schmidt

Depletion-induced interactions between colloids in colloid-polymer mixtures depend in range and strength on size, shape, and concentration of depletants. Crowding by colloids in turn affects shapes of polymer coils, such as biopolymers in…

Soft Condensed Matter · Physics 2016-02-25 Wei Kang Lim , Alan R. Denton

Using Brownian Dynamics (BD) simulations we investigate the non-equilibrium structure formation of a two-dimensional (2D) binary system of dipolar colloids propelling in opposite directions. Despite of a pronounced tendency for chain…

Soft Condensed Matter · Physics 2015-06-23 Florian Kogler , Sabine H. L. Klapp

We report molecular dynamics simulation results for two-component fluid mixtures of Gaussian-core particles, focusing on how tracer diffusivities and static pair correlations depend on temperature, particle concentration, and composition.…

Soft Condensed Matter · Physics 2009-11-04 Mark J. Pond , William P. Krekelberg , Vincent K. Shen , Jeffrey R. Errington , Thomas M. Truskett

Liquid polyamorphism is the intriguing possibility for a single component substance to exist in multiple liquid phases. We propose a minimal model for this phenomenon. Starting with a binary lattice model with critical azeotropy and…

Statistical Mechanics · Physics 2023-09-19 Frédéric Caupin , Mikhaïl A. Anisimov

Lateral microsegregation in a monolayer of a binary mixture of particles or macromolecules is studied by MD simulations in a generic model with the interacting potentials inspired by effective interactions in biological or soft-matter…

Soft Condensed Matter · Physics 2025-05-26 M. Litniewski , W. T. Gozdz nd A. Ciach

In conflict with standard notions of thermodynamics, mesoscopically-sized inclusions (``clusters'') of a solute-rich liquid have been observed in equilibrated solutions of proteins and other molecules. According to a complexation scenario…

Soft Condensed Matter · Physics 2025-09-11 Ilya Davydov , Vassiliy Lubchenko

The design of complex materials and the formation of specific patterns often arise from the properties of the individual building blocks. In this respect, colloidal systems offer a unique opportunity because nowadays they can be synthesized…

Soft Condensed Matter · Physics 2022-03-01 Fabrizio Camerin , Emanuela Zaccarelli

We consider binary mixtures of soft repulsive spherical particles and calculate the depletion interaction between two big spheres mediated by the fluid of small spheres, using different theoretical and simulation methods. The validity of…

Co-existence of phase segregation and \emph{interconversion} or \emph{isomerization} reaction among molecular species leads to fascinating structure formation in biological and chemical world. Using Monte Carlo simulations of the prototype…

Statistical Mechanics · Physics 2023-08-07 Shubham Thwal , Suman Majumder

The microscopic approach to the description of the phase behaviour and critical phenomena in binary fluid mixtures is proposed. It is based on the method of collective variables with a reference system. The physical nature of the order…

Condensed Matter · Physics 2009-10-31 O. V. Patsahan