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We consider stochastically modeled chemical reaction systems with mass-action kinetics and prove that a product-form stationary distribution exists for each closed, irreducible subset of the state space if an analogous deterministically…

Probability · Mathematics 2010-01-31 David F. Anderson , Gheorghe Craciun , Thomas G. Kurtz

We consider macroscopic systems in weak contact with boundary reservoirs and under the action of external fields. We present an explicit formula for the Hamiltonian of such systems, from which we deduce the equation of motions, the action…

Probability · Mathematics 2022-11-14 Angèle Bouley , Claudio Landim

We study nonequilibrium steady states of lattice gases with nearest-neighbor interactions that are driven between two reservoirs. Density profiles in these systems exhibit oscillations close to the reservoirs. We demonstrate that an…

Statistical Mechanics · Physics 2015-05-30 Marcel Dierl , Philipp Maass , Mario Einax

We show that intensive thermodynamic parameters associated to additive conserved quantities can be naturally defined from a statistical approach in far-from-equilibrium steady-state systems, under few assumptions, and without any detailed…

Statistical Mechanics · Physics 2007-05-23 Eric Bertin , Olivier Dauchot , Michel Droz

We describe the macroscopic behaviour of a particle system with long-range interactions. We describe conditions on the interaction strength in dependency of the distance of the particles, such that the scaling limit of the particle system…

Probability · Mathematics 2015-12-21 Anton Bovier , Carina Geldhauser

Systems of classical continuous particles in the grand canonical ensemble interacting through purely attractive, yet stable, interactions are defined. By a lattice approximation, FKG ferromagnetic inequalities are shown to hold for such…

Mathematical Physics · Physics 2007-05-23 H. Gottschalk

In this paper we consider an interacting particle system modeled as a system of $N$ stochastic differential equations driven by Brownian motions with a drift term including a confining potential acting on each particle, and an interaction…

Probability · Mathematics 2007-05-23 Matteo Ortisi

Investigation of simple far-from-equilibrium systems exhibiting phase separation leads to the conclusion that phase coexistence is not well defined in this context. This is because the properties of the coexisting nonequilibrium systems…

Statistical Mechanics · Physics 2016-02-11 Ronald Dickman

We search for steady states in a class of fluctuating and driven physical systems that exhibit sustained currents. We find that the physical concept of a steady state, well known for systems at equilibrium, must be generalised to describe…

Soft Condensed Matter · Physics 2020-04-15 Tanniemola B. Liverpool

A particle system with a single locally-conserved field (density) in a bounded interval with different densities maintained at the two endpoints of the interval is under study here. The particles interact in the bulk through a long range…

Probability · Mathematics 2012-10-02 Mustapha Mourragui , Enza Orlandi

Bridging equilibrium and nonequilibrium statistical physics attracts sustained interest. Hallmarks of nonequilibrium systems include a breakdown of detailed balance, and an absence of a priori potential function corresponding to the…

Statistical Mechanics · Physics 2015-04-24 Ying Tang , Ruoshi Yuan , Jianhong Chen , Ping Ao

We apply a recently proposed novel thermostating mechanism to an interacting many-particle system where the bulk particles are moving according to Hamiltonian dynamics. At the boundaries the system is thermalized by deterministic and…

chao-dyn · Physics 2009-10-31 C. Wagner , R. Klages , G. Nicolis

All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory which accounts for interactions between chemical species within a…

Statistical Mechanics · Physics 2021-03-09 Francesco Avanzini , Emanuele Penocchio , Gianmaria Falasco , Massimiliano Esposito

The electromagnetic interaction is characterised by discrete states for bound systems in contrast to continuous states for unbound systems. The difference merely arises because the characteristic equations do not exhibit the same behaviour…

General Physics · Physics 2007-05-23 Alasdair Macleod

Many references exist in the density functional theory (DFT) literature to the chemical potential of the electrons in an atom or a molecule. The origin of this notion has been the identification of the Lagrange multiplier $\mu = \partial…

Chemical Physics · Physics 2022-06-15 Evert Jan Baerends

We address the issue of extending thermodynamics to nonequilibrium steady states. Using driven stochastic lattice gases, we ask whether consistent definitions of an effective chemical potential mu, and an effective temperature T_e, are…

Statistical Mechanics · Physics 2015-06-18 Ronald Dickman , Ricardo Motai

We show that, in general, any complex weakly nonlinear highly multimode system can reach thermodynamic equilibrium that is characterized by a unique temperature and chemical potential. The conditions leading to either positive or negative…

We consider systems of n particles that move with constant velocity between collisions. Their total momentum but not necessarily their kinetic energy is preserved at collisions. As there are no further constraints, these systems are…

Mathematical Physics · Physics 2024-11-07 Andreas Knauf , Manuel Quaschner

We introduce a model of chemically active particles of a multi-component fluid that can change their interactions with other particles depending on their state. Since such switching of interactions can only be maintained by the input of…

Soft Condensed Matter · Physics 2019-05-01 Dino Osmanovic , Yitzhak Rabin

We study long-range interacting systems perturbed by external stochastic forces. Unlike the case of short-range systems, where stochastic forces usually act locally on each particle, here we consider perturbations by external stochastic…

Statistical Mechanics · Physics 2013-12-04 Cesare Nardini , Shamik Gupta , Stefano Ruffo , Thierry Dauxois , Freddy Bouchet