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We report a strategy based on introduction of point defects for improving the thermoelectric properties of FeSb2, a promising candidate for low temperature applications. Introduction of Sb deficiency to the tune of 20% leads to enhancement…

Materials Science · Physics 2015-05-01 Anup V. Sanchela , Ajay D. Thakur , C. V. Tomy

We investigate electronic structures and thermoelectric properties of recent synthetic half-Heusler $\mathrm{ZrNiPb}$ by using generalized gradient approximation (GGA) and GGA plus spin-orbit coupling (GGA+SOC). Calculated results show that…

Materials Science · Physics 2016-03-29 San-Dong Guo

The lattice thermal conductivity ($\kappa_{\rm L}$) of PbTiO$_3$ (PTO) is estimated using a combination of {\em ab initio} calculations and semiclassical Boltzmann transport equation. The computed $\kappa_{\rm L}$ is remarkably low, nearly…

Materials Science · Physics 2016-03-23 Anindya Roy

The thermoelectric properties and electronic band structures for Se-doped Co3SnInS2 were examined. The parent compound of this material (Co3Sn2S2) has two kinds of Sn sites (Sn1 and Sn2 sites). The density functional theory (DFT)…

It has been demonstrated that InSb nanoinclusions, which are formed in situ, can simultaneously improve all three individual thermoelectric properties of the n-type half Heusler compound (Ti,Zr,Hf)(Co,Ni)Sb [Xie et al., Acta Mater. 58, 4795…

We have investigated the effect of Sb-deficiency on the thermoelectric figure of merit (zT) of Zn4Sb3 prepared by solid state reaction route. At high temperatures, the Seebeck coefficient (S) and electrical conductivity ({\sigma}) increase…

Materials Science · Physics 2015-05-06 Anup V. Sanchela , Ajay D. Thakur , C. V. Tomy

Low temperature (<400 K) thermoelectric properties of semiconducting RuIn3 and metallic IrIn3 are reported. RuIn3 is a narrow band gap semiconductor with a large n-type Seebeck coefficient at room temperature (S(290K)~400 {\mu}V/K), but the…

Materials Science · Physics 2014-04-15 N. Haldolaarachchige , W. A. Phelan , Y. M. Xiong , R. Jin , J. Y. Chan , S. Stadler , D. P. Young

As-Based Zintl compounds Ba1-xKxCd2As2 crystallized in the CaAl2Si2-type structure (space group P3-m1) were prepared using solid-state reactions followed by hot-pressing. We have successfully substituted K for Ba up to x = 0.08, producing…

Materials Science · Physics 2018-11-28 H. Kunioka , K. Kihou , H. Nishiate , a A. Yamamoto , H. Usui , K. Kuroki , C. H. Lee

We investigated the electrical conductivity, thermal conductivity and thermopower as a function of Nb content (x) in Ba0.7Eu0.3Ti1-xNbxO3 (x = 0.001- 0.10) in the temperature range T = 400-2 K. The substitution of Nb destabilizes the…

Materials Science · Physics 2018-02-20 KmRubi , R. Mahendiran

We conduct comprehensive investigations of both thermal and electrical transport properties of SnSe and SnS using first-principles calculations combined with the Boltzmann transport theory. Due to the distinct layered lattice structure,…

Materials Science · Physics 2015-10-14 Ruiqiang Guo , Xinjiang Wang , Youdi Kuang , Baoling Huang

The lattice thermal conductivity of the candidate thermoelectric material Mg$_3$Sb$_2$ is studied from first principles, with the inclusion of anharmonic, isotope, and boundary scattering processes, and via an accurate solution of the…

Materials Science · Physics 2018-12-11 Maria Barbara Maccioni , Roberta Farris , Vincenzo Fiorentini

There is evidence that magnetism can potentially increase the thermopower of materials, most likely due to magnon scattering, suggesting the incorporation of intrinsic magnetic semiconductors in non-magnetic thermoelectric materials. Here,…

Superconducting poly- and single-crystalline samples of Sm1-xThxFeAsO with partial substitution of Sm3+ by Th4+ were synthesized and grown under high pressure and their structural, magnetic and transport properties are studied. The…

Superconductivity · Physics 2011-05-25 N. D. Zhigadlo , S. Katrych , S. Weyeneth , R. Puzniak , P. Moll , Z. Bukowski , J. Karpinski , H. Keller , B. Batlogg

Tin chalcogenides (SnS, SnSe, and SnTe) are found to have improved thermoelectric properties upon the reduction of their dimensionality. Here we found the tilted AA + s stacked two-dimensional (2D) SnTe bilayer as the most stable phase…

Materials Science · Physics 2021-03-10 Abhiyan Pandit , Raad Haleoot , Bothina Hamad

Although SbSe2-based layered compounds have been predicted to be high-performance thermoelectric materials and topological materials, most of these compounds obtained experimentally have been insulators so far. Here, we present the effect…

Materials Science · Physics 2019-01-30 Yosuke Goto , Akira Miura , Chikako Moriyoshi , Yoshihiro Kuroiwa , Yoshikazu Mizuguchi

Monolayer semiconductors of group-VA elements (As, Sb, Bi) with graphenelike buckled structure offer a potential to achieve nanoscale electronic, optoelectronic and thermoelectric devices. Motivated by recently-fabricated Sb monolayer, we…

Materials Science · Physics 2017-02-10 Dong-Chen Zhang , Ai-Xia Zhang , San-Dong Guo

The introduction of A-site vacancies in SrTiO3 results in a glass-like thermal conductivity while Nb substituted samples maintains good electrical conductivity. This unexpected result brings SrTiO3 one step closer to being a high-performing…

Materials Science · Physics 2014-11-04 S. R. Popuri , A. J. M. Scott , R. A. Downie , M. A. Hall , E. Suard , R. Decourt , M. Pollet , J. -W. G. Bos

The shandite family of solids, with hexagonal structure and composition A3M2X2 (A = Ni,Co,Rh,Pd; M = Pb,In,Sn,Tl; X = S,Se), has attracted recent research attention due to promising applications as thermoelectric materials. Herein we…

Materials Science · Physics 2016-11-23 Alex Aziz , Panagiotis Mangelis , Paz Vaqueiro , Anthony V. Powell , Ricardo Grau-Crespo

Copper-based sulfide is an attractive material for Earth-abundant thermoelectrics. In this study, we demonstrate the effect of Sn-substitution on the electrical and thermal transport properties of fematinite Cu3SbS4 from 300 to 573 K. The…

Materials Science · Physics 2015-06-23 Yosuke Goto , Yuki Sakai , Yoichi Kamihara , Masanori Matoba

We present a study of the thermal conductivity k and the thermopower S of single crystals of La_{1-x}Sr_xCoO_3 with 0<= x <= 0.3. For all Sr concentrations La_{1-x}Sr_xCoO_3 has rather low k values, whereas S strongly changes as a function…

Strongly Correlated Electrons · Physics 2009-11-11 K. Berggold , M. Kriener , C. Zobel , A. Reichl , A. Freimuth , T. Lorenz