Related papers: Reactive transport under stress: Permeability evol…
Liquid water can become metastable with respect to its vapor in hydrophobic confinement. The resulting dewetting transitions are often impeded by large kinetic barriers. According to macroscopic theory, such barriers arise from the free…
We show that during evaporation of a pore network, liquid can refill the gas occupied pores, snapping off a gas bubble, which then moves to a stable configuration. This phenomenon is induced by the capillary instability due to the…
The Angstrom-scale transport characteristics of water and six different solutes, methanol, ethanol, 2-propanol, urea, Na+, and Cl-, were studied for a polyamide reverse osmosis (RO) membrane, FT-30, using non-equilibrium molecular dynamics…
We use computer simulations to study the relaxation dynamics of a model for oil-in-water microemulsion droplets linked with telechelic polymers. This system exhibits both gel and glass phases and we show that the competition between these…
This paper presents a micromechanical study of unsaturated granular media in the pendular regime, based upon numerical experiments using the discrete element method, compared to a microstructural elastoplastic model. Water effects are taken…
Shale gas recovery has seen a major boom in recent years due to the increasing global energy demands; but the extraction technologies are very expensive. It is therefore important to develop realistic transport modelling and simulation…
Theoretical and experimental investigations of water vapor interaction with porous materials are carried out both at the macro level and at the micro level. At the macro level, the influence of the arrangement structure of individual pores…
Imbibition, the displacement of a nonwetting fluid by a wetting fluid, plays a central role in diverse energy, environmental, and industrial processes. While this process is typically studied in homogeneous porous media with uniform…
Pressurized fluid injection into underground rocks occurs in applications like carbon sequestration, hydraulic fracturing, and wastewater disposal, and may lead to human-induced earthquakes and surface uplift. The fluid injection raises the…
We investigate the stabilization mechanisms due to viscous forces in the invasion front during drainage displacement in two-dimensional porous media using a network simulator. We find that in horizontal displacement the capillary pressure…
Rock weathering is a common phenomenon in most engineering applications, such as underground storage or geothermal energy. This work offers a discrete element modelization of the problem considering cohesive granular material and debonding…
Ionic transport in nano- to sub-nano-scale pores is highly dependent on translocation barriers and potential wells. These features in the free-energy landscape are primarily the result of ion dehydration and electrostatic interactions. For…
The application of stress to multiphase solid-liquid systems often results in morphological instabilities. Here we propose a solid-solid phase transformation model for roughening instability in the interface between two porous materials…
We present a continuum model describing dissolution and growth of a crystal contact confined against a substrate. Diffusion and hydrodynamics in the liquid film separating the crystal and the substrate are modeled within the lubrication…
We study the characteristics of fluid-fluid displacement in simple mixed-wet porous micromodels numerically using a dynamic pore network model. The porous micromodel consists of distinct water-wet and oil-wet regions, whose fractions are…
We present results from microscopic mode coupling theory generalized to colloidal dispersions under shear in an integration-through-transients formalism. Stress-strain curves in start-up shear, flow curves, and normal stresses are…
Periodic forcing of flow in compressible porous media is an important driver for solute dispersion and mixing in geological and engineered porous media subject for example to tides, pumping and recharge cycles, or fluid injection and…
In this paper, the dilatational response of porous solids with pressure-insensitive matrix displaying strength differential (SD) effects is investigated. To this end, micromechanical finite-element analyses of three-dimensional unit cells…
In the popular solution-diffusion picture, the membrane permeability is defined as the product of the partition ratio and the diffusivity of penetrating solutes inside the membrane in the linear response regime, i.e., in equilibrium.…
We revisit the theory of ion transport in parallel-plate channels and also discuss how the wettability of a solid and the mobility of adsorbed surface charges impact the transport of ions. It is shown that depending on the ratio of the…