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Ultrafast laser irradiation of solids leads to a thermodynamic nonequilibrium within and between the electron and phonon subsystems of the material. Due to electron-electron and phonon-phonon collisions, both subsystems relax into…

Materials Science · Physics 2018-10-24 Isabel Klett , Baerbel Rethfeld

This paper describes the effects of electronic nonequilibrium in a simulation of ultrafast laser irradiation of materials. The simulation scheme based on tight-binding molecular dynamics, in which the electronic populations are traced with…

Materials Science · Physics 2023-12-29 Nikita Medvedev

We study the relaxation dynamics of laser-excited non-equilibrium electron distributions in the valence- and conduction band of a dielectric. We apply Boltzmann collision integrals to trace the influence of different scattering mechanisms…

Statistical Mechanics · Physics 2023-04-28 Nils Brouwer , Steffen Hirtle , Baerbel Rethfeld

The out-of-equilibrium dynamics of electrons and phonons upon laser excitation are often described by the two-temperature model, which assumes that both subsystems are separately in thermal equilibrium. However, recent experiments show that…

Materials Science · Physics 2021-01-04 Ulrike Ritzmann , Peter M. Oppeneer , Pablo Maldonado

Femtosecond laser excitation of solid-state systems creates non-equilibrium hot electrons that cool down by transferring their energy to other degrees of freedom and ultimately to lattice vibrations of the solid. By combining ab initio…

A semiempirical theory for the excitation and subsequent relaxation of nonthermal electrons is described. The theory, which is applicable to ultrafast-laser excited metals, is based on the Boltzmann transport equation for the carrier…

Materials Science · Physics 2023-07-12 D. M. Riffe , Richard B. Wilson

Electron-phonon coupling is a fundamental process that governs the energy relaxation dynamics of solids excited by ultrafast laser pulses. It has been found to strongly depend on electron temperature as well as on nonequilibrium effects.…

Materials Science · Physics 2023-08-03 Tobias Held , Sebastian T. Weber , Baerbel Rethfeld

We present a theoretical study of the ultrafast electron dynamics in transition metals using ultrashort pulsed laser beams. The significant influence of the contribution of the dynamics of produced nonthermal electrons to electron…

Materials Science · Physics 2016-12-14 George D. Tsibidis

A short overview of theoretical models for the description of the relaxation processes in metals excited by a short laser pulse is presented. The main effort is given to description of different processes which are taking place after…

Strongly Correlated Electrons · Physics 2020-05-20 V. V. Kabanov

We study the electron and phonon thermalization in simple metals excited by a laser pulse. The thermalization is investigated numerically by solving the Boltzmann transport equation taking into account all the relevant scattering mechanism:…

Materials Science · Physics 2018-02-28 Shota Ono

An electron-phonon system at commensurate filling often displays charge order (CO) in the ground state. Such a system subject to a laser pulse shows a wide variety of behaviour. A weak pulse sets up low amplitude oscillations in the order…

Strongly Correlated Electrons · Physics 2024-09-10 Sankha Subhra Bakshi , Debraj Bose , Arijit Dutta , Pinaki Majumdar

Electron and phonon transient temperatures are analyzed in the case of nondegenerate semiconductors. An analytical solution is obtained for rectangular laser pulse absorption. It is shown that thermal diffusion is the main energy relaxation…

Ultrafast optical excitation of metals induces a non-equilibrium energy distribution in the electronic system, with a characteristic step-structure determined by Pauli blocking. On a femtosecond timescale, electron-electron scattering…

The electrons and phonons in metal films after ultra-short pulse laser heating are in highly non-equilibrium states not only between the electron sub-system and the phonon sub-system but also within the electron sub-system. An…

Materials Science · Physics 2014-08-05 Jun Zhou , Nianbei Li , Ronggui Yang

Ultrafast laser excitation of a metal causes correlated, highly nonequilibrium dynamics of electronic and ionic degrees of freedom, which are however only poorly captured by the widely-used two-temperature model. Here we develop an…

Materials Science · Physics 2017-12-06 Pablo Maldonado , Karel Carva , Martina Flammer , Peter M. Oppeneer

Photoexcited hot carriers in solids can drive processes, such as photocatalytic reactions on the surface, beyond those available in thermal equilibrium. Hot-electron-mediated reaction pathways are limited by the thermalization of the…

Materials Science · Physics 2026-04-13 Christopher Seibel , Tobias Held , Markus Uehlein , Baerbel Rethfeld

Ultrafast relaxation dynamics of an athermal electron distribution is investigated in silver films using a femtosecond pump-probe technique with 18 fs pulses in off-resonant conditions. The results yield evidence for an increase with time…

Strongly Correlated Electrons · Physics 2022-09-29 Natalia Del Fatti , Roland Bouffanais , Fabrice Vallée , Christos Flytzanis

Ultrafast electron dynamics of solids after an absorption of femtosecond laser pulse is governed by electron-electron, electron-phonon, phonon-electron, and phonon-phonon collisions. It is of importance to construct a framework for…

Materials Science · Physics 2019-01-16 Shota Ono

The rate of energy transfer between electrons and phonons is investigated by a first principles framework for electron temperatures up to $T_e=50000$ K while considering the lattice at ground state. Two typical but differently complex…

Other Condensed Matter · Physics 2022-03-08 Jia Zhang , Rui Qin , Wenjun Zhu , Jan Vorberger

We combine femtosecond electron diffuse scattering experiments and first-principles calculations of the coupled electron-phonon dynamics to provide a detailed momentum-resolved picture of the ultrafast lattice thermalization in a thin film…

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