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Density functional calculations are employed to study the molecular dissociation of hydrogen on graphene, the diffusion of chemisorbed atomic species, and the electronic properties of the resulting hydrogen on graphene system. Our results…

Materials Science · Physics 2011-06-03 Hayley McKay , David J. Wales , S. J. Jenkins , J. A. Verges , P. L. de Andres

Graphene is one of the stiffest known materials, with a Young's modulus of 1 TPa, making it an ideal candidate for use as a reinforcement in high-performance composites. However, being a one-atom thick crystalline material, graphene poses…

Materials Science · Physics 2010-07-13 L. Gong , I. A. Kinloch , R. J. Young , I. Riaz , R. Jalil , K. S. Novoselov

Mechanical properties of graphene prepared by chemical vapor deposition (CVD) are not easily comparable to the properties of nearly perfect graphene prepared by mechanical cleavage. In this work, we attempt to investigate the mechanical…

Graphene's structure bears on both the material's electronic properties and fundamental questions about long range order in two-dimensional crystals. We present an analytic calculation of selected area electron diffraction from multi-layer…

Mesoscale and Nanoscale Physics · Physics 2015-03-20 Brian Shevitski , Matthew Mecklenburg , William A. Hubbard , E. R. White , Ben Dawson , M. S. Lodge , Masa Ishigami , B. C. Regan

Practical applications of graphene require a reliable high-throughput method of graphene identification and quality control, which can be used for large-scale substrates and wafers. We have proposed and experimentally tested a fast and…

Materials Science · Physics 2011-06-21 Craig M. Nolen , Giovanni Denina , Desalegne Teweldebrhan , Bir Bhanu , Alexander A. Balandin

It has recently been demonstrated that difference frequency mixing (DFM) can generate surface plasmons in graphene [1]. Here, we present detailed calculations comparing the contributions to this effect from substrate and from graphene…

A single-layer graphene is synthesized on Cu foil in the absence of H2 flow by plasma enhanced chemical vapor deposition (PECVD). In lieu of an explicit H2 flow, hydrogen species are produced during methane decomposition process into their…

Confocal laser scanning microscopy (CLSM) is a non-destructive, highly-efficient optical characterization method for large-area analysis of graphene on different substrates, which can be applied in ambient air, does not require additional…

In crystal growth, surfactants are additive molecules used in dilute amount or as dense, permeable layers to control surface morphologies. Here, we investigate the properties of a strikingly different surfactant: a two-dimensional and…

This paper describes the use of a high-stability quartz-crystal microbalance (QCM) to measure the mass of a gas absorbed on and in the metal electrode on the quartz oscillator, when the gas pressure is low and the gas can be considered as…

Materials Science · Physics 2018-03-19 Alan J. Slavin

The mechanical integrity of composite materials depends primarily on the interface strength and the defect density of the reinforcement which is the provider of enhanced strength and stiffness. In the case of graphene/ polymer…

Raman spectroscopy is one of the widely used methods in the analysis of various samples including carbon-based materials. This study aimed to identify the number of layers and defects in graphene using micro-Raman spectroscopy. More…

Optics · Physics 2024-03-21 Somayeh Gholipour , Maryam Bahreini , Mohamad Reza Jafarfard

We demonstrate using graphene sheets as a novel mass standard in the scanning transmission electron microscopy (STEM) based mass spectrometry. Here, free-standing graphene sheets are investigated by STEM. The discrete number of graphene…

Mesoscale and Nanoscale Physics · Physics 2011-04-11 Fengqi Song , Ziyou Li , Zhiwei Wang , Longbing He , Min Han , Guanghou Wang

A distant-neighbor quantum-mechanical method is used to study the nonlinear optical wave mixing in graphene nanoflakes (GNFs), including sum- and difference-frequency generation, as well as four-wave mixing. Our analysis shows that…

Optics · Physics 2022-03-11 Hanying Deng , Changming Huang , Yingji He , Fangwei Ye

Graphene stands as a promising material with vast potential across energy storage, electronics, etc. Here, we present a novel mechanical approach utilizing ultrasonic high-energy intercalation exfoliation to extract monolayer graphene from…

Materials Science · Physics 2025-01-15 Kaitong Sun , Si Wu , Junchao Xia , Yinghao Zhu , Guanping Xu , Hai-Feng Li

Thousands of tons of isotopic mixtures are processed annually for heavy-water production and tritium decontamination. The existing technologies remain extremely energy intensive and require large capital investments. New approaches are…

Materials Science · Physics 2017-05-18 M. Lozada-Hidalgo , S. Zhang , S. Hu , A. Esfandiar , I. V. Grigorieva , A. K. Geim

We report a new method for quantitative estimation of graphene layer thicknesses using high contrast imaging of graphene films on insulating substrates with a scanning electron microscope. By detecting the attenuation of secondary electrons…

Mesoscale and Nanoscale Physics · Physics 2012-03-28 Vidya Kochat , Atindra Nath Pal , Sneha E. S. , Arjun B. S. , Anshita Gairola , S. A. Shivashankar , Srinivasan Raghavan , Arindam Ghosh

In order to realise the potential of graphene nanocomposites it is vital to control the degree of dispersion and achieve a strong graphene polymer interface. Herein, we developed a facile grafting to functionalisation approach for graphene…

Crystallographic defects play a key role in determining the properties of crystalline materials. The new class of two-dimensional materials, foremost graphene, have enabled atomically resolved studies of defects, such as vacancies, grain…

Materials Science · Physics 2015-06-22 Ossi Lehtinen , Nilesh Vats , Gerardo Algara-Siller , Pia Knyrim , Ute Kaiser

A strategy to overcome sluggish hydrogenation/dehydrogenation of magnesium is demonstrated by creating magnesium-graphene interphase boundaries via high-pressure torsion (HPT). HPT reduces the grain size of pure magnesium from 1 mm to 850…