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Transport properties of dense fluids are fundamentally challenging, because the powerful approaches of equilibrium statistical physics cannot be applied. Polar fluids compound this problem, because the long-range interactions preclude the…

Soft Condensed Matter · Physics 2020-06-16 Faezeh Pousaneh , Astrid S. de Wijn

We present a stochastic description of a model of N mutually repelling active spheres in the presence of external fields and characterize its steady state behavior. To reproduce the effects of the experimentally observed persistence of the…

Soft Condensed Matter · Physics 2015-11-03 Umberto Marini Bettolo Marconi , Claudio Maggi

Polymer self-consistent field theory techniques are used to derive quantum density functional theory without the use of the theorems of density functional theory. Instead, a free energy is obtained from a partition function that is…

Chemical Physics · Physics 2022-11-29 Russell B. Thompson

The density functional theory originally developed by Hohenberg, Kohn and Sham provides a rigorous conceptual framework for dealing with inhomogeneous interacting Fermi systems. We extend this approach to deal with inhomogeneous interacting…

Condensed Matter · Physics 2015-06-25 A. Griffin

We investigate motility-induced phase separation of active Brownian particles, which are modeled as purely repulsive spheres that move due to a constant swim force with freely diffusing orientation. We develop on the basis of power…

Statistical Mechanics · Physics 2019-11-13 Sophie Hermann , Philip Krinninger , Daniel de las Heras , Matthias Schmidt

A quantitative analysis is presented for the stochastic interactions of a pair of Brownian hard spheres in non-adsorbing polymer solutions. The hard spheres are hypothetically trapped by optical tweezers and allowed for random motion near…

Soft Condensed Matter · Physics 2015-06-18 Mehdi Karzar-Jeddi , Remco Tuinier , Takashi Taniguchi , Tai-Hsi Fan

We investigate the nonequilibrium dynamics of spherical active Brownian particles in three spatial dimensions that interact via a pair potential. The investigation is based on a predictive local field theory that is derived by a rigorous…

Soft Condensed Matter · Physics 2020-08-19 Jens Bickmann , Raphael Wittkowski

To understand sparse systems we must account for both strong local atom bonds and weak nonlocal van der Waals forces between atoms separated by empty space. A fully nonlocal functional form [H. Rydberg, B.I. Lundqvist, D.C. Langreth, and M.…

Materials Science · Physics 2009-11-10 H. Rydberg , M. Dion , N. Jacobson , E. Schroder , P. Hyldgaard , S. I. Simak , D. C. Langreth , B. I. Lundqvist

Ab initio density functional theory has been used to analyze flexural modes, elastic constants, and atomic corrugations on single and bi-layer graphene. Frequencies of flexural modes are sensitive to compressive stress; its variation under…

Materials Science · Physics 2013-01-22 P. L. de Andres , F. Guinea , M. I. Katsnelson

The dynamics of macroscopically homogeneous sheared suspensions of neutrally buoyant, non-Brownian spheres is investigated in the limit of vanishingly small Reynolds numbers using Stokesian dynamics. We show that the complex dynamics of…

Statistical Mechanics · Physics 2007-05-23 G. Drazer , J. Koplik , B. Khusid , A. Acrivos

Using simulation and theory we study the dynamics of a colloidal suspension in two dimensions subject to a time-delayed repulsive feedback that depends on the positions of the colloidal particles. The colloidal particles experience an…

Soft Condensed Matter · Physics 2019-09-06 Sonja Tarama , Stefan U. Egelhaaf , Hartmut Löwen

The Active Brownian Particle (ABP) model has become a prototype of self-propelled particles. ABPs move persistently at a constant speed $V$ along a direction that changes slowly by rotational diffusion, characterized by a coefficient $\Dr$.…

Soft Condensed Matter · Physics 2025-03-11 Rodrigo Soto

In the vicinity of their glass transition, dense colloidal suspensions acquire elastic properties over experimental timescales. We investigate the possibility of a visco-elastic flow instability in curved geometry for such materials. To…

Soft Condensed Matter · Physics 2015-08-21 Alexandre Nicolas , Matthias Fuchs

We study poly-crystalline spherical drops of an aqueous suspension of highly charged colloidal spheres exposed to a colloid-free aqueous environment. Crystal contours were obtained from standard optical imaging. The crystal spheres first…

The Dean-Kawasaki (DK) equation, which is at the basis of stochastic density functional theory (SDFT), was proposed in the mid-nineties to describe the evolution of the density of interacting Brownian particles, which can represent a large…

Soft Condensed Matter · Physics 2025-05-13 Pierre Illien

We introduce numerical methods for simulating the diffusive motion of rigid bodies of arbitrary shape immersed in a viscous fluid. We parameterize the orientation of the bodies using normalized quaternions, which are numerically robust,…

Soft Condensed Matter · Physics 2015-10-28 Steven Delong , Florencio Balboa Usabiaga , Aleksandar Donev

The majority of studies on self-propelled particles and microswimmers concentrates on objects that do not feature a deterministic bending of their trajectory. However, perfect axial symmetry is hardly found in reality, and shape-asymmetric…

Statistical Mechanics · Physics 2018-07-18 Christian Hoell , Hartmut Löwen , Andreas M. Menzel

The fundamental measure density functional theory for hard spheres is generalized to binary mixtures of arbitrary positive and moderate negative non-additivity between unlike components. In bulk the theory predicts fluid-fluid phase…

Soft Condensed Matter · Physics 2009-11-10 Matthias Schmidt

We propose and compare different strategies to construct dynamic density functional theories (DDFTs) for inhomogeneous polymer systems close to equilibrium from microscopic simulation trajectories. We focus on the systematic construction of…

Soft Condensed Matter · Physics 2020-09-29 Sriteja Mantha , Shuanhu Qi , Friederike Schmid

We derive a closed equation for the empirical concentration of colloidal particles in the presence of both hydrodynamic and direct interactions. The ensemble average of our functional Langevin equation reproduces known deterministic Dynamic…

Statistical Mechanics · Physics 2015-06-19 A. Donev , E. Vanden-Eijnden