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We develop a fast method for computing the electrostatic energy and forces for a collection of charges in doubly-periodic slabs with jumps in the dielectric permittivity at the slab boundaries. Our method achieves spectral accuracy by using…

Numerical Analysis · Mathematics 2021-06-16 Ondrej Maxian , Raul P. Peláez , Leslie Greengard , Aleksandar Donev

A multiple-image method is developed to accurately calculate the electrostatic interaction between neutral dielectric particles and a uniformly charged dielectric substrate. The difference in dielectric constants between the particle and…

Soft Condensed Matter · Physics 2024-12-18 Xin Li , Changhao Li , Xiangui Chen , Zaixin Wang , Sun Min , Decai Huang

A tight binding model of electrons interacting via bare Coulomb repulsion is numerically investigated by use of the Density Matrix Renormalization Group method which we prove applicable also to very long range potentials. From the analysis…

Strongly Correlated Electrons · Physics 2009-10-31 G. Fano , F. Ortolani , A. Parola , L. Ziosi

A numerical method is presented for first-principle simulations of charged colloidal dispersions in electrolyte solutions. Utilizing a smoothed profile for colloid-solvent boundaries, efficient mesoscopic simulations are enabled for…

Soft Condensed Matter · Physics 2007-05-23 Kang Kim , Ryoichi Yamamoto

A modified 3D-Ewald summation is presented for accurately simulating the ion-dipole mixture under dielectric confinement. The method is based on the combination of image charges and image dipoles with the conventional Ewald summation and…

Soft Condensed Matter · Physics 2019-10-10 Jiaxing Yuan

An Ewald decomposition of the two-dimensional Yukawa potential and its derivative is presented for both the periodic and the free-space case. These modified Bessel functions of the second kind of zeroth and first degrees are used e.g. when…

Computational Engineering, Finance, and Science · Computer Science 2019-11-15 Sara Pålsson , Anna-Karin Tornberg

A model is developed, based on the density functional perturbation theory and the inverse Kohn-Sham method, that can be used to improve relativistic nuclear energy density functionals towards an exact but unknown Kohn-Sham…

Nuclear Theory · Physics 2021-04-28 Giacomo Accorto , Tomoya Naito , Haozhao Liang , Tamara Niksic , Dario Vretenar

The ground-state energy and the density correlation function of the electron liquid in a thin one-dimensional wire are computed. The calculation is based on an approximate mapping of the problem with a realistic Coulomb interaction law onto…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael M. Fogler

The energy density method is generalized to include spin polarization with the full formalism derived based on spin-density functional theory, which aims at decomposing the total energy into well-defined atomic energies. The method involves…

Materials Science · Physics 2026-04-27 Yang Dan , Dallas R. Trinkle

A crucial aspect in the simulation of electrochemical interfaces consists in treating the distribution of electronic charge of electrode materials that are put in contact with an electrolyte solution. Recently, it has been shown how a…

Materials Science · Physics 2024-07-16 Andrea Grisafi , Mathieu Salanne

We carry out the Ewald summation for the Rotne-Prager-Yamakawa mobility tensor, the Oseen mobility tensor and further variations of both, relevant for the hydrodynamic interactions in colloidal suspensions, where all interacting particles…

Soft Condensed Matter · Physics 2012-05-21 J. Bleibel

In this work, we provide the mathematical elements we think essential for a proper understanding of the calculus of the electrostatic energy of point-multipoles of arbitrary order under periodic boundary conditions. The emphasis is put on…

Chemical Physics · Physics 2021-03-30 Benjamin Stamm , Louis Lagardère , Étienne Polack , Yvon Maday , Jean-Philip Piquemal

We consider a point charge fixed in the Rindler coordinates which describe a uniformly accelerated frame. We determine an integral expression of the induced charge density due to the vacuum polarization at the first order in the fine…

General Relativity and Quantum Cosmology · Physics 2009-10-28 B. Linet

We present a new theory for partitioning simulations of periodic and solid-state systems into physically sound atomic contributions at the level of Kohn-Sham density functional theory. Our theory is based on spatially localized linear…

Chemical Physics · Physics 2024-10-01 Luna Zamok , Janus J. Eriksen

Recent advances in laser technology enable to follow electronic motion at its natural time-scale with ultrafast pulses, leading the way towards atto- and femtosecond spectroscopic experiments of unprecedented resolution. Understanding of…

Chemical Physics · Physics 2023-07-12 Marius Kadek , Lukas Konecny , Michal Repisky

A new iterative solver is proposed to efficiently calculate the ground state electronic structure in Density Functional Theory calculations. This algorithm is particularly useful for simulating physical systems considered difficult to…

Computational Physics · Physics 2021-11-24 Jean-Luc Fattebert

Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…

Soft Condensed Matter · Physics 2021-03-03 Michiel Sprik

For several configurations of charges in the presence of conductors, the method of images permits us to obtain some observables associated with such a configuration by replacing the conductors with some image charges. However, simple…

Classical Physics · Physics 2016-08-16 Rodolfo A. Diaz , William J. Herrera , J. Virgilio Niño

In the framework of the grand-canonical ensemble of statistical mechanics, we give an exact diagrammatic representation of the density profiles in a classical multicomponent plasma near a dielectric wall. By a reorganization of Mayer…

Statistical Mechanics · Physics 2007-05-23 Jean-Noel Aqua , Francoise Cornu

A bivariate perspective on Kohn-Sham density functional theory is proposed, treating potential and density as simultaneous independent variables, and used to make fruitful connection between Lieb's rigorous foundational framework and…

Materials Science · Physics 2020-07-07 Paul E. Lammert