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Related papers: A Modified Poisson--Nernst--Planck Model with Excl…

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Ion transport, often described by the Poisson--Nernst--Planck (PNP) equations, is ubiquitous in electrochemical devices and many biological processes of significance. In this work, we develop conservative, positivity-preserving, energy…

Numerical Analysis · Mathematics 2020-07-15 Jie Ding , Zhongming Wang , Shenggao Zhou

Effective Poisson-Nernst-Planck (PNP) equations are derived for macroscopic ion transport in charged porous media under periodic fluid flow by an asymptotic multi-scale expansion with drift. The microscopic setting is a two-component…

Mathematical Physics · Physics 2014-07-16 Markus Schmuck , Martin Z. Bazant

We derive a set of modified Poisson-Nernst-Planck (mPNP) equations for ion transport from the variation of the free energy functional which includes the many-body Coulomb correlation in media of variable dielectric coefficient. The…

Computational Physics · Physics 2017-08-22 Pei Liu , Xia Ji , Zhenli Xu

In situations involving large potentials or surface charges, the Poisson Boltzman(PB) equation has shortcomings because it neglects ion-ion interactions and steric effects. This has been widely recognized by the electrochemistry community,…

Chemical Physics · Physics 2007-05-23 Mustafa Sabri Kilic , Martin Z. Bazant , Armand Ajdari

First-order energy dissipative schemes in time are available in literature for the Poisson-Nernst-Planck (PNP) equations, but second-order ones are still in lack. This work proposes novel second-order discretization in time and finite…

Numerical Analysis · Mathematics 2023-09-08 Jie Ding , Shenggao Zhou

We propose a modified Poisson-Nernst-Planck (PNP) model to investigate charge transport in electrolytes of inhomogeneous dielectric environment. The model includes the ionic polarization due to the dielectric inhomogeneity and the ion-ion…

Computational Physics · Physics 2015-06-19 Zhenli Xu , Manman Ma , Pei Liu

A macroscopic model to describe the dynamics of ion transport in ion channels is the Poisson-Nernst-Planck(PNP) equations. In this paper, we develop a finite-difference method for solving PNP equations, which is second-order accurate in…

Numerical Analysis · Mathematics 2013-03-18 Allen Flavell , Michael Machen , Bob Eisenberg , Chun Liu , Xiaofan Li

The molecular mechanism of ion channel gating and substrate modulation is elusive for many voltage gated ion channels, such as eukaryotic sodium ones. The understanding of channel functions is a pressing issue in molecular biophysics and…

Biomolecules · Quantitative Biology 2016-11-15 Duan Chen , Guowei Wei

The Poisson-Nernst-Planck (PNP) equations are fundamental for modeling ion transport in electrochemical systems, capturing the intricate interplay of concentration gradients, electric fields, and ion fluxes essential for applications such…

Chemical Physics · Physics 2025-01-13 Yitao He , Dan Zhao

In this paper, we propose and validate a two-species Multiscale model for a Poisson-Nernst-Planck (PNP) system, focusing on the correlated motion of positive and negative ions under the influence of a trap. Specifically, we aim to model…

Numerical Analysis · Mathematics 2026-04-28 Clarissa Astuto , Giovanni Russo

We present a finite volume scheme for modeling the diffusion of charged particles, specifically ions, in constrained geometries using a degenerate Poisson-Nernst-Planck system with size exclusion yielding cross-diffusion. Our method…

Numerical Analysis · Mathematics 2026-03-04 Clément Cancès , Maxime Herda , Annamaria Massimini

In order to describe the dynamics of crowded ions (charged particles), we use an energetic variation approach to derive a modified Poisson-Nernst-Planck (PNP) system which includes an extra dissipation due to the effective velocity…

Mathematical Physics · Physics 2014-08-01 Chia-Yu Hsieh , YunKyong Hyon , Hijin Lee , Tai-Chia Lin , Chun Liu

The reduced 1D Poisson-Nernst-Planck (PNP) model of artificial nanopores in the presence of a permanent charge on the channel wall is studied. More specifically, we consider the limit where the channel length exceed much the Debye screening…

Chemical Physics · Physics 2008-11-23 I. D. Kosińska , I. Goychuk , M. Kostur , G. Schmid , P. Hänggi

Understanding the properties of charge dynamics is crucial to many practical applications, such as electrochemical energy devices and transmembrane ion channels. This work proposes a Maxwell-Amp\`{e}re Nernst-Planck (MANP) framework for the…

Computational Physics · Physics 2025-06-04 Zhonghua Qiao , Zhenli Xu , Qian Yin , Shenggao Zhou

We have developed efficient numerical algorithms for solving 3D steady-state Poisson-Nernst-Planck (PNP) equations with excess chemical potentials described by the classical density functional theory (cDFT). The coupled PNP equations are…

Numerical Analysis · Mathematics 2016-08-24 Da Meng , Bin Zheng , Guang Lin , Maria L. Sushko

In this paper, we introduce and analyze a class of numerical schemes that demonstrate remarkable superiority in terms of efficiency, the preservation of positivity, energy stability, and high-order precision to solve the time-dependent…

Numerical Analysis · Mathematics 2025-07-01 Waixiang Cao , Yuzhe Qin , Minqiang Xu

The analysis of structure-preserving numerical methods for the Poisson--Nernst--Planck (PNP) system has attracted growing interests in recent years. In this work, we provide an optimal rate convergence analysis and error estimate for finite…

Numerical Analysis · Mathematics 2022-02-23 Jie Ding , Cheng Wang , Shenggao Zhou

The Poisson-Nernst-Planck (PNP) system is a widely accepted model for simulation of ionic channels. In this paper, we design, analyze, and numerically validate a second order unconditional positivity-preserving scheme for solving a reduced…

Numerical Analysis · Mathematics 2019-10-01 Hailiang Liu , Wumaier Maimaitiyiming

The Poisson-Nernst-Planck (PNP) system is a standard model for describing ion transport. In many applications, e.g., ions in biological tissues, the presence of thin boundary layers poses both modelling and computational challenges. In this…

Biological Physics · Physics 2018-09-12 Zilong Song , Xiulei Cao , Huaxiong Huang

Charge dynamics play essential role in many practical applications such as semiconductors, electrochemical devices and transmembrane ion channels. A Maxwell-Amp\`{e}re Nernst-Planck (MANP) model that describes charge dynamics via…

Numerical Analysis · Mathematics 2025-06-04 Zhonghua Qiao , Zhenli Xu , Qian Yin , Shenggao Zhou
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