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The choice of vibrational coordinates is crucial for the accuracy, efficiency, and interpretability of molecular vibrational dynamics and spectra calculations. We explore the recently proposed normalizing-flow vibrational coordinates, which…

Chemical Physics · Physics 2025-10-28 Emil Vogt , Álvaro Fernández Corral , Yahya Saleh , Andrey Yachmenev

When trapped atoms are illuminated by weak lasers, off-resonant transitions cause shifts in the frequencies of the vibrational-sideband resonances. These frequency shifts may be understood in terms of Stark-shifts of the individual levels…

Quantum Physics · Physics 2009-11-13 I. Lizuain , J. G. Muga , J. Eschner

A procedure for calculation of rotation-vibration states of medium sized molecules is presented. It combines the advantages of variational calculations and perturbation theory. The vibrational problem is solved by diagonalizing a…

Chemical Physics · Physics 2015-04-13 A. I. Pavlyuchko , S. N. Yurchenko , Jonathan Tennyson

We consider some implications of the mass defect on the frequency of atomic transitions. We have found that some well-known frequency shifts (gravitational shift and motion-induced shifts such as: quadratic Doppler and micromotion shifts)…

Atomic Physics · Physics 2018-02-08 V. I. Yudin , A. V. Taichenachev

Trapped-ion hardware based on the Magnetic Gradient Induced Coupling (MAGIC) scheme is emerging as a promising platform for quantum computing. Nevertheless, in this -- as in any other -- quantum-computing platform, many technical questions…

An algebraic model taking into account the influence of the molecular rotation on the wave functions of vibrational-rotational states of the diatomic molecule using the formalism of the ladder operators and an expansion in a small parameter…

Atomic Physics · Physics 2011-12-30 S. A. Astashkevich

We present a method that formally calculates \emph{exact} frequency shifts of an electromagnetic field for arbitrary changes in the refractive index. The possible refractive index changes include both anisotropic changes and boundary…

Optics · Physics 2007-05-23 Lars Rindorf , Niels Asger Mortensen

For understanding magnetic effects on dynamical tides, we study the rotating magneto-hydrodynamic (MHD) flow driven by harmonic forcing. The linear responses are analytically derived in a periodic box under the local WKB approximation. Both…

Solar and Stellar Astrophysics · Physics 2016-08-31 Xing Wei

In the approach of the effective field theory of modified gravity, we derive the second-order action and the equation of motion for tensor perturbations on the flat isotropic cosmological background. This analysis accommodates a wide range…

High Energy Physics - Theory · Physics 2015-05-27 Antonio De Felice , Shinji Tsujikawa

In continuation of our previous study [Phys. Rev. D 99 (2019) 4, 044012], we investigate the motion of charged particles in the $\gamma$-metric. We provide some examples of curled trajectories in the equatorial plane and escape trajectories…

General Relativity and Quantum Cosmology · Physics 2020-06-15 Carlos A. Benavides-Gallego , Ahmadjon Abdujabbarov , Daniele Malafarina , Cosimo Bambi

We propose a new method to characterize the spatial distribution of particles' vibrations in solids with much lower computational costs compared to the usual normal mode analysis. We excite the specific vibrational mode in a two dimensional…

Soft Condensed Matter · Physics 2016-05-24 Elsen Tjhung , Takeshi Kawasaki

The influence of molecular vibrations on dissociative adsorption is studied by six-dimensional quantum dynamical calculations. For the system H_2 at Pd(100), which possesses non-activated pathways, it is shown that large vibrational effects…

mtrl-th · Physics 2009-10-30 Axel Gross , Matthias Scheffler

Global second-order phase transitions are expected to produce scale-invariant gravitational wave spectra. In this manuscript we explore the dynamics of a symmetry-breaking phase transition using lattice simulations. We explicitly calculate…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-03 John T. Giblin , Larry R. Price , Xavier Siemens , Brian Vlcek

We consider an oscillator model to describe qualitatively friction force for an atomic force mi-croscope (AFM) tip driven on a surface described by periodic potential. It is shown that average value of the friction force could be controlled…

Pattern Formation and Solitons · Physics 2020-10-06 E. V. Kazantseva , Y. Braiman , J. Barhen

In this paper the effects of vibrations at high frequencies onto a freely falling two-body system in Schwarzschild spacetime are investigated. As reference motion of the same system without vibrations a circular orbit around the central…

General Relativity and Quantum Cosmology · Physics 2010-12-02 L. Bergamin , P. Delva , A. Hees

The analytic energy gradients in the atomic orbital representation have recently been published (J. Chem. Phys. 146, 014102, 2017) within the framework of the natural orbital functional theory (NOFT). We provide here an alternative…

Chemical Physics · Physics 2018-02-19 Ion Mitxelena , Mario Piris

We study a stiff quasi-periodic orbit of the electromagnetic two-body problem of Dirac's electrodynamics of point charges. We expand the delay equations of motion about circular orbits to obtain the variational equations up to nonlinear…

Atomic Physics · Physics 2009-11-11 Jayme De Luca

A new heuristic model of interaction of an atomic system with a gravitational wave is proposed. In it, the gravitational wave alters the local electromagnetic field of the atomic nucleus, as perceived by the electron, which changes the…

Quantum Physics · Physics 2017-12-04 Diego A. Quiñones , Benjamin Varcoe

The orbital dynamics of a test particle moving in the non-spherically symmetric field of a rotating oblate primary is impacted also by certain indirect, mixed effects arising from the interplay of the different Newtonian and post-Newtonian…

General Relativity and Quantum Cosmology · Physics 2017-10-06 Lorenzo Iorio

We discuss the electronic transport through molecules in the Kondo regime. We concentrate here on the influence of molecular vibrations. Two types of vibrations are investigated: (i) the breathing internal molecular modes, where the…

Mesoscale and Nanoscale Physics · Physics 2009-12-21 J. Mravlje , A. Ramsak