Related papers: Quantum paramagnet near spin-state transition
A gradual spin-state transition occurs in LaCoO3 around T~80-120 K, whose detailed nature remains controversial. We studied this transition by means of inelastic neutron scattering (INS), and found that with increasing temperature an…
We report a magnetostriction study of a perovskite $\rm{LaCoO}_{3}$ above 100 T using our state-of-the-art strain gauge to investigate an interplay between electron correlations and spin crossover. There has been a controversy regarding…
The electronic structure of the perovskite La$_{1-x}$Sr$_x$CoO$_3$ has been obtained as a function of Sr substitution and volume from a series of generalized-gradient-corrected, full-potential, spin-density-functional band structure…
The doping series Eu1-xCaxCoO3-d provides a rather peculiar way to study the spin-state transition in cobalt-based complex oxides since partial substitution of Eu3+ ions by Ca2+ ions does not increase the mean valence state of cobalt but is…
In the external field slightly inclined to the $x$- or y-axis of the frustrated tetragonal atiferromagnet Pr2CuO4, a transition is discovered from the phase with orthogonal antiferromagnetic spin subsystems along [1,0,0] and [0,1,0] to the…
Magnetization measurements of LaCoO$_{3}$ have been carried out up to 133 T generated with a destructive pulse magnet at a wide temperature range from 2 to 120 K. A novel magnetic transition was found at $B>100$ T and $T>T^{*}=32\pm 5$ K…
In spin crossover materials, an abrupt phase transition between a low spin state and a high spin state can be driven by temperature, pressure or by light irradiation. Of a special relevance are Fe(II) based coordination polymers where, in…
Quantum spin liquids are highly entangled ground states of quantum systems with emergent gauge structure, fractionalized spinon excitations, and other unusual properties. While these features clearly distinguish quantum spin liquids from…
Spin crossover molecules have recently emerged as a family of compounds potentially useful for implementing molecular spintronics devices. The calculations of the electronic properties of such molecules is a formidable theoretical challenge…
Spin-crossover compounds, which are characterized by magnetic ions showing low-spin and high-spin states at thermally accessible energies, are ubiquitous in nature. We here focus on the effect of an exchange interaction on the collective…
In magnets with strong quantum fluctuations, paramagnetic ground states with or without confinement of spinon excitations can be realized. Here we discuss the physics of the confined phase in the vicinity of a confinement--deconfinement…
We give a general introduction to quantum phase transitions in strongly-correlated electron systems. These transitions which occur at zero temperature when a non-thermal parameter $g$ like pressure, chemical composition or magnetic field is…
We present first principles LDA+U calculations of electronic structure and magnetic state for LaCoO3 and HoCoO3. Low Spin to Intermediate Spin state transition was found in our calculations using experimental crystallographic data for both…
Quantum criticality is the intriguing possibility offered by the laws of quantum mechanics when the wave function of a many-particle physical system is forced to evolve continuously between two distinct, competing ground states. This…
\lco{} is known for its two-step spin crossover as a function of temperature. Despite efforts spanning over half a century, the origin of this phenomenon is still debated, particularly regarding how the microscopic spin states are involved…
We investigated domain growth in switching processes between the low-spin and high-spin phases in thermally induced hysteresis loops of spin-crossover (SC) solids. Elastic interactions among the molecules induce effective long-range…
Exploring the physics of low-dimensional spin systems and their pressure-driven electronic and magnetic transitions are thriving research field in modern condensed matter physics. In this context, recently antiferromagnetic Cr-based…
To study non-Heisenberg effects in the vicinity of spin crossover in strongly correlated electron systems we derive an effective low-energy Hamiltonian for the two-band Kanamori model. It contains Heisenberg high-spin term proportional to…
We study quantum phase transitions from easy-plane antiferromagnetic metals to paramagnetic metals in Kondo-Heisenberg lattice systems. If the paramagnetic metal is a fractionalized Fermi liquid then the universal critical properties of the…
Quantum phase transitions in quantum matter occur at zero temperature between distinct ground states by tuning a nonthermal control parameter. Often, they can be accurately described within the Landau theory of phase transitions, similarly…