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General properties of the recently observed screening of the van der Waals (vdW) attraction between a silica substrate and silica tip by insertion of graphene are predicted using basic theory and first-principles calculations. Results are…

Materials Science · Physics 2022-06-08 Musen Li , Jeffrey R. Reimers , John F. Dobson , Tim Gould

It is shown that it is now possible to include van der Waals interactions via a nonempirical implementation of density functional theory to describe the correlation energy in electronic structure calculations on infinite systems of no…

Materials Science · Physics 2009-11-11 Svetla D. Chakarova Kack , Elsebeth Schroder , Bengt I. Lundqvist , David C. Langreth

We extend the method of Silvestrelli [P. L. Silvestrelli, J. Chem. Phys. 139, 054106 (2013)] to approximate long-range van der Waals interactions at the density functional theory level based on maximally localized Wannier functions combined…

Materials Science · Physics 2015-04-21 Pouya Partovi-Azar , T. D. Kühne

Understanding molecular adsorption on surfaces underpins many problems in chemistry and materials science. Accurately and efficiently describing the adsorption has been a challenging task for first-principles methods as the process can…

Materials Science · Physics 2025-08-14 Manish Kothakonda , Ruiqi Zhang , Jinliang Ning , James Furness , Abhirup Patra , Qing Zhao , Jianwei Sun

The description of the molecular solid phase of O$_2$, especially its ground-state antiferromagnetic insulating phase, is known to be quite unsatisfactory within the conventional local and semilocal density functional approximations used in…

Materials Science · Physics 2017-12-18 Shusuke Kasamatsu , Takeo Kato , Osamu Sugino

The dispersion interaction between a pair of parallel DNA double-helix structures is investigated by means of the van der Waals density functional (vdW-DF) method. Each double-helix structure consists of an infinite repetition of one B-DNA…

Soft Condensed Matter · Physics 2013-04-09 Elisa Londero , Per Hyldgaard , Elsebeth Schroder

This paper presents a model of van der Waals forces in the framework of diffusion-convection equations. The model consists of a nonlinear and degenerated diffusion-convection equation, which furthermore can be considered as a model for slow…

Numerical Analysis · Mathematics 2016-08-31 Matthias Herz , Peter Knabner

Following the recent demonstration that van der Waals forces control the ferroelectric ordering of layers within nanoflakes and bulk samples of CuBiP2Se6 and CuInP2S6, it is demonstrated that they also control the internal geometrical…

Materials Science · Physics 2018-05-30 Sherif Abdulkader Tawfik , Jeffrey R. Reimers , Catherine Stampfl , Michael J. Ford

The fundamental ideas for a non-local density functional theory -- capable of reliably capturing van der Waals interaction -- were already conceived in the 1990's. In 2004, a seminal paper introduced the first practical non-local…

Materials Science · Physics 2020-10-21 Debajit Chakraborty , Kristian Berland , T. Thonhauser

We provide a systematic study of the optical models for thin layers: the 3D model, the 2D model and the linearized 2D model. We show that the 2D model is applicable for layers with small optical thicknesses. Excellent agreement of the 2D…

Optics · Physics 2018-01-03 Yilei Li , Tony F. Heinz

Within the frame of macroscopic quantum electrodynamics in causal media, the van der Waals interaction between an atomic system and an arbitrary arrangement of dispersing and absorbing dielectric bodies including metals is studied. It is…

Quantum Physics · Physics 2007-05-23 Stefan Yoshi Buhmann , Ho Trung Dung , Dirk-Gunnar Welsch

Wetting behaviour of surfaces is believed to be affected by van der Waals (vdW) forces, however, there is no clear demonstration of this. With the isolation of two-dimensional vdW layered materials it is possible to test this hypothesis. In…

Mesoscale and Nanoscale Physics · Physics 2022-01-26 Meenakshi Annamalai , Kalon Gopinadhan , Sang A Han , Surajit Saha , Hye Jeong Park , Eun Bi Cho , Brijesh Kumar , Sang-Woo Kim , T Venkatesan

Detailed experimental data for physisorption potential-energy curves of H2 on low-indexed faces of Cu challenge theory. Recently, density-functional theory has been developed to also account for nonlocal correlation effects, including van…

Two-dimensional materials can be combined by placing individual layers on top of each other, so that they are bound only by their van der Waals interaction. The sequence of layers can be chosen arbitrarily, enabling an essentially…

Applied Physics · Physics 2022-03-02 Jonas Haas , Finn Ulrich , Christoph Hofer , Xiao Wang , Kai Braun , Jannik C. Meyer

A recent paper [J. Chem. Phys. 132, 134705 (2010)] illustrated the potential of the van der Waals density functional (vdW-DF) method [Phys. Rev. Lett. 92, 246401 (2004)] for efficient first-principle accounts of structure and cohesion in…

Materials Science · Physics 2015-05-19 Kristian Berland , Oyvind Borck , Per Hyldgaard

We investigate energetic and electronic properties of TiS2 , an archetypal van der Waals (vdW) material, from first principles, in the framework of the Density Functional Theory (DFT). In this system a recent experimental study showed a…

Materials Science · Physics 2020-11-26 Ricci Matteo , Ambrosetti Alberto , Silvestrelli Pier Luigi

We use density functional theory (DFT) with a recently developed van der Waals density functional (vdW-DF) to study the adsorption of graphene on Al, Cu, Ag, Au, Pt, Pd, Co and Ni(111) surfaces. In constrast to the local density…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 M. Vanin , J. J. Mortensen , A. K. Kelkkanen , J. M. Garcia-Lastra , K. S. Thygesen , K. W. Jacobsen

More is left to do in the field of flat bands besides proposing theoretical models. One unexplored area is the flat bands featured in the van der Waals (vdW) materials. Exploring more flat-band material candidates and moving the promising…

Materials Science · Physics 2022-04-05 Jingyi Duan , Da-Shuai Ma , Run-Wu Zhang , Zeying Zhang , Chaoxi Cui , Wei Jiang , Zhi-Ming Yu , Yugui Yao

Recent atomic force microscopy (AFM) experiments~[ACS Nano {\bf 2014}, 8, 12410-12417] conducted on graphene-coated SiO$_2$ demonstrated that monolayer graphene (G) can effectively screen dispersion van der Waals (vdW) interactions deriving…

Materials Science · Physics 2018-06-13 Alberto Ambrosetti , Pier Luigi Silvestrelli

A version of the Green's functions theory of the Van der Waals forces which can be conveniently used in the presence of spatial dispersion is presented. The theory is based on the fluctuation-dissipation theorem and is valid for interacting…

Statistical Mechanics · Physics 2009-05-22 L. P. Pitaevskii